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Select the energy band which represent the electrical conductivity in direction parallel to chain in graphite
Graphite behave as semimetal in direction parallel to chain. Second band represent the band structure of semimetal. Hence, correct option is (b)
KMg3(OH)2Si3AlO10 is an example of
Correct order of metal ion regarding logβ value for [M-crown-6]+ in gas phase is
In gas phase, ion tends to form stable complex with ligand having more contact point (donor atom) rather than more preference to cavity size. Hence, Na+ due to high charge density than K+ favour crown-6 more than K+ in gas phase. Correct option is (b)
Reaction of S4N4 with metallic potassium or sodium leads to formation of
Reaction of B2H6 with Na/Hg leads to formation of
The formula and type of above borate is
In the above diagram, two oxygen atom is shared hence it is metaborate.
Number of cluster electron pair in [In4Bi5]3- is ________
The number of Banana bond in B5H9 is _____
STYX code of B5H9 = 4120 where S represents number of bond also called Banana Bond.
31P NMR spectrum of cation shows _____doublet of equal intensity
Number of species paramagnetic in nature is/are______
Hydrolysis of P2X4 produces an acid which have basicity _________
Electrophilic substitution reaction of terminal H atom attached to B in closo-1, 2 C2B10H12 follow the sequence
Terminal H atom attached to Boron undergo facile electrophilic substitution and sequence of reactivity follow the sequence of negative charge density on B–Ht group.
More the distance from carbon = more the reactivity towards nucleophile.
The correct statement regarding P is/are
(I) electrical conductivity decreases with increase in temperature
(II) M-graphite compounds are coloured.
(III) Mechanism of conductivity in M-graphite complexes are similar to conductivity in n-type semiconductors.
(IV) In product planarity and delocalization of layers are retained.
Metal graphite complexes has conductivity like Metals and their conductivity decreases with increase in temperature.
These complexes have excess electron in valence band. Hence, their conductivity is due to migration of free electron.
Match Column-A (species) with Column-B (properties related to species)
Correct statement regarding A is/are
(1) It has T-shaped structure
(2) 129Xe NMR spectrum show a triplet
(3) 19F NMR spectrum show four signal
(4) It has TBP geometry
Correct statement regarding A and B are
(1) A is very strong oxidising agent
(4) B is strong oxidising agent.
In the above reaction A and B respectively are
Correct statement regarding C60 is/are
(1) It has Ih point group
(2) Its satisfies IPR
(3) It has two kind of C–C bond length
(4) It is more reactive than graphite
No pentagons are adjacent to each other in C60 and also it has two kinds of bond length, one between two hexagon and one between one hexagon and pentagon.
CH3Cl + Si + HCI → (A)
The (C) is
Number of framework electron in carbonanes C2B5H7 is ________