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Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - JEE MCQ


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18 Questions MCQ Test - Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones)

Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) for JEE 2024 is part of JEE preparation. The Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) questions and answers have been prepared according to the JEE exam syllabus.The Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) MCQs are made for JEE 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) below.
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Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 1

The major product of the following reaction is

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 1


Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 2

The major product in the following reaction is

  

(2014 Adv., Only One Option Correct Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 2

This problem includes concept of nucleophilic addition reaction to carbonyl compound (ketone here) and intramolecular nucleophilic substitution reaction.
Complete reaction sequence is as shown below

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*Answer can only contain numeric values
Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 3

Consider all possible isomeric ketones including stereoisomers of MW = 100. All these isomers are independently reacted with NaBH4. The total number of ketones that give a racemic product(s) is/are

Note Stereoisomers are also reacted separately.

(2014 Adv., Integer Type)


Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 3

Molecular weight of the ketone is 100.
So, molecular formula = C6H12O


While in case of (4) and (5), they do not produce enantiomer due to the presence of stereogenic centre on ketone.

Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 4

The major product H in the given reaction sequence is

(2012, Only One Option Correct Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 4

The first step is cyanohydrin reaction.


In the second step, the —CN of intermediate (I) is first hydrolysed and then dehydrated on heating in the presence of cone. H2SO4.


Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 5

The number of aldol reaction (s) that occurs in the given transformation is    

(2012, Only One Option Correct Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 5

The given reaction is an example of repeated aldol condensation followed by Cannizaro reaction.








In the last step, formaldehyde is oxidised and the other aldehyde is reduced giving the desired products.

*Answer can only contain numeric values
Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 6

In the scheme given below, the total number of intramolecular aldol condensation products formed from 'Y' is 


Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 6

Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 7

Passage for Q. Nos. (7-9) 

Two aliphatic aldehydes P and Q react in the presence of aqueous K2CO3 to give compound R, which upon treatment with HCN provides compounds. On acidification and heating, S gives the product shown below :

 

Q. 

The compounds P and Q respectively are 

(2010, Comprehension Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 7

The given product is an ester, obtained by condensation of a hydroxy acid obtained through hydrolysis of a cyanohydrin.

Acid above is obtained by acid hydrolysis of cyanohydrin S as 

S is obtained by nucleophilic addition of HCN on R, hence R is 

R is obtained by treatment of P and Q with aqueous K2CO3 through aldol condensation reaction as

Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 8

Two aliphatic aldehydes P and Q react in the presence of aqueous K2CO3 to give compound R, which upon treatment with HCN provides compounds. On acidification and heating, S gives the product shown below :

 

Q. 

The compound R is 

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 8

The given product is an ester, obtained by condensation of a hydroxy acid obtained through hydrolysis of a cyanohydrin.

Acid above is obtained by acid hydrolysis of cyanohydrin S as 

S is obtained by nucleophilic addition of HCN on R, hence R is 

R is obtained by treatment of P and Q with aqueous K2CO3 through aldol condensation reaction as

Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 9

Two aliphatic aldehydes P and Q react in the presence of aqueous K2CO3 to give compound R, which upon treatment with HCN provides compounds. On acidification and heating, S gives the product shown below :

 

Q. 

The compound S is

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 9

The given product is an ester, obtained by condensation of a hydroxy acid obtained through hydrolysis of a cyanohydrin.

Acid above is obtained by acid hydrolysis of cyanohydrin S as 

S is obtained by nucleophilic addition of HCN on R, hence R is 

R is obtained by treatment of P and Q with aqueous K2CO3 through aldol condensation reaction as

Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 10

Passage for Q. Nos. (10-12)

A carbonyl compound P, which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin Q. Ozonolysis of Q leads to a dicarbonyi compound R, which undergoes intramolecular aldo reaction to give predominantly S.

Q. 

The structure of the carbonyl compound P, is

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 10


Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 11

A carbonyl compound P, which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin Q. Ozonolysis of Q leads to a dicarbonyi compound R, which undergoes intramolecular aldo reaction to give predominantly S.

Q. 

The structure of the product S, is 

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 11


Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 12

A carbonyl compound P, which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin Q. Ozonolysis of Q leads to a dicarbonyi compound R, which undergoes intramolecular aldo reaction to give predominantly S.

Q. 

The structures of the products Q and R, respectively, are

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 12


Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 13

Passage for Q. Nos. (13-15)

In the following sequence, product I, J and L are formed , K represents a reagent.


Q. 

The structure of the product I is

(2008, Comprehension Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 13




Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 14

In the following sequence, product I, J and L are formed , K represents a reagent.


Q. 

The structures of compounds J and K, respectively, are

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 14




Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 15

In the following sequence, product I, J and L are formed , K represents a reagent.


Q. 

The structure of product L is

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 15




Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 16

Cyclohexene on ozonolysis followed by reaction with zinc dust and water gives compound E. Compound E on further treatment with aqueous KOH yields compound F. Compound F is 

(2007, Only One Option Correct Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 16


Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 17

The smallest ketone and its next homologue are reacted with NH2OH to form oxime

(2006, Only One Option Correct Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 17



Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 18

Butan-2-one can be converted to propanoic acid by which of the following ?

(2006, Only One Option Correct Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Aliphatic Aldehydes And Ketones) - Question 18

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