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Case Based Questions Test: Haloalkanes & Haloarenes - 2


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12 Questions MCQ Test Chemistry Class 12 | Case Based Questions Test: Haloalkanes & Haloarenes - 2

Case Based Questions Test: Haloalkanes & Haloarenes - 2 for NEET 2022 is part of Chemistry Class 12 preparation. The Case Based Questions Test: Haloalkanes & Haloarenes - 2 questions and answers have been prepared according to the NEET exam syllabus.The Case Based Questions Test: Haloalkanes & Haloarenes - 2 MCQs are made for NEET 2022 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Case Based Questions Test: Haloalkanes & Haloarenes - 2 below.
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Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 1

 Read the  passage given below and answer the following questions:

Alkyl/Aryl halides may be classified as mono, di or polyhalogen compounds depending on one, two or more halogen atoms in their structures. Alkyl halides are prepared by free radical halogenation of alkanes, addition of halogen acids to alkenes and replacement of –OH group of alcohols with halogens using phosphorus halides, thionyl chloride or halogen acids. Aryl halides are prepared by electrophilic substitution to arenes.

Q. Name the major monohalo product of the following reaction:

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 1

According to Markovnikov ’s rule, iodine will add to the carbon atom having less number of hydrogen atoms.

Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 2

Read the  passage given below and answer the following questions:

Alkyl/Aryl halides may be classified as mono, di or polyhalogen compounds depending on one, two or more halogen atoms in their structures. Alkyl halides are prepared by free radical halogenation of alkanes, addition of halogen acids to alkenes and replacement of –OH group of alcohols with halogens using phosphorus halides, thionyl chloride or halogen acids. Aryl halides are prepared by electrophilic substitution to arenes.

Q. Which of the following  is halogen exchange reaction?

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 2

RX → RI + NaX
It is halogen exchange reaction as in this reaction both R and Na exchanges halogens.

Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 3

Read the  passage given below and answer the following questions:

Alkyl/Aryl halides may be classified as mono, di or polyhalogen compounds depending on one, two or more halogen atoms in their structures. Alkyl halides are prepared by free radical halogenation of alkanes, addition of halogen acids to alkenes and replacement of –OH group of alcohols with halogens using phosphorus halides, thionyl chloride or halogen acids. Aryl halides are prepared by electrophilic substitution to arenes.

Q. Complete the reaction:
H3C-Br + AgF →

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 3

H3C-Br + AgF → H3C-F + AgBr.
 

Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 4

Read the  passage given below and answer the following questions:

Alkyl/Aryl halides may be classified as mono, di or polyhalogen compounds depending on one, two or more halogen atoms in their structures. Alkyl halides are prepared by free radical halogenation of alkanes, addition of halogen acids to alkenes and replacement of –OH group of alcohols with halogens using phosphorus halides, thionyl chloride or halogen acids. Aryl halides are prepared by electrophilic substitution to arenes.

Q. 2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bromopentane Write the compound which is most reactive towards β-elimination reaction.

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 4


Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 5

Read the  passage given below and answer the following questions:

Alkyl/Aryl halides may be classified as mono, di or polyhalogen compounds depending on one, two or more halogen atoms in their structures. Alkyl halides are prepared by free radical halogenation of alkanes, addition of halogen acids to alkenes and replacement of –OH group of alcohols with halogens using phosphorus halides, thionyl chloride or halogen acids. Aryl halides are prepared by electrophilic substitution to arenes.

Q. Arrange the following compounds in increasing order of their boiling points.

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 5

Boiling point of (i) is 364 K, boiling  point of (ii) is 375 K. boiling point of (iii) is 346 K As the branching increases in the isomeric alkyl halides, the boiling point decreases.

Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 6

Read the passage given below and answer the following questions:

The objects which are non-superimposable on their mirror image (like a pair of hands) are said to be chiral and this property is known as chirality. Chiral molecules are optically active, while the objects, which are, superimposable on their mirror images are called achiral. These molecules are optically inactive. The above test of molecular chirality can be applied to organic molecules by constructing models and its mirror images or by drawing three dimensional structures and attempting to superimpose them in our minds. There are other aids, however, that can assist us in recognising chiral molecules. One such aid is the presence of a single asymmetric carbon atom.

