A current carrying wire heats a metal rod. The wire provides a constant power (P) to the rod. The metal rod is enclosed in an insulated container. It is observed that the temperature (T) in the metal rod changes with time (t) as:
T(t) = T0 (1 + βt1/4)
where β is a constant with appropriate dimension while T0 is a constant with dimension of temperature. The heat capacity of the metal is:
A thin spherical insulating shell of radius R carries a uniformly distributed charge such that the potential at its surface is V0. A hole with a small area α4πR2 (α<<1) is made on the shell without affecting the rest of the shell. Which one of the following statements is correct?
Let charge on the sphere initially be Q.
∴
and charge removed = αQ
Consider a spherical gaseous cloud of mass density ρ(r) in free space where r is the radial distance from its center. The gaseous cloud is made of particles of equal mass m moving in circular orbits about the common center with the same kinetic energy K. The force acting on the particles is their mutual gravitational force. If ρ(r) is constant in time, the particle number density n(r) = ρ(r)/m is :
[G is universal gravitational constant]
Let total mass included in a sphere of radius r be M.
For a particle of mass m,
In a radioactive sample, nuclei either decay into stable
nuclei with decay constant 4.5 × 10–10 per year or into stable
nuclei with decay constant 0.5 × 10–10 per year. Given that in this sample all the stable
nuclei are produced by the
nuclei only. In time t × 109 years, if the ratio of the sum of stable
nuclei to the radioactive
nuclei is 99, the value of t will be: [Given ln 10 = 2.3]
Parallel radioactive decay
One mole of a monoatomic ideal gas goes through a thermodynamic cycle, as shown in the volume versus temperature (V - T) diagram. The correct statement(s) is/are:
[R is the gas constant]
From graph
In the circuit shown, initially, there is no charge on capacitors and keys S1 and S2 are open. The values of the capacitors are C1 = 10 μF, C2 = 30 μF and C3 = C4 = 80 μF.
Which of the statement(s) is/are correct?
(1) at t = 0, capacitor C1 acts as a battery of 4V, C4 & C3 of 1/2 V each, C2 is shorted Circuit is
(2) and (4)
At steady state,
When capacitor is fully charged it behave as open circuit and current through it zero.
Hence, Charge on each capacitor is same.
Now,
(3) At t = 0, S1 is closed, capacitor act as short circuit.
A thin convex lens is made of two materials with refractive indices n1 and n2, as shown in figure. The radius of curvature of the left and right spherical surfaces are equal. f is the focal length of the lens when n1 = n2 = n. The focal length is f + Δf when n1 = n and n2 = n + Δn. Assuming Δn << (n–1) and 1 < n < 2, the correct statement(s) is/are:
when n1 = n2 = n
...(1)
2nd case:
...(2)
(1) Relation between is independent of R so (1) is correct.
(2) 2n – 2 < n because n < 2
Let us consider a system of units in which mass and angular momentum are dimensionless. If length has dimension of L, which of the following statement (s) is/are correct?
Mass = M0L0T0
L2 = T1 ...(1)
= M0L2L–4 (In new system from equation (1))
= L-2
A cylindrical capillary tube of 0.2 mm radius is made by joining two capillaries T1 and T2 of different materials having water contact angles of 0° and 60°, respectively. The capillary tube is dipped vertically in water in two different configurations, case I and II as shown in figure. Which of the following option(s) is(are) correct?
(Surface tension of water = 0.075 N/m, density of water = 1000 kg/m3, take g = 10 m/s2)
⇒ h1 = 75 mm (in T1) [If we assume entire tube of T1]
⇒ mm (in T2) [If we assume entire tube of T2]
Option (1): Since contact angles are different so correction in the height of water column raised in the tube will be different in both the cases, so option (1) is correct
Option (2): If joint is 5 cm is above water surface, then let's say water crosses the joint by height h, then:
⇒ h = –ve, not possible, so liquid will not cross the interface, but angle of contact at the interface will change, to balance the pressure,
So option (2) is wrong.
Option (3): If interface is 8 cm above water then water will not even reach the interface, and water will rise till 7.5 cm only in T1, so option (3) is right.
Option (4): If interface is 5 cm above the water in vessel, then water in capillary will not even reach the interface. Water will reach only till 3.75 cm, so option (4) is right.
Two identical moving coil galvanometer have 10 Ω resistance and full scale deflection at 2 µA current. One of them is converted into a voltmeter of 100 mV full scale reading and the other into an Ammeter of 1 mA full scale current using appropriate resistors. These are then used to measure the voltage and current in the Ohm's law experiment with R = 1000 Ω resistor by using an ideal cell. Which of the following statement(s) is/are correct?
