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Electrochemistry - Class 12 MCQ


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30 Questions MCQ Test - Electrochemistry

Electrochemistry for Class 12 2024 is part of Class 12 preparation. The Electrochemistry questions and answers have been prepared according to the Class 12 exam syllabus.The Electrochemistry MCQs are made for Class 12 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Electrochemistry below.
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Electrochemistry - Question 1

The amount of electricity required to produce one mole of copper from copper sulphate solution will be:    

Detailed Solution for Electrochemistry - Question 1

 no. of electrons used is equal to no. of Faradays.

Electrochemistry - Question 2

Which of the following condition is correct for operation of electrolytic cell?    

Detailed Solution for Electrochemistry - Question 2

Electrolytic cell is non-spontaneous cell, so, ΔG > O
As, ΔG = -nFE ,E must be less than zero

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Electrochemistry - Question 3

On passing one faraday of electricity through a dilute solution of an acid, the volume of hydrogen obtained at NTP is:    

Detailed Solution for Electrochemistry - Question 3

2H2 + 2e- →H2 ; 1 mole of H2 gas requires 2F charge, So, 11200 ml will be liberated by 1F.

Electrochemistry - Question 4

When electricity is passed through a solution of AICI3, 13.5 g of AI is discharged. The amount of charge passed is:    

Detailed Solution for Electrochemistry - Question 4

number of Faradays passed = no. of g-eq of metal

= 13.5/9 = 1.5F

Electrochemistry - Question 5

The specific conductance of a 0.01 M solution of KCI is 0.0014 ohm-1 at 250C. Its equivalent conductance is:    

Detailed Solution for Electrochemistry - Question 5

Electrochemistry - Question 6

The equivalent conductivity of 0.1 N CH3COOH at 250C is 80 and at infinite dilution 400 ohm-1. The degree of dissociation of CH3COOH is:    

Detailed Solution for Electrochemistry - Question 6

Electrochemistry - Question 7

One faraday of charge was passed through the electrolytic cells placed in series containing solution of Ag+, Ni2+ and Cr3+ respectively. The amount of Ag (At. mass 108), Ni (At. mass 59) and Cr (At mass 52) deposited will be:      

Detailed Solution for Electrochemistry - Question 7

1 F deposits - 1 mole of Ag, 1/2 mole of Ni & 1/3 mole of Cr

Electrochemistry - Question 8

At 250C, the , molar conductance at infinite dilution for the strong electrolytes NaOH, NaCI and BaCI2 are 248 x 10-4, 126 x 10-4 and 280 x 10-4 S m2 mol-1 respectively.    

Detailed Solution for Electrochemistry - Question 8

= 280*10-4 + 496*10-4 - 252*10-4

= 524*10-4 Sm2 mol-1

Electrochemistry - Question 9

The electrochemical cell stops working after some time because :    

Detailed Solution for Electrochemistry - Question 9

Cell works due to difference in electrode potential, during working of cell, reduction potential of anode increases & cathode decreases. Finally, cell stops working when electrode potentials become equal.

Electrochemistry - Question 10

If a spoon of copper metal is placed in a solution of ferrous sulphate :    

Detailed Solution for Electrochemistry - Question 10

Fe is reactive metal than copper ion is positive while Fe2+ ion is negative) When copper metal is placed in ferrous sulphate solution nothing happens, as they do not react

Electrochemistry - Question 11

Which of the following represent the potential of silver wire dipped into 0.1 M AgNO3 solution at 250C ?

Detailed Solution for Electrochemistry - Question 11

According to Nernst equation,

Electrochemistry - Question 12

If the solution of the CuSO4 in which copper rod is immersed is diluted to 10 times, the electrode potential :    

Detailed Solution for Electrochemistry - Question 12

When solution is diluted 10 times, conc. of [Cu2+] become 1/10
, electrode potential decreases by 0.03 V

Electrochemistry - Question 13

From the electrochemical series, it can be conculded that:    

Detailed Solution for Electrochemistry - Question 13

Zn metal is more reactive, while Ag metal is less reactive than H2, So, Zn metal can reduce Hions

Electrochemistry - Question 14

Which is not true for a standard hydrogen electrode?    

