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QUESTION: 1

A block of mass m is connected at one end of spring fixed at other end having natural length l0 and spring constant K. The block is rotated with constant angular speed (ω) about the fixed end in gravity free space. The elongation in spring is-

Solution:

QUESTION: 2

3 point charges are placed on circumference of a circle of radius 'd' as shown in figure. The electric field along x-axis at centre of circle is:

Solution:

QUESTION: 3

Choose the correct P-V graph of ideal gas for given V-T graph.

Solution:

QUESTION: 4

Find the coordinates of centre of mass of the lamina, shown in figure.

Solution:

QUESTION: 5

Which graph correctly represents v ariation between relaxation time of gas molecules with absolute temperature (T) of an ideal gas.

Solution:

QUESTION: 6

If two capacitors C_{1} & C_{2} are connected in parallel then equivalent capacitance is 10μF. If both capacitor are connected across 1V battery then energy stored by C_{2} is 4 times that of C_{1}. Then the equivalent capacitance if they are connected in series is -

Solution:

Given C_{1} + C_{2 }= 10μF ........ (i)

⇒ 4C_{1} = C_{2} …(ii)

from equation (i) & (ii)

C_{1} = 2μF

C_{2} = 8μF

If they are in series

QUESTION: 7

A rod of mass 4m and length L is hinged at the mid point. A ball of mass 'm' moving with speed V in the plane of rod which is perpendicular to axis of rotation, strikes at one end at an angle of 45º and sticks to it. The angular velocity of system after collision is–

Solution:

L_{oi} = L_{of}

QUESTION: 8

Two photons of energy 4eV and 4.5eV are incident on two metals A and B respectively. Maximum kinetic energy for ejected electron is T_{A} for A and T_{B }= T_{A} – 1.5eV for metal B. Relation between de-Broglie wavelengths of ejected electron of A and B are λ_{B} = 2λ_{A}. The work function of metal B is -

Solution:

Relation between De-Broglie wav elength and K.E. is

⇒ T_{A} = 2 eV

∴ KE_{B} = 2 – 1.5 = 0.5 eV

φ_{B} = 4.5 - 0.5 = 4 eV

QUESTION: 9

There is a potentiometer wire of length 1200 cm and 60 mA current is flowing in it. A battery of emf 5V and internal resistance of 20Ω is balanced on potentiometer wire with balancing length 1000 cm. The resistance of potentiometer wire is–

Solution:

Potential gradient = 5 / 1000 = V_{p}/1200

VP = 6V

and RP = = 100Ω

QUESTION: 10

A telescope has magnifying power 5 and length of tube is 60cm then the focal length of eye piece is–

Solution:

m = f_{o}/f_{e}

5 = f_{o}/f_{e}

f_{o} = 5f_{e}

f_{o} + f_{e} = 60

6f_{e} = 60

f_{e} = 10

QUESTION: 11

Two spherical bodies of mass m_{1} and m_{2} have radii 1 m and 2 m respectively. The gravitational field of the two bodies with the radial distance from centre is shown below. The value of is-

Solution:

QUESTION: 12

When a proton of KE = 1.0 MeV moving in South to North direction enters the magnetic field (from West to East direction), it accelerates with acceleration a = 10^{12} m/s^{2}. The magnitude of magnetic field is–

Solution:

∴ Bqv = ma

= 0.71× 10^{–3}T

So, 0.71 mT

QUESTION: 13

If electric field around a surface is given by where 'A' is the normal area of surface and Q_{in} is the charge enclosed by the surface. This relation of gauss's law is valid when

Solution:

Magnitude of electric field is constant & the surface is equipotential

QUESTION: 14

Stopping potential depends on Planks constant (h), current (I), Universal gravitational constant (G) and speed of light (C). Choose the correct option for the dimension of stopping potential (V)

Solution:

V = K (h)^{a}(I)^{b}(G)^{c}(C)^{d} (V is voltage)

we know [h] = ML^{2}T^{-1}

a – c = 1………………(1)

2a + 3c + d = 2………………(2)

