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Chemistry: Topic-wise Test- 4 - NEET MCQ


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30 Questions MCQ Test NEET Mock Test Series 2025 - Chemistry: Topic-wise Test- 4

Chemistry: Topic-wise Test- 4 for NEET 2024 is part of NEET Mock Test Series 2025 preparation. The Chemistry: Topic-wise Test- 4 questions and answers have been prepared according to the NEET exam syllabus.The Chemistry: Topic-wise Test- 4 MCQs are made for NEET 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Chemistry: Topic-wise Test- 4 below.
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Chemistry: Topic-wise Test- 4 - Question 1

(T) imparts violet colour (V) Red gas (W) Red ppt.

(W) Red ppt.  white ppt.

(U)  gas (gives white fumes with HCl)

sublimes on heating Identify (T) to (Z).

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 1

The correct answer is option B

Chemistry: Topic-wise Test- 4 - Question 2

The number of moles of acidified KMnO4 required to convert one mole of sulphite ion into sulphate ion is-

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 2

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Chemistry: Topic-wise Test- 4 - Question 3

N2(g) + 3H2 (g)  2NH3(g) ; Haber's process, Mo is used as -

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 3

MO is catalytic promoter & it improves catalytic properties as catalyst

*Multiple options can be correct
Chemistry: Topic-wise Test- 4 - Question 4

Potash alum is a double salt, its aqueous solution shows the characteristics of-

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 4

K2SO4 .Al2(SO4)3.24 H2O + H2O

*Multiple options can be correct
Chemistry: Topic-wise Test- 4 - Question 5

Cr2O72-  2CrO42-, X and Y are respectively-

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 5

Chemistry: Topic-wise Test- 4 - Question 6

x is moles of HIO4 consumed

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 6

Chemistry: Topic-wise Test- 4 - Question 7

The structure of the product formed in the reaction given below is -

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 7

Chemistry: Topic-wise Test- 4 - Question 8

, Products obtained in the above reaction are -

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 8

Chemistry: Topic-wise Test- 4 - Question 9

Vapour pressure of pure water at 298 K is 23.8 torr. Thus, vapour pressure of a solution containing 6 g urea and 68.4 g sucrose in 10 moles of water is

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 9

By Raoult’s law, for a mixture of non-volatile solute in volatile solvent.

 

Chemistry: Topic-wise Test- 4 - Question 10

Vapour pressure of nitrobenzene (molar mass = 123 g mol-1) is 3.6 kNm-2 and that of water (molar mass = 18 g mol-1) is 977 kNm-2. They form immiscible mixture at the given temperature. Thus, percentage of nitrobenzene in the vapour phase is

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 10

For immiscible solvents, composition of each component is based on

 

Chemistry: Topic-wise Test- 4 - Question 11

At 298 K, the vapour pressure of pure water is 23.76 mm Hg and that of an aqueous solution is 22.98 mm Hg. Thus, molality of solution is (assume dilute solution) 

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 11

(c)

By Raoult’s law for a non-volatile solute in volatile solvent.

Chemistry: Topic-wise Test- 4 - Question 12

Elevation in boiling point of a molar (1 M) glucose solution (d = 1.2 g mL-1) is

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 12

(a) Molarity =1 M =1 mol L-1

 1000 mL of solution has glucose = 180 g

(1000 x 1.2) g of solution has glucose = 180g

∴ Solute (w1) =180 g

Solution =1200 g 

Chemistry: Topic-wise Test- 4 - Question 13

Relative lowering of vapour pressure of a non-volatile solute X in water is 0.05. If   Kb(H20) = 0.52° mol-1  kg-1.

(ΔTb) = elevation in boiling point assuming a dilute solution

(ATb)' = elevation in boiling point assuming a solution of moderate concentration then, {ΔTb) - {ΔTb)' =

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 13

By Raoult’s law,

If solution is dilute,

If solution is of moderate concentration,

Chemistry: Topic-wise Test- 4 - Question 14

Which has maximum osmotic pressure at temperature T K?

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 14

Chemistry: Topic-wise Test- 4 - Question 15

There is formation of Prussian blue when Fe3+ reacts with [Fe(CN)6]4-. Two solutions as shown are separated by a semipermeable membrane AB. Due to osmosis, there is

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 15

Side X (0.1 M)            Side Y (0.01 M)

     (Concentrated)              (Dilute)

There is osmosis of solvent (H20) from dilute solution (Y) to concentrated solution (X). There is no osmosis of ions, hence no blue colour formation.

Chemistry: Topic-wise Test- 4 - Question 16

Three solutions of following in water are isothermal conditions as given:

Thus,

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 16

Chemistry: Topic-wise Test- 4 - Question 17

Only One Option Correct Type
This section contains 7 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct

Q.