Detailed Solution for Electrochemistry - Question 14

Feature of SHE

Electrochemistry - Question 15

Given, standard electrode potential;The standard electrode potential 

The standard electrode potential 

Detailed Solution for Electrochemistry - Question 15

Apply ΔG = -nFE

Subtracting eq.(i) from eq. (ii)

= - 0.772 F

E0 for the reaction = 

Electrochemistry - Question 16

The potential of a hydrogen electrode at pH = 10 is:    

Detailed Solution for Electrochemistry - Question 16

Electrode potential of SHE is,

= -0.59V

Electrochemistry - Question 17

The standard emf for the cell reaction,

is 1.10 volt at 250C. The emf for the cell reaction when solution are used at 250C

Detailed Solution for Electrochemistry - Question 17

It will remains unaffected as [Cu2+ ] = [Zn2+ ]

Electrochemistry - Question 18

Kohlrausch’s law states that at:    

Detailed Solution for Electrochemistry - Question 18

Definition of Kohlransch’s law

Electrochemistry - Question 19

Statements:    
(i) Unit of specific conductivity is ohm-1 cm-1    
(ii) Specific conductivity of strong electrolytes decreases on dilution.    
(iii) The amount of an ion discharged during electrolysis does not depend upon resistance.    
(iv) The unit of electrochemical equivalence is g/coulomb.    

Detailed Solution for Electrochemistry - Question 19

Conceptual

Electrochemistry - Question 20

The emf of the cell in which the following reaction,   occurs, is formed to 0.5105 V at 298 K. The standard emf of the cell is:

Detailed Solution for Electrochemistry - Question 20

= 0.5400V

Electrochemistry - Question 21

In the electrochemical reaction.   increasing the concentration of Fe2+:    

Detailed Solution for Electrochemistry - Question 21

So, Ecell decreases with increase in concentration of Fe2+

Electrochemistry - Question 22

When 9.65 coulomb of electricity is passed through a solution of silver nitrate (Atomic mass of Ag=108 g mol-1), the amount of silver deposited is:    

Detailed Solution for Electrochemistry - Question 22

no. of g-eq of Ag deposited = 9.65/96500=10-4
WAg deposited = 10-4 x 108 = 10.8 mg

Electrochemistry - Question 23

A current is passed through two voltameters connected in series. The first voltameter contains XSO4(aq.) while the second voltameter conatins Y2SO4(aq.). The relative atomic masses of X and Y are in the ratio 2:1. The ratio of the mass of X liberated to the mass of Y liberated is:    

Detailed Solution for Electrochemistry - Question 23

Ratio of mass deposited is calculated by Faraday’s second law

Electrochemistry - Question 24

In which of the following cells will the emf be independent of the acitvity of the chloride ions?

Detailed Solution for Electrochemistry - Question 24

Given cell uses metal insoluble salt electrode, where emf is decided by Ksp

Electrochemistry - Question 25

The emf of the cell, at 298 K is 0.2905 V then the value of equilibrium constant for the cell reaction is:

Detailed Solution for Electrochemistry - Question 25

Electrochemistry - Question 26

The standard electrode potential of Ag+/ Ag is + 0.80 V and of Cu2+ / Cu is + 0.34 V. These electrodes are connected through a salt bridge and if:

Detailed Solution for Electrochemistry - Question 26

Metal ion with low acts as anode & high as cathode, so,as to get +ve value of

Electrochemistry - Question 27

The reduction potential of hydrogen half-cell will be negative if:

Detailed Solution for Electrochemistry - Question 27

Electrochemistry - Question 28

Given    The potential for the cell,  :

Detailed Solution for Electrochemistry - Question 28

=0.29V

Electrochemistry - Question 29

The emf of a cell containing sodium/ copper electrodes is 3.05 V, if the electrode potential copper electrode is +0.34 V, the electrode potential of sodium is:    

Detailed Solution for Electrochemistry - Question 29

Electrochemistry - Question 30

Given  

Among the following, the strongest reducing agent is:

Detailed Solution for Electrochemistry - Question 30

Greater is the positive value of standard oxidation potential more is reducing behaviour. Thus, Cr will be strongest reducing agent.]
 

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