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Organic Spectroscopy - IIT JAM MCQ


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20 Questions MCQ Test - Organic Spectroscopy

Organic Spectroscopy for IIT JAM 2024 is part of IIT JAM preparation. The Organic Spectroscopy questions and answers have been prepared according to the IIT JAM exam syllabus.The Organic Spectroscopy MCQs are made for IIT JAM 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Organic Spectroscopy below.
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Organic Spectroscopy - Question 1

In a 200 MHz NMR spectrometer, a molecule shows two doublets separated by 2 ppm. The observed coupling constant is 10 Hz. The separation between these two signals and the coupling constant in a 600 MHz spectrometer will be, respectively:

Organic Spectroscopy - Question 2

A molecule, AX, has a vibrat ional energy of 1000 cm–1 and rotational energy of 10 cm–1. Another molecule, BX, has a vibrat ional energy of 400 cm–1 and rotational energy of 40 cm–1. Which one of the following statements about the coupling of vibrational and rotational motion is true:

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Organic Spectroscopy - Question 3

The order of carbonyl stretching frequency in the IR spectra of ketone, amide and anhydride is:

Organic Spectroscopy - Question 4

In the IR spectrum, carbonyl absorption band for the following compound appears at:

Organic Spectroscopy - Question 5

In the IR spectrum of p-nitrophenyl acetate, the carbonyl absorption band appears at:

Organic Spectroscopy - Question 6

A triatomic molecule of the type AB2 shows two IR absorption lines and one IR-Raman line. The structure of the molecule is:

Organic Spectroscopy - Question 7

In the IR spectrum, the absorption band due to carbonyl group in phenyl acetate appears at:

Organic Spectroscopy - Question 8

In the IR spectrum of p-nitrophenyl, acetate, the carbonyl absorption band appears at:

Organic Spectroscopy - Question 9

A compound with molecule formula C4H6O2 shows band at 1170 cm–1 in IR  spectrum and peaks at 178, 68, 28 and 22 ppm in 13CNMR spectrum. The correct structure of the compound is:

Organic Spectroscopy - Question 10

The compound that exhibits sharp bands at 3300 and 2150 cm–1 in the IR spectrum is:

Organic Spectroscopy - Question 11

The resonance Raman stretching frequency (νo–o, cm–1) of O2 is 1580. The νo–o for O2 in bond oxyhemoglobin is close to:

Organic Spectroscopy - Question 12

Correctly matched structure and carbonyl stretching frequency set is:

Organic Spectroscopy - Question 13

Among the following, the compound that displays an IR band at 2150 cm–1 is:

Organic Spectroscopy - Question 14

The compound which shows IR frequencies at both 3314 and 2126 cm–1 is:

Organic Spectroscopy - Question 15

Match the compound P-S with their carbonyl stretching frequencies (cm–1) I-VI in IR spectroscopy.

Organic Spectroscopy - Question 16

Out of the following, the one which is not an excitation source for IR spectrometer is:

Organic Spectroscopy - Question 17

The molecule active in rotation microwave, infrared absorption as well as rotational Raman spectra is:

Organic Spectroscopy - Question 18

Match the compounds in List – I with the stretching frequencies (cm–1) of the principal functional groups given in List – II.

Organic Spectroscopy - Question 19

The IR stretching frequencies (cm–1) for the compound X are as fo llows: 3300-3500 (s, br); 3000 (m); 2225 (s); 1680(s). The correct assignment of the absorption bands is:

Organic Spectroscopy - Question 20

Among the compounds given in the option (a) to (d), the one that exhibits a sharp band at around 3300 cm–1 in the IR spectrum is:

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