–a –2c –d = –3 ………………(3)

b = –1………………(4)

on solving

c = –1

a = 0

d = 5,

b = –1

V = K (h)° (I)^{-1}(G)^{-1}(C)^{5}

QUESTION: 15

A cylinder of height 1m is floating in water at 0°C with 20 cm height in air. Now temperature of water is raised to 4°C, height of cylinder in air becomes 21cm. The ratio of density of water at 4°C to density of water at 0°C is– (Consider expansion of cylinder is negligible)

Solution:

mg = A(80) ρ_{0}_{º}_{c }g

mg = A(79) ρ_{4}_{º}_{c }g

QUESTION: 16

Number N of the α-particles deflected in Rutherford's α-scattering experiment varies with the angle of deflection θ. Then the graph between the two is best represented by.

Solution:

QUESTION: 17

If relative permittivity and relative permeability of a medium are 3 and 4/3 respectively. The critical angle for this medium is.

Solution:

QUESTION: 18

The given loop is kept in a uniform magnetic field perpendicular to plane of loop. The field changes from 1000G to 500G in 5seconds. The average induced emf in loop is–

Solution:

QUESTION: 19

Choose the correct Boolean expression for the given circuit diagram:

Solution:

First part of figure shown is OR gate and Second part of figure shown is NOT gate

So Y_{p} = OR + NOT = NOR gate

QUESTION: 20

A solid sphere of density just floats in a liquid. The density of liquid is –

(r is distance from centre of sphere)

Solution:

0 < r ≤ R

mg = B

*Answer can only contain numeric values

QUESTION: 21

Two particles each of mass 0.10kg are moving with velocities 3m/s along x-axis and 5m/s along y-axis respectively. After an elastic collision one of the mass moves with a velocity . The energy of other particle after collision is x/10 , then x is.

Solution:

For elastic collision KE_{i} = KE_{f}

34 = 32 + v^{2}

x = 1

*Answer can only contain numeric values

QUESTION: 22

A plano-convex lens of radius of curvature 30 cm made of refractive index 1.5 is kept in air. Find its focal length (in cm).

Solution:

R_{1} = ∝

R_{2} = –30 cm

f = 60 cm

*Answer can only contain numeric values

QUESTION: 23

Position of two particles A and B as a function of time are given by X_{A} = – 3t^{2} + 8t + c and Y_{B} = 10 – 8t^{3}. The velocity of B with respect to A at t = 1 is √v . Find v.

Solution:

= 580

*Answer can only contain numeric values

QUESTION: 24

An open organ pipe of length 1m contains an ideal gas whose density is twice the density of atmosphere at STP. Find the difference between fundamental and second harmonic frequencies if speed of sound in atmosphere is 300 m/s.

Solution:

*Answer can only contain numeric values

QUESTION: 25

Four resistors of 15Ω, 12Ω, 4Ω and 10Ω are arranged in cyclic order to form a wheatstone bridge. What resistance (in Ω) should be connected in parallel across the 10Ω resistor to balance the wheatstone bridge.

Solution:

= 15 × 4

on solving

R = 10 Ω

QUESTION: 26

Number of S–O bond in S_{2}O_{8}^{2–} and number of S–S bond in Rhombic sulphur are respectively:

Solution:

QUESTION: 27

Following vanderwaal forces are present in ethyl acetate liquid

Solution:

Ethyl acetate is polar molecule so dipole-dipole interaction will be present there.

*Multiple options can be correct

QUESTION: 28

Given, for H-atom

Select the correct options regarding this formula for Balmer series.

Solution:

**Correct Answer : a,c**

**Explanation :** (a) For balmer series always started ground state n 1 = 2

(c) At the longest wavelength, the higher state energy will be minimum therefore the excited state will be n2 = 3 next to the ground always.

