In a 200 MHz NMR spectrometer, a molecule shows two doublets separated by 2 ppm. The observed coupling constant is 10 Hz. The separation between these two signals and the coupling constant in a 600 MHz spectrometer will be, respectively:
A molecule, AX, has a vibrat ional energy of 1000 cm–1 and rotational energy of 10 cm–1. Another molecule, BX, has a vibrat ional energy of 400 cm–1 and rotational energy of 40 cm–1. Which one of the following statements about the coupling of vibrational and rotational motion is true:
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The order of carbonyl stretching frequency in the IR spectra of ketone, amide and anhydride is:
In the IR spectrum, carbonyl absorption band for the following compound appears at:
In the IR spectrum of p-nitrophenyl acetate, the carbonyl absorption band appears at:
A triatomic molecule of the type AB2 shows two IR absorption lines and one IR-Raman line. The structure of the molecule is:
In the IR spectrum, the absorption band due to carbonyl group in phenyl acetate appears at:
In the IR spectrum of p-nitrophenyl, acetate, the carbonyl absorption band appears at:
A compound with molecule formula C4H6O2 shows band at 1170 cm–1 in IR spectrum and peaks at 178, 68, 28 and 22 ppm in 13CNMR spectrum. The correct structure of the compound is:
The compound that exhibits sharp bands at 3300 and 2150 cm–1 in the IR spectrum is:
The resonance Raman stretching frequency (νo–o, cm–1) of O2 is 1580. The νo–o for O2 in bond oxyhemoglobin is close to:
Correctly matched structure and carbonyl stretching frequency set is:
Among the following, the compound that displays an IR band at 2150 cm–1 is:
The compound which shows IR frequencies at both 3314 and 2126 cm–1 is:
Match the compound P-S with their carbonyl stretching frequencies (cm–1) I-VI in IR spectroscopy.
Out of the following, the one which is not an excitation source for IR spectrometer is:
The molecule active in rotation microwave, infrared absorption as well as rotational Raman spectra is:
Match the compounds in List – I with the stretching frequencies (cm–1) of the principal functional groups given in List – II.
The IR stretching frequencies (cm–1) for the compound X are as fo llows: 3300-3500 (s, br); 3000 (m); 2225 (s); 1680(s). The correct assignment of the absorption bands is:
Among the compounds given in the option (a) to (d), the one that exhibits a sharp band at around 3300 cm–1 in the IR spectrum is: