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Major Organic Chemistry - Chemistry MCQ


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30 Questions MCQ Test Mock Test Series for IIT JAM Chemistry - Major Organic Chemistry

Major Organic Chemistry for Chemistry 2024 is part of Mock Test Series for IIT JAM Chemistry preparation. The Major Organic Chemistry questions and answers have been prepared according to the Chemistry exam syllabus.The Major Organic Chemistry MCQs are made for Chemistry 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Major Organic Chemistry below.
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Major Organic Chemistry - Question 1

An organic compound (MF = C8H10O) exhibit the following 1H NMR spectral data:           
δ 2.5 (3H, s), 3.8 (3H, s), 6.8 (2H, d, J = 8 Hz), 7.2 (2H, d, J = 8Hz), The compound is:           

Major Organic Chemistry - Question 2

Which chemical test will distinguish the compounds shown below?     
      

Detailed Solution for Major Organic Chemistry - Question 2

The given compounds are:

  1. Bromo-methylbenzene (C6H5-CH2Br)
  2. Bromo-toluene (C6H4Br-CH3)

The ethanolic silver nitrate test distinguishes between these two compounds based on their reactivity.

  • Bromo-methylbenzene (C6H5-CH2Br) contains a benzylic bromide, which undergoes nucleophilic substitution easily. When treated with ethanolic AgNO3, it forms a precipitate of AgBr due to the release of the bromide ion.
  • Bromo-toluene (C6H4Br-CH3), on the other hand, has a bromine atom directly attached to the aromatic ring. This bromine is less reactive in nucleophilic substitution due to the resonance stabilization of the C-Br bond, so it does not give the test under similar conditions.

Hence, the ethanolic silver nitrate test can distinguish between the two compounds.

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Major Organic Chemistry - Question 3

The reactivity of compound I-IV with maleic anhydride (V) follows the order:
 (I)  (II)   (III)  (IV)  (V)  

Major Organic Chemistry - Question 4

Major product formed in the following reaction is:

Major Organic Chemistry - Question 5

The mechanism of the transformation involves:  

Major Organic Chemistry - Question 6

Major Organic Chemistry - Question 7

The major product of the following reaction is:

Major Organic Chemistry - Question 8

Consider the following:
   
Order of stretching frequency in IR-spectroscopy would be:           

Detailed Solution for Major Organic Chemistry - Question 8

Correct Answer :- a

Explanation : The stretching frequency increases with increase in the number of Pi bond which is present in the carbon bond. In case of triple bond there are two pi bond , in case of double bond there is only a single pi bond.

This is because with increase in the number of bond there is decrease in the atomic distance and hence there is more chance of stretching between the two atoms with respect to each other.

Major Organic Chemistry - Question 9

The major product formed in the following reaction is:

Major Organic Chemistry - Question 10

The major product formed in the reaction given below is:

Major Organic Chemistry - Question 11

Which is reducing sugar?

Detailed Solution for Major Organic Chemistry - Question 11

Ans: c

Explanation: A reducing sugar is any sugar that is capable of acting as a reducing agent because it has a free aldehyde group or a free ketone group. Ketoses must first tautomerize to aldoses before they can act as reducing sugars. The common dietary monosaccharides galactose, glucose and fructose are all reducing sugars.

Major Organic Chemistry - Question 12

The conditions A-B, required for the following pericyclic are:           
  

Major Organic Chemistry - Question 13

In the following three step transformation, identify the correct combination product P, Q and R:
 

Major Organic Chemistry - Question 14

Consider the given chemical reaction and predict B and C:

Major Organic Chemistry - Question 15

Major product formed in the given reaction is:

Major Organic Chemistry - Question 16

Consider the following chemical reaction and choose the correct product:

Major Organic Chemistry - Question 17

Which of the following is diastereomer of the given compound?

Major Organic Chemistry - Question 18

Consider the following reactions for a compound with molecular formula C10H16:

C10H16 is a terpene called Myrcene and follows is isoprene rule. Hence, correct structure of Myrcene among three possible isomers of C10H16 is:

Major Organic Chemistry - Question 19

For the conversion of X to Y, the appropriate sequence of reaction is:

Major Organic Chemistry - Question 20

Consider the following chemical reaction & predict the major product. [Major product has two geometrical isomers which are inter-convertible in presence of light]:

Major Organic Chemistry - Question 21

The correct order of the basicity of following compounds is:
   

Major Organic Chemistry - Question 22

Correct order of rate of hydrolysis for following compounds is:
 
 
 

Major Organic Chemistry - Question 23

Predict the product for the following sugar functionalization reaction:

Major Organic Chemistry - Question 24

Which of the following bases would give the high percentage of alk-1-ene from 2-bromo-2,3-dimethylbutane?
 

Major Organic Chemistry - Question 25

Choose the major product formed in given chemical reaction sequence:

Major Organic Chemistry - Question 26

What are the most likely products of the reaction shown below?

Major Organic Chemistry - Question 27

Product [B] formed in the following reaction would be:

Major Organic Chemistry - Question 28

Major product formed in the following chemical reaction would be?

Major Organic Chemistry - Question 29

Consider the following chemical reaction and predict the product ‘D’:

Major Organic Chemistry - Question 30

Consider the following chemical reaction sequence. Predict the product ‘Z’:
 

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