A charged shell of radius R carries a total charge Q. Given φ as the flux of electric field through a closed cylindrical surface of height h, radius r and with its center same as that of the shell. Here, center of the cylinder is a point on the axis of the cylinder which is equidistant from its top and bottom surfaces. Which of the following option(s) is/are correct ? [∈0 is the permittivity of free space]
For option (1), cylinder encloses the shell, thus option is correct
For option (2),
cylinder perfectly enclosed by shell,
thus φ = 0, so option is correct.
For option (3)
For option (4) :
Flux enclosed by cylinder
A conducting wire of parabolic shape, initially y = x2, is moving with velocity in a non-uniform magnetic field
as shown in figure. If V0, B0, L and β are positive constants and Δφ is the potential difference developed between the ends of the wire, then the correct statement(s) is/are:
y = x2
Δφ will be same if the wire is repalced by the straight wire of length √2L and y = x
∵ range of y remains same
∴ option 1 is correct.
A block of weight 100 N is suspended by copper and steel wires of same cross sectional area 0.5 cm2 and, length √3 m and 1 m, respectively. Their other ends are fixed on a ceiling as shown in figure. The angles subtended by copper and steel wires with ceiling are 30° and 60°, respectively. If elongation in copper wire is (ΔlC) and elongation in steel wire is (Δls), then the ratio is _____.
[Young's modulus for copper and steel are 1 × 1011 N/m2 and 2 × 1011 N/m2 respectively]
Let TS = tension in steel wire
TC = Tension in copper wire
in x direction
in y direction
Solving equation (i) & (ii)
We know
On solving above equation
A planar structure of length L and width W is made of two different optical media of refractive indices n1 = 1.5 and n2 = 1.44 as shown in figure. If L >> W, a ray entering from end AB will emerge from end CD only if the total internal reflection condition is met inside the structure. For L = 9.6 m, if the incident angle θ is varied, the maximum time taken by a ray to exit the plane CD is t × 10–9 s, where t is ____. [Speed of light c = 3 × 108 m/s]
For maximum time the ray of light must undergo TIR at all surfaces at minimum angle i.e. θC
For TIR n1sinθC = n2
where L = length of tube, D = length of path of light
Time taken by light
A particle is moved along a path AB-BC-CD-DE-EF-FA, as shown in figure, in presence of a force where x and y are in meter and α = –1 N/m–1. The work done on the particle by this force
will be ____ Joule.
Similarly,
WBC = 1J
WCD = 0.25J
WDE = 0.5 J
WEF = WFA = 0 J
∴ New work in cycle = 0.75 J
A parallel plate capacitor of capacitance C has spacing d between two plates having area A. The region between the plates is filled with N dielectric layers, parallel to its plates, each with thickness δ = d/N. The dielectric constant of the mth layer is For a very large N (> 103), the capacitance C is
The value of α will be _____.
[∈0 is the permittivity of free space]
A train S1, moving with a uniform velocity of 108 km/h, approaches another train S2 standing on a platform.
An observer O moves with a uniform velocity of 36 km/h towards S2, as shown in figure. Both the trains are blowing whistles of same frequency 120 Hz. When O is 600 m away from S2 and distance between S1 and S2 is 800 m, the number of beats heard by O is ____.
[Speed of the sound = 330 m/s]
Frequency observed by O from S2
frequency observed by O from S1
beat frequency = 131.76 – 123.63 = 8.128 ≈ 8.12 to 8.13 Hz
A liquid at 30°C is poured very slowly into a Calorimeter that is at temperature of 110°C. The boiling temperature of the liquid is 80°C. It is found that the first 5 gm of the liquid completely evaporates. After pouring another 80 gm of the liquid the equilibrium temperature is found to be 50°C. The ratio of the Latent heat of the liquid to its specific heat will be ______ °C.
[Neglect the heat exchange with surrounding]
Let m = mass of calorimeter,
x = specific heat of calorimeter
s = specific heat of liquid
L = latent heat of liquid
First 5 g of liquid at 30° is poured to calorimeter at 110°C
∴ m × x × (110 – 80) = 5 × s × (80 × 30) + 5 L
⇒ mx × 30 = 250 s + 5 L ... (i)
Now, 80 g of liquid at 30° is poured into calorimeter at 80°C, the equilibrium temperature reaches to 50°C.
Molar conductivity (∧m) of aqueous solution of sodium stearate, which behaves as a strong electrolyte, is recorded at varying concentrations (c) of sodium stearate. Which one of the following plots provides the correct representation of micelle formation in the solution?