QUESTION: 29

Correct order of first ionization energy of the following metals Na, Mg, Al, Si in KJ mol^{-1} respectively are:

Solution:

The electronic configurations are as follows:

_{11}Na [Ne]3s^{1}, _{12}Mg [Ne]3s^{2}, _{13}Al [Ne] 3s^{2}3p^{1}, _{14}Si [Ne]3s^{2}3p^{2}

The ionization energy of Mg will be larger than that of Na due to fully filled configuration [Ne] 3s^{2}

The ionization of Al will be smaller than that of Mg due to one electron extra than the stable configuration but smaller than Si due to the increase in effective nuclear charge of Si.

⇒ Na < Mg > Al < S

QUESTION: 30

Select the correct stoichiometry and its k_{sp} value according to given graphs.

Solution:

K_{sp} = [X^{+}] [Y^{–}]

or K_{sp} = 2 × 10^{–3} × 10^{–3}

or K_{sp} = 2 × 10^{–6}

QUESTION: 31

According to Hardy Schultz rule, correct order of flocculation value for Fe(OH)_{3} sol is :

Solution:

According to hardy-schultz rule,

Coagulation value or flocculation value

QUESTION: 32

Which of the following complex exhibit facial meridional geometrical isomerism.

Solution:

[Ma_{3}b_{3}] type complex shows facial and meridional isomerism

QUESTION: 33

(A) Intermolecular force of attraction of X > Y.

(B) Intermolecular force of attraction of X < Y.

(C) Intermolecular force of attraction of Z < X.

Select the correct option(s).

Solution:

At a particular temperature as intermolecular force of attraction increases vapour pressure decreases.

QUESTION: 34

Rate of a reaction increases by 10^{6 }times when a reaction is carried out in presence of enzyme catalyst at same temperature. Determine change in activation energy.

Solution:

or 6 ln 10 = (E - E_{c} ) / RT

or

or E–EC = 2.303 × 6RT

or

=

QUESTION: 35

Gypsum on heating at 393K produces

Solution:

Theory based.

QUESTION: 36

Among the following least 3^{rd} ionization energy is for

Solution:

QUESTION: 37

Accurate measurement of concentration of NaOH can be performed by following titration:

Solution:

Oxalic acid is a primary standard solution while H_{2}SO_{4} is a secondary standard solution.

QUESTION: 38

Arrange the following compounds in order of dehydrohalogenation (E1) reaction.

(A) (B) (C) (D)

Solution:

E1 reaction proceeds via carbocation formation, therefore greater the stability of carbocation, faster the E1 reaction.

QUESTION: 39

Product A and B are respectively :

Solution:

[A] is more stable radical and undergoes Markovnikov addition to form [B].

QUESTION: 40

Major product in the following reaction is

Solution:

QUESTION: 41

Arrange the order of C—OH bond length of the following compounds.

Solution:

CH_{3}–OH

A B C

There is not any resonance in CH_{3}–OH. Resonance is poor in p-Ethoxyphenol than phenol

QUESTION: 42

Which of the following are "green house gases"?

(a) CO_{2 }

(b) O_{2 }

(c) O_{3}

(d) CFC

(e) H_{2}O

Solution:

CO_{2}, O_{3}, H_{2}O vapours and CFC's are green house gases.

QUESTION: 43

Two liquids isohexane and 3-methylpentane has boiling point 60°C and 63°C. They can be separated by

Solution:

Liquid having lower boiling point comes out first in fractional distillation. Simple distillation can't be used as boiling point difference is very small.

QUESTION: 44

Which of the given statement is incorrect about glucose?

Solution:

Open chain form of glucose is very very small, hence does not gives Schiff's test.

QUESTION: 45

Reagent used for the given conversion is:

Solution:

B_{2}H_{6} is very selective and usually used to reduce acid to alcohol.

*Answer can only contain numeric values

QUESTION: 46

0.3 g [ML_{6}]Cl_{3} of molar mass 267.46 g/mol is reacted with 0.125 M AgNO_{3}(aq) solution, calculate volume of AgNO_{3} required in ml.

Solution:

*Answer can only contain numeric values

QUESTION: 47

Given : 2H_{2}O → O_{2} + 4H** ^{+}** + 4e

Eº = –1.23 V Calculate electrode potential at pH = 5.

