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Raoult's and Henry's law - Free MCQ Practice Test with solutions, JEE Chemistry


MCQ Practice Test & Solutions: Test: Raoult's and Henry's law (15 Questions)

You can prepare effectively for JEE Chemistry for JEE Main & Advanced with this dedicated MCQ Practice Test (available with solutions) on the important topic of "Test: Raoult's and Henry's law". These 15 questions have been designed by the experts with the latest curriculum of JEE 2026, to help you master the concept.

Test Highlights:

  • - Format: Multiple Choice Questions (MCQ)
  • - Duration: 20 minutes
  • - Number of Questions: 15

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Test: Raoult's and Henry's law - Question 1

A 5.2 molal aqueous solution of methyl alcohol (CH3OH) is supplied. What is the mole fraction of methyl alcohol in the solution?

Detailed Solution: Question 1

Test: Raoult's and Henry's law - Question 2

Two 1-litre flask and are connected to each other by a valve which is closed. Flask A has benzene in equilibrium with its vapours at . The flask , is evacuated, and the valve is opened. Which of the following is true. If temperature is kept constant.'

Detailed Solution: Question 2

There is no change in vapour pressure.

Test: Raoult's and Henry's law - Question 3

All form ideal solution except

Detailed Solution: Question 3

and OH form non-ideal solution. Solutions that do not obey Raoult's law over the entire range of concentration are known as non-ideal solutions. Ethyl iodide and ethyl alcohol are chemically dissimilar and form a non-ideal solution.

Test: Raoult's and Henry's law - Question 4

Vapour pressure (in torr) of an ideal solution of two liquids and is given by : where is the mole fraction of in the mixture. The vapour pressure (in torr) of equimolar mixture of the two liquids will be :

Detailed Solution: Question 4

Total V.P.,


Thus, torr
or torr
Hence torr

Test: Raoult's and Henry's law - Question 5

The vapour pressure (at the standard boiling point of water) of an aqueous solution containing by mass of a non-volatile normal solute (molecular mass = 28)  will be

Detailed Solution: Question 5

Moles of solute ;
moles of water
V.P. of solution
torr

Test: Raoult's and Henry's law - Question 6

At a particular temperature, the vapour pressures of two liquids and are respectively 120 and of mercury. If 2 moles of and 3 moles of are mixed to form an ideal solution, the vapour pressure of the solution at the same temperature will be (in mm of mercury)

Detailed Solution: Question 6

Vapour pressure of solution

Test: Raoult's and Henry's law - Question 7

Which one of the following binary mixtures forms an azeotrope with minimum boiling point type?

Detailed Solution: Question 7

Minimum boiling azeotrope is formed by solution showing positive deviation. e.g. acetone ethanol.

Test: Raoult's and Henry's law - Question 8

The vapour pressure of pure benzene and toluene at a particular temperature are and respectively. Then the mole fraction of benzene in vapour phase in contact with equimolar solution of benzene and toluene is

Detailed Solution: Question 8

Total vapour pressure vapour pressure of pure benzene vapour pressure of toluene

We know,

Test: Raoult's and Henry's law - Question 9

A solution at is composed of of benzene and of toluene. If the vapour pressure of pure benzene and pure toluene at this temperature are torr and torr, respectively, then the total vapour pressure of the solution and the benzene mole fraction in equilibrium with it will be, respectively :

Detailed Solution: Question 9

Total V.P. of solution
Given, torr, torr



Total V.P. of solution
torr
torr torr
Mole fraction of benzene in vapour form

Test: Raoult's and Henry's law - Question 10

Pick the correct statement.

Detailed Solution: Question 10

Relative lowering of vapour pressure is , which is equal to mole fraction of solute which is independent of temperature.

Test: Raoult's and Henry's law - Question 11

For an ideal solution of two components and B, which of the following is true?

Detailed Solution: Question 11

Solutions in which solute - solute and solvent-solvent interactions are almost similar to solute solvent interactions are known as ideal solution.

Test: Raoult's and Henry's law - Question 12

Which one of the following gases has the lowest value of Henry's law constant?

Detailed Solution: Question 12

According to Henry's law the mass of a gas dissolved per unit volume of solvent is proportional to the pressure of the gas at constant temperature i.e. as the solubility increases, value of Henry's law constant decreases. Since is most soluble in water among the given set of gases. Therefore has the lowest value of Henry's law constant.

Test: Raoult's and Henry's law - Question 13

Which of the following statement is correct if the intermolecular forces in liquids and are in the order

Detailed Solution: Question 13

Lesser the intermolecular forces, the more the volatile character.

Test: Raoult's and Henry's law - Question 14

At and 1 atmosphere partial pressure of hydrogen, of hydrogen measured at STP dissolves in of water. If water at is exposed to a gaseous mixture having a total pressure of of (excluding the vapour pressure of water) and containing hydrogen by volumne, then the volume of hydrogen measured at STP that will dissolve in 1 L of water is

Detailed Solution: Question 14

From the given data
of atmosphere
atmosphere If 's are volumes of gas dissolved by same volume of liquid, then from Henry's law
; or
or

Test: Raoult's and Henry's law - Question 15

100 mL of liuqid 'A' was mixed with 25 ml of a liquid 'B' to give a non-ideal solution of A-B mixture showing (-) ve deviation from Raoult's law. The volume of this mixture would be

Detailed Solution: Question 15

When two liquids form a non-ideal solution which exhibits a (-) ve deviation from Raoult's law, the volume change on mixing the two components is always negative, i.e., ΔVmix < 0 . Hence, the volume of solution cannot be equal to or greater than 125 mL, but is slightly less than 125 mL.

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