JEE Advanced 2017 Paper - 2 with Solutions

A symmetric star shaped conducting wire loop is carrying a steady state current I as shown in the figure. The distance between the diametrically opposite vertices of the star is 4a. The magnitude of the magnetic field at the center of the loop is :

A photoelectric material having work-function φ₀ is illuminated with light of wavelength  The fastest photoelectron has a de-Broglie wavelength λ_d. A change in wavelength of the incident light by Δλ results in a change Δλ_d in λ_d. Then the ratio Δλ_d / Δλ is proportional to

A person measures the depth of a well by measuring the time interval between dropping a stone and receiving the sound of impact with the bottom of the well. The error in his measurement of time is δT = 0.01 second and he measures the depth of the well to be L = 20 meters. Take the acceleration due to gravity g = 10 ms^–2and the velocity of sound is 300 ms^–1. Then the fractional error in the measurement, δL/L, is closest to

Consider an expanding sphere of instantaneous radius R whose total mass remains constant. The expansion is such that the instantaneous density r remains uniform throughout the volume. The rate of fractional change in density  is constant. The velocity v of any point on the surface of the expanding sphere is proportional to :

Consider regular polygons with number of sides n = 3, 4, 5 ..... as shown in the figure. The center of mass of all the polygons is at height h from the ground. They roll on a horizontal surface about the leading vertex without slipping and sliding as depicted. The maximum increase in height of the locus of the center of mass for each polygon is Δ. Then Δ depends on n and h as :

A rigid uniform bar AB of length L is slipping from its vertical position on a frictionless floor (as shown in the figure). At some instant of time, the angle made by the bar with the vertical is q. Which of the following statements about its motion is/are correct ?

Two coherent monochromatic point sources S₁ and S₂ of wavelength λ = 600 nm are placed symmetrically on either side of the center of the circle as shown. The sources are separated by a distance d = 1.8mm. This arrangement produces interference fringes visible as alternate bright and dark spots on the circumference of the circle. The angular separation between two consecutive bright spots is Δθ. Which of the following options is/are correct ?

A source of constant voltage V is connected to a resistance R and two ideal inductors L₁ and L₂ through a switch S as shown. There is no mutual inductance between the two inductors. The switch S is initially open. At  t = 0, the switch is closed and current begins to flow. Which of the following options is/ are correct?

A wheel of radius R and mass M is placed at the bottom of a fixed step of height R as shown in the figure. A constant force is continuously applied on the surface of the wheel so that it just climbs the step without slipping. Consider the torque τ about an axis normal to the plane of the paper passing through the point

Q. Which of the following options is/are correct ?

The instantaneous voltages at three terminals marked X, Y and Z are given by

An ideal voltmeter is configured to read rms value of the potential difference between its terminals. It is connected between points X and Y and then between Y and Z. The reading(s) of the voltmeter will be:-

A point charge +Q is placed just outside an imaginary hemispherical surface of radius R as shown in the figure. Which of the following statements is/are correct ?

PARAGRAPH–1
Consider a simple RC circuit as shown in figure 1.
Process 1 : In the circuit the switch S is closed at t = 0 and the capacitor is fully charged to voltage V₀ (i.e., charging continues for time T >> RC). In the process some dissipation (E_D) occurs across the resistance R. The amount of energy finally stored in the fully charged capacitor is E_C.
Process 2 : In a different process the voltage is first set to  and maintained for a charging time T >> RC. Then the voltage is raised to   without discharging the capacitor and again maintained for a time T >> RC. The process is repeated one more time by raising the voltage to V0 and the capacitor is charged to the same final voltage V₀ as in Process 1. These two processes are depicted in Figure 2.