Solution:

*Answer can only contain numeric values

QUESTION: 48

Calculated the mass of FeSO_{4}.7H_{2}O, which must be added in 100 kg of wheat to get 10 PPM of Fe.

Solution:

*Answer can only contain numeric values

QUESTION: 49

A gas undergoes expansion according to the following graph. Calculate work done by the gas.

Solution:

*Answer can only contain numeric values

QUESTION: 50

Number of chiral centres in Pencillin is

Solution:

Star marked atoms are chiral centers.

QUESTION: 51

If f(x) = g(x) = then find the area bounded by f(x) and g(x) from x = 1/2 to x =

Solution:

Required area = Area of trapezium ABCD –

QUESTION: 52

z is a complex number such that |Re(z)| + |Im (z)| = 4 then |z| can't be

Solution:

z = x + iy

|x| + |y| = 4

Minimum value of |z| = 2√2

Maximum value of |z| = 4

So |z| can't be √7

QUESTION: 53

If f(x) = and a – 2b + c = 1 then

Solution:

Apply R_{1} = R_{1} + R_{3} – 2R_{2}

⇒ f(x) = 1

⇒ f(50) = 1

QUESTION: 54

Let a_{n} is a positive term of a GP and

Solution:

Let GP is a, ar, ar^{2} ……..

= 200

................. (i)

................... (ii)

Form (1) and (2) r = 2

add both

⇒ a_{2} + a_{3} + ........... a_{200 }+ a_{201} = 300 ⇒ r(a_{1} +...........a_{200}) = 300

= 300/r

= 150

QUESTION: 55

If y(1) = 1 and y(x) = e then x = ?

Solution:

Put y = vx

When x = 1, y = 1 then

x^{2} = y^{2}(1 + 2lny)

x^{2} = e^{2}(3)

x = ± √3 e

So x = √3e

QUESTION: 56

Let probability distribution is then value of p(x > 2) is

Solution:

⇒ 6k^{2} + 5k = 1

6k^{2} + 5k – 1 = 0

6k^{2} + 6k – k – 1 = 0

(6k – 1) (k + 1) = 0 ⇒ k = - 1

(rejected) ; k = 1/6

P(x > 2) = k + 2k + 5k^{2}

QUESTION: 57

= λtanθ + 2log f(x) + c then ordered pair (λ,f(x)) is

Solution:

= – t + 2 log (1+t) + C

= –tanθ + 2 log (1 + tanθ) + C

⇒ λ = -1 and f(x) = 1 + tanθ

QUESTION: 58

If p → (p ∧ ~ q) is false. Truth value of p & q will be

Solution:

QUESTION: 59

If = A then the value of x at which f(x) = [x^{2}] sinπx is discontinuous

(where [.] denotes greatest integer function)

Solution:

4 – 0 = A check when

(A) x = ⇒ x = √5 ⇒ discontinuos

(B) x = ⇒ x = 5 ⇒ continuous

(C) x = √A ⇒ x = 2 ⇒ continuous

(D) x = ⇒ x = 3 ⇒ continuous

QUESTION: 60

Let one end of focal chord of parabola y^{2} = 8x is , then equation of tangent at other end of this focal chord is

Solution:

Let is (2t^{2}, 4t) ⇒ t = -1/2

Parameter of other end of focal chord is 2

⇒ point is (8, 8)

⇒ equation of tangent is 8y - 4(x+8) = 0

⇒ 2y - x = 8

QUESTION: 61

Let x + 6y = 8 is tangent to standard ellipse where minor axis is , then eccentricity of ellipse is

Solution:

,

Equation of tangent ≡ y = mx ±

comparing with ≡

m = -1/6 and a^{2}m^{2} + b^{2} = 16/9

a^{2} = 16

QUESTION: 62

if f(x) and g(x) are continuous functions, fog is identity function, g'(b) = 5 and g(b) = a then f'(a) is

Solution:

QUESTION: 63

If 7x + 6y – 2z = 0

3x + 4y + 2z = 0

x – 2y – 6z = 0

then which option is correct

Solution:

= 7(–20) – 6(–20) – 2(–10)