The degree of dissociation (α ) o f weak electrolyte AxBy is related to van’t Hoff factor (i) by the expression

[AIEEE 2011]

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 17

 (a) van’t Hoff factor (i) = [1 + (n - 1)α] where, n = number of ions from one mole of solute

α = degree of ionisation/association 

Chemistry: Topic-wise Test- 4 - Question 18

0.004 M Na2S04 aqueous solution is isotonic with 0.01 M glucose solution at 300 K. Thus, degree of dissociation of Na2S04 is

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 18

i (van’t Hoff factor) = 1 + (y — 1) x = (1 + 2 x)

∴ π, (osmotic pressure) = MRTi = 0.004 x R x 300 x (1 + 2x)

Glucose is a non-electrolyte.
Hence,

i = 1

π2 = mRTi = 0.01 x R x 300 x 1 Two solutions are isotonic, hence

Chemistry: Topic-wise Test- 4 - Question 19

When 20 g of naphthoic acid (C11H8O2) is dissolved in 50 g of benzene, a freezing point depression of 2 K is observed. [Kf (benzene) = 1.72Kmol-1 kg]. The van’t Hoff factor (i) is 

[IIT - JEE 2007]

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 19

w1| = 20.0 g

m1 = 11x 12 + 8 x 1 + 2 x 16 = 172 g mol-1  w2 = 50.0 g 

Chemistry: Topic-wise Test- 4 - Question 20

An aqueous solution of a solute AB has boiling point of 101.08° C and freezes at -1 .80 °C . AB is found to be 100% ionised at boiling point. If Kb /Kf = 0.3, then AB

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 20

Thus, AS behaves as a non-electrolyte at the freezing point of solution (remains non-ionised).

Chemistry: Topic-wise Test- 4 - Question 21

Among the alkenes which one produces tertiary butyl alcohol on acid hydration

Chemistry: Topic-wise Test- 4 - Question 22

What is the correct increasing order of acidity of the following?

 

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 22

Both (I) and (II) are 2° alcohols, less acidicthan (I) and (IV) where there is electron withdrawing chloride group is present. Between (I) and (II), (I) is less acidic as ring is considered here equivalent to two ethyl groups attached to α-carbon. (Ill) is more acidic than (IV) because in (III) Cl is at α-carbon while it is at β-carbon in (IV).

Chemistry: Topic-wise Test- 4 - Question 23

Which of the following can be used for the distinction of ethanol from phenol?

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 23

Phenol forms salt with NaOH while a liphatic alcohols do not.

Chemistry: Topic-wise Test- 4 - Question 24

Consider the following reaction,

The above reaction can best be brought about by

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 24

In the below reaction , no bond with chiral carbon is disturbed, hence, configuration is retained in product.

Chemistry: Topic-wise Test- 4 - Question 25

Passage III

When suspected drunk drivers are tested with a breathalyser, the alcohol (ethanol) in the exhaled breath is oxidised to ethanoic acid with an acidic solution of potassium dichromate.

 

Q.

Under standard state, E°cell of the breathalyser would be  

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 25

CH3CH2OH is oxidised to CH3COOH and is reduced to Cr3+.
cell - E°CH3CH2OH/CH3COOH + E°/Cr3+
= -0.06+1.33 
= 1.27 V
Reaction quotient

Chemistry: Topic-wise Test- 4 - Question 26

Passage III

When suspected drunk drivers are tested with a breathalyser, the alcohol (ethanol) in the exhaled breath is oxidised to ethanoic acid with an acidic solution of potassium dichromate.

 

Q.

Under the condition of unit activity of each species,emf recorded in the breathalyser at pH 4 would be  

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 26

CH3CH2OH is oxidised to CH3COOH and is reduced to Cr3+.
cell - E°CH3CH2OH/CH3COOH + E°/Cr3+
= -0.06+1.33 
= 1.27 V
Reaction quotient

*Answer can only contain numeric values
Chemistry: Topic-wise Test- 4 - Question 27

E° values of Mn+ + ne- → M are given below
Fe2+/Fe -0.44 V, Mg2+/Mg -2.37 V, Pt(H2)/H+ 0.00 V,
AI3+/AI -1.66 V , Zn2+/Zn - 0.76 V, Cu2+/Cu +0.34 V,
Ag+/Ag + 0.80 V, Ni2+/Ni -0.26 V

How many of the metals can be used to prevent corrosion of Ni to Ni2+?


Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 27

Fe, Al, Zn and Mg can be used to protect Ni from being oxidised to Ni2+ since, E°cell > 0 and ΔG° < 0.

*Answer can only contain numeric values
Chemistry: Topic-wise Test- 4 - Question 28

A fully charged battery contains 500 mL of 5.00 M H2SO4. What is the concentration of H2SO4 in the battery after 6.0 A of current is drawn from the battery for 13.40 h?


Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 28

*Answer can only contain numeric values
Chemistry: Topic-wise Test- 4 - Question 29

A hydrogen-oxygen fuel cell opeartes on the simple reaction:

  

If the cell is designed to produce 1.46A of current and if the H2 is contained in a 1.0 L tank at 2.00 atm pressure at 298K, how long can the fuel cell operate(in hour) before the H2 runs out.(Assume unlimited supply of oxygen)   


Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 29


Chemistry: Topic-wise Test- 4 - Question 30

Matching List Type

Choices for the correct combination of elements from Column I and Column II are given as options (a), (b), (c) and (d), out of which one is correct

Four electrolytic cells containing solution of ZnSO4, AgNO3, CuSO4 and dil. H2SO4 are connected in series. A steady current of 1.5 A was passed through them until 77 mL of O2 gas at STP is formed in anode compartment of H2SO4 solution. Match the different elements/gas formed In Column I with their values in Column II and select the answer from the codes given below. (Cu = 63.5, Zn = 65, Ag = 108, S = 32, H = 1, 0 = 16) 
 

   

Codes   i       ii      iii      iv 

Detailed Solution for Chemistry: Topic-wise Test- 4 - Question 30

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