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Retro JEE Advanced (Liquid Solutions) - JEE MCQ


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8 Questions MCQ Test - Retro JEE Advanced (Liquid Solutions)

Retro JEE Advanced (Liquid Solutions) for JEE 2024 is part of JEE preparation. The Retro JEE Advanced (Liquid Solutions) questions and answers have been prepared according to the JEE exam syllabus.The Retro JEE Advanced (Liquid Solutions) MCQs are made for JEE 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Retro JEE Advanced (Liquid Solutions) below.
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Retro JEE Advanced (Liquid Solutions) - Question 1

For a dilute solution containing 2.5 g of a non-volatile non-electrolyte solute in 100 g of water, the elevation in boiling point at 1 atm pressure is 2°C. Assuming concentration of solute is much lower than the concentration of solvent, the vapour pressure (mm of Hg) of the solution is (take Kb = 0,76 K kg mol-1).

(2012)

Detailed Solution for Retro JEE Advanced (Liquid Solutions) - Question 1

Retro JEE Advanced (Liquid Solutions) - Question 2

The freezing point (in° C) of solution containing 0.1 g of K3[Fe(CN)6] (mol. wt. 329) in 100 g of water (Kf = 1.86 K kg mol-1) is

Detailed Solution for Retro JEE Advanced (Liquid Solutions) - Question 2

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Retro JEE Advanced (Liquid Solutions) - Question 3

The Henry’s law constant for the solubility of N2 gas in water at 298 K is 1.O x 105 atm. The mole fraction of N2 in air is 0.8. The number of moles of N2 from air dissolved in 10 moles of water of 298 K and 5 atm pressure is

(2009)

Detailed Solution for Retro JEE Advanced (Liquid Solutions) - Question 3

Retro JEE Advanced (Liquid Solutions) - Question 4

Passage

Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties.
Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles.
A solution M is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixture is 0.9.
Given, freezing point depression constant of water

() = l . 8 6 K kg mol-1

 Freezing point depression constant of ethanol

() = 2.0 K kg mol-1

Boiling point elevation constant of water

{) = 0.52 K kg mol-1

Boiling point elevation constant of ethanol

()=1.2 K kg mol-1

Standard freezing point of water =273 K

Standard freezing point of ethanol = 155.7 K

Standard boiling point of water = 373 K

Standard boiling point of ethanol = 351.5 K

Vapour pressure of pure water = 32.8 mm Hg

Vapour pressure of pure ethanol = 40 mm Hg

Molecular weight of water = 18 g mol-1 

Molecular weight of ethanol = 46 g mol-1

 In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Q.

The freezing point of the solution M is

Detailed Solution for Retro JEE Advanced (Liquid Solutions) - Question 4

(d)

Water is solute and ethanol is solvent

Retro JEE Advanced (Liquid Solutions) - Question 5

Passage

Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties.
Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles.
A solution M is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixture is 0.9.
Given, freezing point depression constant of water

() = l . 8 6 K kg mol-1

 Freezing point depression constant of ethanol

() = 2.0 K kg mol-1

Boiling point elevation constant of water

{) = 0.52 K kg mol-1

Boiling point elevation constant of ethanol

()=1.2 K kg mol-1

Standard freezing point of water =273 K

Standard freezing point of ethanol = 155.7 K

Standard boiling point of water = 373 K

Standard boiling point of ethanol = 351.5 K

Vapour pressure of pure water = 32.8 mm Hg

Vapour pressure of pure ethanol = 40 mm Hg

Molecular weight of water = 18 g mol-1 

Molecular weight of ethanol = 46 g mol-1

 In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Q.

The vapour pressure of the solution M is

Detailed Solution for Retro JEE Advanced (Liquid Solutions) - Question 5

Retro JEE Advanced (Liquid Solutions) - Question 6

Passage

Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties.
Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles.
A solution M is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixture is 0.9.
Given, freezing point depression constant of water

() = l . 8 6 K kg mol-1

 Freezing point depression constant of ethanol

() = 2.0 K kg mol-1

Boiling point elevation constant of water

{) = 0.52 K kg mol-1

Boiling point elevation constant of ethanol

()=1.2 K kg mol-1

Standard freezing point of water =273 K

Standard freezing point of ethanol = 155.7 K

Standard boiling point of water = 373 K

Standard boiling point of ethanol = 351.5 K

Vapour pressure of pure water = 32.8 mm Hg

Vapour pressure of pure ethanol = 40 mm Hg

Molecular weight of water = 18 g mol-1 

Molecular weight of ethanol = 46 g mol-1

 In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Q.

Water is added to the solution M such that the mole fraction of water in the solution becomes 0.9. The boiling point of this solution is

Detailed Solution for Retro JEE Advanced (Liquid Solutions) - Question 6

∴ Boiling point of solution as water solvent = 373.0 +3.2= 379.2 K

Retro JEE Advanced (Liquid Solutions) - Question 7

When 20 g of naphthoic acid (C11H8O2 is dissolved in 50 g of benzene {Kf = 1.72 K kg mol-1), a freezing point depression of 2 K is observed. The van’t Hoff factor (i) is

(2007)

Detailed Solution for Retro JEE Advanced (Liquid Solutions) - Question 7

Retro JEE Advanced (Liquid Solutions) - Question 8

The elevation in boiling point, when 13.44 g of freshly prepared CuCI2 are added to one kilogram of water, is (Some useful data, Kb = 0.52 kg K mol-1 molecular weight of CuCI2 =134.4 g).

Detailed Solution for Retro JEE Advanced (Liquid Solutions) - Question 8

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