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Test: Characteristics of Halo Compounds - NEET MCQ


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10 Questions MCQ Test Chemistry Class 12 - Test: Characteristics of Halo Compounds

Test: Characteristics of Halo Compounds for NEET 2024 is part of Chemistry Class 12 preparation. The Test: Characteristics of Halo Compounds questions and answers have been prepared according to the NEET exam syllabus.The Test: Characteristics of Halo Compounds MCQs are made for NEET 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Test: Characteristics of Halo Compounds below.
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Test: Characteristics of Halo Compounds - Question 1

Which one of the following is likely to give a precipitate with AgNO3 solution?

Detailed Solution for Test: Characteristics of Halo Compounds - Question 1
  • Tert-butyl chloride forms most stable 3° carbocation. So will give white precipitate of AgCl with AgNO3 solution immediately.
  • (CH₃)₃CCl reacts with AgNO₃ because it forms a stable tertiary carbocation upon ionization. This stable carbocation facilitates the reaction, allowing chloride ions (Cl⁻) to combine with Ag⁺ from AgNO₃, resulting in the formation of a white precipitate of AgCl:

(CH3​)3​CCl+AgNO3​→(CH3​)3​C++AgCl ↓

Hence, option (B) is the answer.

Test: Characteristics of Halo Compounds - Question 2

A solution of (–)-1-chloro-1-phenylethane in toluene racemises slowly in the presence of a small amount of SbCl5, due to the formation of

 

Detailed Solution for Test: Characteristics of Halo Compounds - Question 2

During racemisation, carbocation intermediate is formed.

Hence option (A) is the answer.

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Test: Characteristics of Halo Compounds - Question 3

In SN2 reactions, the correct order of reactivity for the following compounds: CH3Cl, CH3CH2Cl, (CH3)2CHCl and (CH3)3CCl is

Detailed Solution for Test: Characteristics of Halo Compounds - Question 3

Test: Characteristics of Halo Compounds - Question 4

Elimination of bromine from 2-bromobutane results in the formation of

Detailed Solution for Test: Characteristics of Halo Compounds - Question 4

2-bromobutane → CH3CH = CHCH3 + CH3CH2CH=CH2

The major product follows Saytzeff rule.

Hence option (A) is the correct answer.

Test: Characteristics of Halo Compounds - Question 5

Which of the following is a tertiary halogenoalkanes?

Detailed Solution for Test: Characteristics of Halo Compounds - Question 5

The carbon with which the Br is bonded with another 3 carbon atoms. So haloalkane is Tertiary Haloalkane.

Test: Characteristics of Halo Compounds - Question 6

 Which of the following is not true about optical isomers?

Detailed Solution for Test: Characteristics of Halo Compounds - Question 6

Superimposable (mirror images of each other) substances are achiral because chiral substances cannot have its own mirror image. And achiral substances do not show optical activity nor any optical isomers. Hence, answer is B.

Test: Characteristics of Halo Compounds - Question 7

 Which of the following is not an aryl halide?

Detailed Solution for Test: Characteristics of Halo Compounds - Question 7

 Because it is Open chain compound /Aliphatic Compound and not aryl halide as it does not contain halogen atom. It's simply  alkane.

Test: Characteristics of Halo Compounds - Question 8

Pick up the correct statement about alkyl halides.

Detailed Solution for Test: Characteristics of Halo Compounds - Question 8

In general organic compounds are soluble in organic solvents. Hence alkyl halides are soluble in organic solvents.

Test: Characteristics of Halo Compounds - Question 9

 Which one of the following is 1-bromo-3-methyl butane?

Detailed Solution for Test: Characteristics of Halo Compounds - Question 9

It is 1-bromo-3-methylbutane.

Test: Characteristics of Halo Compounds - Question 10

C5H11Br is least soluble in:

Detailed Solution for Test: Characteristics of Halo Compounds - Question 10

C5H11Br are only very slightly soluble in water. They are more soluble in organic solvents.

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