(Critical micelle concentration (CMC) is marked with an arrow in the figures.)
The correct order of acid strength of the following carboxylic acids is -
I > II > III > IV
Calamine, malachite, magnetite and cryolite, respectively are
So correct answer is option(2)
The green colour produced in the borax bead test of a chromium(III) salt is due to -
Fusion of MnO2 with KOH in presence of O2 produces a salt W. Alkaline solution of W upon electrolytic oxidation yields another salt X. The manganese containing ions present in W and X, respectively, are Y and Z. Correct statement(s) is (are)
∵ In acidic solution; Y undergoes disproportionation reaction
Which of the following statement(s) is (are) correct regarding the root mean square speed (Urms) and average translational kinetic energy (εav) of a molecule in a gas at equilibrium?
In the decay sequence:
x1, x2, x3 and x4 are particles/ radiation emitted by the respective isotopes. The correct option(s) is/are
U and Z are isotopes
Which of the following statement(s) is(are) true?
(2) TRUE: Six member hemiacetal on anomeric carbon gives α-D glucose & β-D glucose.
(3) TRUE:
(4) TRUE: Monosaccharide cannot be hydrolysed to give polyhydroxy aldehydes and ketones
A tin chloride Q undergoes the following reactions (not balanced)
X is a monoanion having pyramidal geometry. Both Y and Z are neutral compounds. Choose the correct option(s).
Choose the correct option(s) for the following set of reactions
Each of the following options contains a set of four molecules. Identify the option(s) where all four molecules possess permanent dipole moment at room temperature.
Polar molecule
Non-polar molecule
So correct answer is option (2) and (4)
Choose the reaction(s) from the following options, for which the standard enthalpy of reaction is equal to the standard enthalpy of formation.
Enthalpy of formation is defined as enthalpy change for formation of 1 mole of substance from its elements, present in their natural most stable form.
For the following reaction, the equilibrium constant Kc at 298 K is 1.6 × 1017.
When equal volumes of 0.06 M Fe2+(aq) and 0.2 M S2–(aq) solutions are mixed, the equilibrium concentration of Fe2+(aq) is found to be Y × 10–17 M. The value of Y is ––––––––
y = 8.93
Among B2H6, B3N3H6, N2O, N2O4, H2S2O3 and H2S2O8, the total number of molecules containing covalent bond between two atoms of the same kind is ––––––––
So correct answer is 4
Consider the kinetic data given in the following table for the reaction A + B + C → Product.
The rate of the reaction for [A] = 0.15 mol dm–3, [B] = 0.25 mol dm–3 and [C] = 0.15 mol dm–3 is found to be Y × 10–5 mol dm–3 s–1. The value of Y is ––––––––
r = K[A]n1 [B]n2 [C]n3
From table
n1 = 1
n2 = 0
n3 = 1
r = K[A] [C]
From Exp-1
On dissolving 0.5 g of a non-volatile non-ionic solute to 39 g of benzene, its vapor pressure decreases from 650 mm Hg to 640 mm Hg. The depression of freezing point of benzene (in K) upon addition of the solute is _____
(Given data: Molar mass and the molal freezing point depression constant of benzene are 78 g mol–1 and 5.12 K kg mol–1, respectively)
Scheme 1 and 2 describe the conversion of P to Q and R to S, respectively. Scheme 3 describes the synthesis of T from Q and S. The total number of Br atoms in a molecule of T is ________
Scheme 1:
Scheme 2:
Scheme 3:
Scheme 1:
Scheme 2:
Scheme 3:
At 143 K. the reaction of XeF4 with O2F2 produces a xenon compound Y. The total number of lone pair(s) of electrons present on the whole molecule of Y is ______
Y has 3 lone pair of electron in each fluorine and one lone pair of electron in xenon.
Hence total lone pairs of electrons is 19.
Let
where α = α(β) and β = β(θ) are real number, and I is the 2 × 2 identity matrix. If
α* is the minimum of the set {α(θ) : θ ∈ [0, 2π)} and
β* is the minimum of the set {β(θ) : θ ∈ [0, 2π),
then the value of α* + β* is
Given M = αI + βM–1
⇒ M2 – αM – βI = O
By putting values of M and M2, we get
⇒
A line y = mx + 1 intersects the circle (x – 3)2 + (y + 2)2 = 25 at the points P and Q. If the midpoint of the line segment PQ has x-coordinate -3/5, then which one of the following options is correct?