Q. In Process 1, the energy stored in the capacitor EC and heat dissipated across resistance ED are related by :-

PARAGRAPH–1
Consider a simple RC circuit as shown in figure 1.
Process 1 : In the circuit the switch S is closed at t = 0 and the capacitor is fully charged to voltage V₀ (i.e., charging continues for time T >> RC). In the process some dissipation (E_D) occurs across the resistance R. The amount of energy finally stored in the fully charged capacitor is E_C.
Process 2 : In a different process the voltage is first set to  and maintained for a charging time T >> RC. Then the voltage is raised to   without discharging the capacitor and again maintained for a time T >> RC. The process is repeated one more time by raising the voltage to V0 and the capacitor is charged to the same final voltage V₀ as in Process 1. These two processes are depicted in Figure 2.

Q. In Process 2, total energy dissipated across the resistance E_D is :-

PARAGRAPH -2
One twirls a circular ring (of mass M and radius R) near the tip of one's finger as shown in Figure 1. In the process the finger never loses contact with the inner rim of the ring. The finger traces out the surface of a cone, shown by the dotted line. The radius of the path traced out by the point where the ring and the finger is in contact is r. The finger rotates with an angular velocity w0. The rotating ring rolls without slipping on the outside of a smaller circle described by the point where the ring and the finger is in contact (Figure 2). The coefficient of friction between the ring and the finger is µ and the acceleration due to gravity is g.

Q. The total kinetic energy of the ring is :-

PARAGRAPH -2
One twirls a circular ring (of mass M and radius R) near the tip of one's finger as shown in Figure 1. In the process the finger never loses contact with the inner rim of the ring. The finger traces out the surface of a cone, shown by the dotted line. The radius of the path traced out by the point where the ring and the finger is in contact is r. The finger rotates with an angular velocity w0. The rotating ring rolls without slipping on the outside of a smaller circle described by the point where the ring and the finger is in contact (Figure 2). The coefficient of friction between the ring and the finger is µ and the acceleration due to gravity is g.

Q.

The minimum value of w₀ below which the ring will drop down is :-

Which of the following combination will produce H₂ gas ?

Pure water freezes at 273 K and 1 bar. The addition of 34.5 g of ethanol to 500 g of water changes the freezing point of the solution. Use the freezing point depression constant of water as 2 K kg mol^–1. The figures shown below represents plots of vapour pressure (V.P.) versus temperature (T).
[Molecular weight of ethanol is 46 g mol^–1]

Among the following, the option representing change in the freezing point is -

The order of the oxidation state of the phosphorus atom in H₃PO₂ , H₃PO₄ , H₃PO₃ and H₄P₂O₆ is

The standard state Gibbs free energies of formation of C(graphite) and C(diamond) at T = 298 K are
Δ_fG° [C(graphite)] = 0 kJ mol ^-1
Δ_fG° [C(diamond)] = 2.9 kJ mol ^-1

The standard state means that the pressure should be 1 bar , and substance should be pure at a given temperature. The conversion of graphite [C(graphite)] to diamond [C(diamond)]  reduces its volume by 2 × 10^-6 m³ mol^-1. If C(graphite) is converted to C(diamond) isothermally at T = 298 K, the pressure at which C(graphite) is in equilibrium with C(diamond), is

[Useful information : 1 J = 1 kg m² s^–2 ; 1 Pa = 1 kg m^–1 s^–2 ; 1 bar = 10⁵ Pa]

The major product of the following reaction is 

The order of basicity among the following compounds is

For the following cell : 

Zn(s) | ZnSO₄ (aq.) || CuSO₄ (aq.) | Cu(s)
when the concentration of Z n²⁺ is 10 times the concentration of Cu²⁺ , the expression for ΔG ( in J mol^–1) is [F is Faraday constant , R is gas constant, T is temperature , Eº(cell) = 1.1V]

In a bimolecular reaction, the steric factor P was experimentally determined to be 4.5. The correct option(s) among the following is(are):

Compound P and R upon ozonolysis produce Q and S, respectively. The molecular formula of Q and S is C₈H₈O. Q undergoes Cannizzaro reaction but not haloform reaction, whereas S undergoes haloform reaction but not Cannizzaro reaction.