= – 140 + 120 + 20 = 0

so infinite non-trivial solution exist

now equation (1) + 3 equation (3)

10x – 20z = 0

x = 2z

QUESTION: 64

Let x = 2sinθ - sin2θ and y = 2 cosθ - cos2θ

find θ = π

Solution:

QUESTION: 65

g(x) = dt then correct choice is

Solution:

F'(x) = x^{2}g(x)

⇒ F'(1) = 1.g(1) = 0 ......(1)

(∵ g(1) = 0)

Now F''(x) = 2xg(x) + x^{2}g'(x)

QUESTION: 66

Let both root of equation ax^{2} – 2bx + 5 = 0 are α and root of equation x^{2} - 2bx - 10 = 0 are α and β. Find the value of α^{2} + β^{2}

Solution:

⇒ b^{2} = 5a ..... (i) (a ≠ 0)

α + β = 2b ............ (ii)

and αβ = – 10 ............. (iii)

is also root of x^{2} – 2bx – 10 = 0

⇒ b^{2} - 2ab^{2} - 10a^{2} = 0 by (i)

⇒ 5a – 10a^{2} – 10a^{2} = 0

⇒ 20a^{2} = 5a

⇒ a = 1/4 and b^{2} = 5/4

α^{2} = 20 and β^{2} = 5

Now α^{2} + β^{2}

= 5 + 20

= 25

QUESTION: 67

Let A = and B = then

Solution:

A = { x : x ∈ (-2, 2) }

B = { x : x ∈ (-∞, -1] ∪ [5, ∞) }

A ∩ B = { x : x ∈ (-2, -1] }

A ∪ B = { x : x ∈ (-∞, 2) ∪ [5, ∞) }

A - B = { x : x ∈ (-1, 2) }

B - A = { x : x ∈ (-∞, -2] ∪ [5, ∞) }

QUESTION: 68

Let x = and y = where θ ∈ (0,π/4), then

Solution:

y = 1 + cos^{2}θ + cos^{4}θ + .......

cos^{2}θ = x

y (1 – x) = 1

QUESTION: 69

Let the distance between plane passing through lines and = and plane 23x – 10y – 2z + 48 = 0 is then k is equal to

Solution:

Lines must be intersecting

distance of plane contains given lines from given plane is same as distance between point (–3, –2,1) from given plane.

Required distance equal to = = = k = 3

*Answer can only contain numeric values

QUESTION: 70

If ^{25}C_{0} + 5^{25}C_{1} + 9^{25}C_{2 }……… 101 ^{25}C_{25} = 2^{25}k find k = ?

Solution:

= 100 .2^{24} + 2^{25} = 2^{25}(50 + 1) = 51.2^{25}

So k = 51

*Answer can only contain numeric values

QUESTION: 71

Let circles (x – 0)^{2} + (y – 4)^{2} = k and (x – 3)^{2} + (y – 0)^{2} = 1^{2} touches each other than find the maximum value of 'k'

Solution:

Two circles touches each other if C_{1} C_{2} = |r_{1} ± r_{2}|

Distance between C_{2}(3, 0) and C_{1}(0, 4) is either (C_{1}C_{2} = 5)

=> √k + 1 = 5 or |k – 1| = 5

⇒ k = 16 or k = 36

⇒ maximum value of k is 36

*Answer can only contain numeric values

QUESTION: 72

Let angle between equal to π/3

Solution:

⇒

Also,

*Answer can only contain numeric values

QUESTION: 73

Number of common terms in both sequence 3, 7, 11, ………….407 and 2, 9, 16, ……..905 is

Solution:

First common term = 23

common difference = 7 × 4 = 28

Last term ≤ 407

So n = 14

*Answer can only contain numeric values

QUESTION: 74

If minimum value of term free from x for is L_{1} in θ ∈ and L_{2} in θ ∈ find

Solution:

for r = 8 term is free from 'x'

L_{1} = ^{16}C_{8}2^{8
}∵ {Min value of L_{1} at θ = π/4}

{∵ min value of L_{2} at θ = π/8]

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