⇒ m2 – 5m + 6 = 0
⇒ m = 2, 3
Let S be the set of all complex numbers z satisfying |z - 2 + i| ≥ √5. If the complex number z0 is such that is the maximum of the set
then the principal argument of
= arg(–ki) ; k > 0 (as Rez0 < 2 & Imz0 > 0)
= - π/2
The area of the region {(x, y): xy ≤ 8, 1 ≤ y ≤ x2} is
For intersection,8/y = √y ⇒ y = 4
Hence, required area =
There are three bags B1, B2 and B3. The bag B1 contains 5 red and 5 green balls, B2 contains 3 red and 5 green balls, and B3 contains 5 red and 3 green balls, Bags B1, B2 and B3 have probabilities respectively of being chosen. A bag is selected at random and a ball is chosen at random from the bag. Then which of the following options is/are correct?
Define the collections {E1, E2, E3, .....} of ellipses and {R1, R2, R3, .....} of rectangles as follows:
R1: rectangle of largest area, with sides parallel to the axes, inscribed in E1 ;
En: ellipse of largest area inscribed in
Rn: rectangle of largest area, with sides parallel to the axes, inscribed in En, n > 1.
Then which of the following options is/are correct?
Area of R1 = 3sin2θ ; for this to be maximum
Hence for subsequent areas of rectangles Rn to be maximum the coordinates will be in GP with common ratio
Eccentricity of all the ellipses will be same
Distance of a focus from the centre in
Length of latus rectum of
Let where a and b are real numbers. Which of the following options is/are correct?
(adjM)11 = 2 – 3b = –1 ⇒ b = 1
Also, (adjM)22 = –3a = –6 ⇒ a = 2
⇒ (α, β, γ) = (1, –1, 1)
Let ƒ: be given by
Then which of the following options is/are correct?
For x ≥ 3, ƒ(x) is again continuous and
⇒
Hence, range of ƒ(x) is
Hence ƒ' has a local maximum at x = 1 and ƒ' is NOT differentiable at x = 1.
Let α and β be the roots of x2 – x – 1 = 0, with α > β. For all positive integers n, define
Then which of the following options is/are correct?
α, β are roots of x2 – x –1
Let denote a curve y = y(x) which is in the first quadrant and let the point (1, 0) lie on it. Let the tangent to
at a point P intersect the y-axis at YP. If PYP has length 1 for each point P on T, then which of the following options is/are correct?
Y – y = y'(X – x)
So,YP = (0, y – xy')
So,
[dy/dx can not be positive i.e. ƒ(x) can not be increasing in first quadrant, for x ∈ (0, 1)]
Hence,
In a non-right-angled triangle ΔPQR, let p, q, r denote the lengths of the sides opposite to the angles at P, Q, R respectively. The median from R meets the side PQ at S, the perpendicular from P meets the side QR at E, and RS and PE intersect at O. If p = √3, q = 1, and the radius of the circumcircle of the ΔPQR equals 1, then which of the following options is/are correct?
Let L1 and L2 denotes the lines
respectively. If L3 is a line which is perpendicular to both L1 and L2 and cuts both of them, then which of the following options describe(s) L3?
Points on L1 and L2 are respectively A(1 – λ, 2λ, 2λ) and B(2µ, –µ, 2µ)
and vector along their shortest distance
If
then 27I2 equals _____
⇒
Let the point B be the reflection of the point A(2, 3) with respect to the line 8x – 6y – 23 = 0. Let and
be circles of radii 2 and 1 with centres A and B respectively. Let T be a common tangent to the circles
and
such that both the circles are on the same side of T. If C is the point of intersection of T and the line passing through A and B, then the length of the line segment AC is _____
Distance of point A from given line = 5/2
⇒ AC = 2 x 5 = 10
Let AP (a; d) denote the set of all the terms of an infinite arithmetic progression with first term a and common difference d > 0. If AP(1; 3) ∩ AP(2; 5) ∩ AP(3; 7) = AP(a; d) then a + d equals ___
We equate the general terms of three respective
Let S be the sample space of all 3 × 3 matrices with entries from the set {0, 1}. Let the events E1 and E2 be given by
E1 = {A ∈ S : det A = 0} and
E2 = {A ∈ S : sum of entries of A is 7}.
If a matrix is chosen at random from S, then the conditional probability P(E1|E2) equals ____
n(E2) = 9C2 (as exactly two cyphers are there)
Now, det A = 0, when two cyphers are in the same column or same row
Hence,
Three lines are given by
Let the lines cut the plane x + y + z = 1 at the points A, B and C respectively. If the area of the triangle ABC is Δ then the value of (6Δ)2 equals ___
Let ω ≠ 1 be a cube root of unity. Then the minimum of the set { |a + bω + cω2|2 : a, b, c distinct non-zero integers} equals __
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