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Covalent and Co-ordinate Bonding - Free MCQ Practice Test with solutions,


MCQ Practice Test & Solutions: Test: Covalent and Co-ordinate Bonding (15 Questions)

You can prepare effectively for JEE Chemistry for JEE Main & Advanced with this dedicated MCQ Practice Test (available with solutions) on the important topic of "Test: Covalent and Co-ordinate Bonding". These 15 questions have been designed by the experts with the latest curriculum of JEE 2026, to help you master the concept.

Test Highlights:

  • - Format: Multiple Choice Questions (MCQ)
  • - Duration: 20 minutes
  • - Number of Questions: 15

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Test: Covalent and Co-ordinate Bonding - Question 1

Among the following ions, the pπ−dπ overlap could be present in

Detailed Solution: Question 1

In P = O bond, π - bond is formed by the sidewise overlapping of d - orbital of P and p - orbital of oxygen. Hence, it is formed by pπ and dπ overlapping.
In nitrogen and carbon, no vacant d-orbital is present. So, they do not form pπ − dπ bond.

Test: Covalent and Co-ordinate Bonding - Question 2

The bond dissociation energy of B−F in BF3 is 646 kJ mol−1 whereas that of C−F in CF4 is 515 kJ mol−1. The correct reason for higher B−F bond dissociation energy as compared to that of C−F is

Detailed Solution: Question 2

The delocalised pπ − pπ bonding between filled p -orbital of F and vacant p -orbital of B leads to shortening of B−F bond length which results in higher bond dissociation energy of the B-F bond.

Test: Covalent and Co-ordinate Bonding - Question 3

In  ion the formal charge on the oxygen atom of P−O bond is ___

Detailed Solution: Question 3

In ion, formal charge on each -atom of
bond

Test: Covalent and Co-ordinate Bonding - Question 4

Which of the following contains both covalent and ionic bond?

Detailed Solution: Question 4

NH4Cl contains both covalent and ionic

Test: Covalent and Co-ordinate Bonding - Question 5

Which of the following species is a radical?

Detailed Solution: Question 5

According to the question, radical is an exception case to the octet rule which occurs when there is an odd number of electrons in an atom.
In case of nitrogen oxide, it has  Odd electrons (seven valency electrons of nitrogen and eight valency electrons of oxygen), so this species work as radical. 
In case of , the total electrons are  (even), in case of nitro ion, total valency electrons are  (even), In case of cyanide ion, total valency electrons are  (even).

Test: Covalent and Co-ordinate Bonding - Question 6

The correct order in which the O − O bond length increases in the following is-

Detailed Solution: Question 6

The increasing order is

Due to resonance in O3, the O − O bond length will be in between O = O and O − O

Test: Covalent and Co-ordinate Bonding - Question 7

Which of the following Lewis dot structure of is incorrect?

Detailed Solution: Question 7

can be represented as
A.
B. (Incorrect structure)
The correct structure is as follows


Test: Covalent and Co-ordinate Bonding - Question 8

The molecules and are both covalent compounds, but is non polar whereas is polar. The reason for this is

Detailed Solution: Question 8

The shape of BF3 is trigonal planar

and hence it is non polar.
The shape of is pyramidal

and hence it is polar.

Test: Covalent and Co-ordinate Bonding - Question 9

The number and type of bonds in ion in are:

Detailed Solution: Question 9

The structure of is
i.e, one and two bonds

Test: Covalent and Co-ordinate Bonding - Question 10

In and , the number of lone pairs on Xe are respectively

Detailed Solution: Question 10

In Total number of valence electrons of , two electrons shared with atoms, 6 electrons left hence 3 lone pairs, in shared with atoms 4 left hence 2 lone pairs; in shared with atoms 2 left hence 1 lone pair.

Test: Covalent and Co-ordinate Bonding - Question 11

The number of molecules participating in hydrogen bonding in is/are

Detailed Solution: Question 11

Only one water molecule, which is outside the coordination sphere, is hydrogen bonded. The other four molecules of water are coordinated with copper cation.

 is the represenation of given compound.

Test: Covalent and Co-ordinate Bonding - Question 12

The maximum number of H-bonds in which water molecule can participate is

Detailed Solution: Question 12

In molecule, two H-bonds are formed with atom and two are formed with atoms of the molecule.

Test: Covalent and Co-ordinate Bonding - Question 13

Which of the following molecules has highest dipole moment?

Detailed Solution: Question 13

Dipole moment of and is zero because these are symmetrical molecules. Dipole moment of is greater than .

Test: Covalent and Co-ordinate Bonding - Question 14

Which of the following has least covalent P − H bond?

Detailed Solution: Question 14

In bond will have ionic character due to electron attracting tendency of P-carrying positive charge and least covalent.

Test: Covalent and Co-ordinate Bonding - Question 15

Which one of the following has longest covalent bond distance?

Detailed Solution: Question 15

The average distance between the centre of nuclei of the two bonded atoms in a molecule is known as bond length. It depends upon the size of atoms, hybridisation, steric effect, resonance etc.
Usually bond length of polar bond is smaller as compared to a non-polar bond. Therefore, C − C bond length is longest among given options.

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