(i) 

(ii) 

The option(s) with suitable combination of P and R, respectively, is(are)

For a reaction taking place in a container in equilibrium with its surroundings, the effect of temperature on its equilibrium constant K in terms of change in entropy is described by

The option(s) with only amphoteric oxides is (are):

Among the following, the correct statement(s) is are

The correct statement(s) about surface properties is (are)

For the following compounds, the correct statement(s) with respect of nucleophilic substitution reactions is(are); 

Upon heating KClO₃ in the presence of catalytic amount of MnO₂, a gas W is formed. Excess amount of W reacts with white phosphorus to give X. The reaction of X with pure HNO₃ gives Y and Z.

Q. W and X are, respectively

Upon heating KClO₃ in the presence of catalytic amount of MnO₂, a gas W is formed. Excess amount of W reacts with white phosphorus to give X. The reaction of X with pure HNO₃ gives Y and Z.

Q. Y and Z are , respectively

The reaction of compound P with CH₃MgBr (excess) in (C₂H₅)₂O followed by addition of H₂O gives Q, The compound Q on treatment with H₂SO₄ at 0ºC gives R. The reaction of R with CH₃COCl in the presence of anhydrous AlCl₃ in CH₂Cl₂ f ollowed by treatment with H₂O produces compounds S. [Et it compounds P is ethyl group ]

Q.

The reactions, Q to R and S to S, are -

The reaction of compound P with CH₃MgBr (excess) in (C₂H₅)₂O followed by addition of H₂O gives Q, The compound Q on treatment with H₂SO₄ at 0ºC gives R. The reaction of R with CH₃COCl in the presence of anhydrous AlCl₃ in CH₂Cl₂ f ollowed by treatment with H₂O produces compounds S. [Et it compounds P is ethyl group]

Q. The product S is -

Three randomly chosen non negative int egers x, y and z are found to satisfy the equat ion x + y + z = 10. Then the probability that z is even, is

Let S = {1, 2, 3,.....,9}. For k = 1,2, ....., 5, let Nk be the number of subsets of S, each containing five elements out of which exactly k are odd. Then N₁ + N₂ + N₃ + N₅  =

If ƒ :R → R is a twice differentiable function such that f''(x) > 0 for all x ∈ R, and  then

If y = y(x) satisfies the differential equation and y(0) = then y(256) = 

How many 3 × 3 matrices M with entries from {0,1,2} are there, for which the sum of the diagonal entries of M^TM is 5 ?

Let O be the or igin and let PQR be an arbitrary triangl e. The point S issu ch that Then the triangle PQR has S as its 

The equation of the plane passing through the point (1,1,1) and perpendicular to the planes 2x + y – 2z = 5 and 3x – 6y – 2z = 7, is

If ƒ : R → R is a differentiable function such that f"(x) > 2f(x) for all x ∈ R, and f(0) = 1, then

If f(x) =  then

Let a and b be nonzero real numbers such that 2(cosβ - cosα) + cosα cosβ = 1. Then which of the following is/are true ?

If g(x) = 

If the line x = a divides the area of region R = [(x, y) ∈  x³ < y < x, 0 < x < 1} into two equal parts, then

Let f(x) =  Then

Let O be the origin, and    be three unit vectors in the directions of the sides   respectively, of a triangle PQR.

Q. 

Let O be the origin, and    be three unit vectors in the directions of the sides   respectively, of a triangle PQR.

Q. If the triangle PQR varies, then the minimum value of cos(P + Q) + cos(Q + R) + cos(R + P) is

Let p,q be integers and let α, β be the roots of the equation, x² - x - 1 = 0, where α ≠ β. For n = 0,1,2, ........, let a_n = pαⁿ + qβⁿ.
FACT : If a and b are rational numbers and   then a = 0 = b.
Q. If a₄ = 28, then p + 2q =

Let p,q be integers and let α, β be the roots of the equation, x² - x - 1 = 0, where α ≠ β. For n = 0,1,2, ........, let a_n = pαⁿ + qβⁿ.
FACT : If a and b are rational numbers and   then a = 0 = b.

Q. a₁₂ =