Q. In this questions a statement of assertion followed by a statement  of reason is given . Choose the correct answer out of the following  choices.
Assertion (A): A racemic mixture containing two enantiomers in equal proportions will have zero optical rotation.
Reason (R): This is because  the rotation due to one isomer will be cancelled by the rotation due to the other isomer.

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 6

A racemic mixture is an equimolar mixture of d and l forms. It is optically inactive due to external compensation as rotation of one form is cancelled by other form.

Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 7

Read the passage given below and answer the following questions:

The objects which are non-superimposable on their mirror image (like a pair of hands) are said to be chiral and this property is known as chirality. Chiral molecules are optically active, while the objects, which are, superimposable on their mirror images are called achiral. These molecules are optically inactive. The above test of molecular chirality can be applied to organic molecules by constructing models and its mirror images or by drawing three dimensional structures and attempting to superimpose them in our minds. There are other aids, however, that can assist us in recognising chiral molecules. One such aid is the presence of a single asymmetric carbon atom.

Q. In this questions a statement of assertion followed by a statement  of reason is given . Choose the correct answer out of the following  choices. 
Assertion (A): Propan-2-ol is an achiral molecule.
Reason (R): Carbon is called asymmetric carbon or stereocentre.

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 7

Propan-2-ol is an achiral molecule as it does not contain an asymmetric carbon, as all the four groups attached to the tetrahedral carbon are not different.

Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 8

Read the passage given below and answer the following questions:

The objects which are non-superimposable on their mirror image (like a pair of hands) are said to be chiral and this property is known as chirality. Chiral molecules are optically active, while the objects, which are, superimposable on their mirror images are called achiral. These molecules are optically inactive. The above test of molecular chirality can be applied to organic molecules by constructing models and its mirror images or by drawing three dimensional structures and attempting to superimpose them in our minds. There are other aids, however, that can assist us in recognising chiral molecules. One such aid is the presence of a single asymmetric carbon atom.

Q. In this questions a statement of assertion followed by a statement  of reason is given . Choose the correct answer out of the following  choices. 
Assertion (A): The stereoisomers related to each other as non-superimposable mirror images are called enantiomers
Reason (R): Enantiomers possess identical physical properties.

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 8

The stereoisomers related to each other as non-superimposable mirror images are called enantiomers and they possess identical physical properties.

Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 9

Read the passage given below and answer the following questions:

The objects which are non-superimposable on their mirror image (like a pair of hands) are said to be chiral and this property is known as chirality. Chiral molecules are optically active, while the objects, which are, superimposable on their mirror images are called achiral. These molecules are optically inactive. The above test of molecular chirality can be applied to organic molecules by constructing models and its mirror images or by drawing three dimensional structures and attempting to superimpose them in our minds. There are other aids, however, that can assist us in recognising chiral molecules. One such aid is the presence of a single asymmetric carbon atom.

Q. In this questions a statement of assertion followed by a statement  of reason is given . Choose the correct answer out of the following  choices. 
Assertion (A): Butan-2-ol is a chiral molecule.
Reason (R): It has 4 different groups attached to carbon atom.

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 9

Butan-2-ol is a chiral molecule as it has 4 different functional groups attached to the tetrahedral carbon atom.

Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 10

Read the passage given below and answer the following questions:

Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons: 
(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.
(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.
(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.

Q. Which of the following alkyl halides will undergoes SN1 reaction most readily?

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 10

(CH)3C-I being a tertiary alkyl halide will most readily undergo SN1 reaction.

Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 11

Read the passage given below and answer the following questions:

Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons: 
(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.
(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.
(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.

Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 11

C6H5-CH2 is stable cation so favours the progress of reaction by SN1 mechanism.

Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 12

Read the passage given below and answer the following questions:

Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons: 
(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.
(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.
(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.

Q. A primary alkyl halide would prefer to undergo ________.

Detailed Solution for Case Based Questions Test: Haloalkanes & Haloarenes - 2 - Question 12

A primary alkyl halide would prefer to undergo SN2 reaction.

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