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Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Class 12 MCQ


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30 Questions MCQ Test - Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy)

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Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 1

Only One Option Correct Type

Direction (Q. Nos. 1-10) This section contains 10 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.

Q. 

Observe the following statements regarding purification of bauxite

i. During Hall's process, silica, is removed as Si (vapour).
ii. Bauxite ore contaminated with iron oxide is purified in Baeyer's process.
iii. During Serpeck's process silica, is removed as Si (vapour).

The correct answer is

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 1

Hall process
AI2O3 + Na2CO3 → 2NaAIO2 + CO2
Baeyer’s process
Al2O3 + 2NaOH + 3H2O →2Na[AI(OH)4]
Serpeck process
Al2O3 + 3C + N2 → 2AIN + 3CO and SiO2 + 2C → Si + 2CO

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 2

Puddling process is used to convert pig iron into

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 2

Puddling process is the method of converting pig iron into wrought iron by subjecting it to heat and frequent stirring in a furnace in the presence of oxidizing substances.

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Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 3

The impurity present in ruby and sapphire are

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 3

Ruby is a red form of corundum. Al2O3 and im purity present in it is chromium. Sapphire is a blue transparent corundum (alumina, Al2O3). Its colour is due to the tracer of cobalt.

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 4

Which of the following is froth stabilizer in froth floatation process?

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 4

Cresols and aniline are the froth stabilisers which stabilises froth.

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 5

Sulphide ores of metals are usually concentrated by froth floatation process. Which one of the following sulphide ores offers an exception and is concentrated by leaching?

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 5

From argentite,
4Ag + 8NaCN + O2 + 2H2O → 4Na[Ag(CN)2] + 4NaOH
silver is extracted by leaching process.

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 6

The process used in refining blister copper is

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 6

Poling method is employed when the crude metal contains impurities of the oxide of the metal itself.
3Cu2O + CH4 → 6Cu + 2H2O + CO

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 7

The pair of metals obtained by heating their oxides to higher temperatures

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 7

Ag2O and HgO

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 8

After partial roasting, the sulphide of copper is reduced by

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 8

2CuFeS2 + 2SiO2 + 4O2 → Cu2S + 2FeSiO3 + 3 SO2
Cu2S + O2 → 2Cu + SO2

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 9

Type metal is an alloy containing

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 9

In printing, type metal (sometimes called hot metal) refers to the metal alloys used in traditional typefounding and hot metal typesetting. Historically, type metal was an alloy of lead, tin and antimony in different proportions depending on the application, be it individual character mechanical casting for hand setting, mechanical line casting or individual character mechanical typesetting and stereo plate casting. The proportions used are in the range: lead 50‒86%, antimony 11‒30% and tin 3‒20%. Antimony and tin are added to lead for durability while reducing the difference between the coefficients of expansion of the matrix and the alloy. Apart from durability, the general requirements for type-metal are that it should produce a true and sharp cast, and retain correct dimensions and form after cooling down. It should also be easy to cast, at reasonable low melting temperature, iron should not dissolve in the molten metal, and mould and nozzles should stay clean and easy to maintain. Today, Monotype machines can utilize a wide range of different alloys. Mechanical linecasting equipment use alloys that are close to eutectic.

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 10

The formulae of the soluble complexes formed during the extraction of Ag and Au by the cyanide process respectively are

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 10

Ag2S + 4NaCN  2Na[Ag(CN)] + Na2S
4Au + 8KCN + 2H2O + O→ 4K[Au(CN)2] + 4KOH

*Multiple options can be correct
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 11

One or Morethan One Options Correct Type

Direction (Q. Nos. 11-20) This section contains 10 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONE or MORE THAN ONE are correct.

Q. ZnS and PbS present in a sulphide ore can be separated by using selectively suitable chemical. The incorrect statement in this is

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 11

Depressants are used to prevent one type of sulphide ore particles from forming the froth with air bubbles, e.g. NaCN. It is used to separate lead sulphide (PbS) ore from zinc sulphide (ZnS) ore.
4NaCN + ZnS → Na2[Zn(CN)4] + Na2S

*Multiple options can be correct
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 12

Regarding leaching of bauxite ore which of the following is incorrect?

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 12

*Multiple options can be correct
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 13

In the metal extraction which of the following is subjected to calcinations?

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 13

*Multiple options can be correct
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 14

Which of the following process is based on the formation of complex compounds

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 14

Mac Arthur Forest Process

*Multiple options can be correct
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 15

Lapis lazuli is

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 15

Lapis lazuli is a deep blue semi-precious stone.
(Na,Ca)8(AISiO4)6(S,SO4,CI)1-2

*Multiple options can be correct
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 16

ΔG° vs T plot in the Ellingham diagram slopes upwards for the reaction

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 16

The reaction  does not satisfy the upward slope for Ellingham diagram.

*Multiple options can be correct
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 17

Lithopone, a white pigment is a mixture of

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 17

Lithopone is ZnS-BaSO4

*Multiple options can be correct
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 18

Which is incorrect match?

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 18

Corrosive sublim ate = HgCI2 and Hg2Cl2 is called calomel.
Litharge = PbO, Lunar caustic = AgNO3

*Multiple options can be correct
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 19

Which of the following is a hydrated oxide mineral?

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 19

(a) Limonite 2Fe2O3.3H2O , Cassiterite (SnO2), Bauxite = Al2O3, Haematite = Fe2O3

*Multiple options can be correct
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 20

The Ellingham diagram of a certain metal M is represented in the figure

Q. 

The points A and B respectively corresponds to

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 20

The points A and B show minimum and maximum value of ΔG° with melting and boiling points of metals.

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 21

Comprehension Type

Direction (Q, Nos. 21 and 22) This section contains a paragraph, each describing theory, experiments, data, etc. Two questions related to the paragraph have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).

Passage

Metal M is extracted from its ore, which is a double salt. It is a salt of M and potassium. The ore is concentrated and water of hydration present in the double salt is removed. The ore is then reduced to get the metal. The metal so produced used to make Grignard reagent.

Q. 

The ore of the metal in the passage

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 21

Magnesite (MgCO3), Epsomite (MgSO4 .7H2O),
Carnallite (KCI.MgCI2.6H2O), Spodumene = LiAI(SiO3)3

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 22

Passage

Metal M is extracted from its ore, which is a double salt. It is a salt of M and potassium. The ore is concentrated and water of hydration present in the double salt is removed. The ore is then reduced to get the metal. The metal so produced used to make Grignard reagent.

Q. 

The flame colouration given by the ore mentioned in the passage

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 22

The ore carnallite is KCI.MgCI2.6H2O. Due to potassium it gives lilac colour.

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 23

Matching List Type

Direction (Q. No. 23 and 24) Choices for the correct combination of elements from Column I and Column II are given as options (a), (b), (c) and (d), out of which one is correct.

Q. 

Match the Column I with Column II and mark the correct option from the codes given below.

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 23

(i) → (r), (ii) → (s), (iii) → (p), (iv) → (q)

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 24

Match the Column I with Column II and mark the correct option from the codes given below.

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 24

(i) → (q), (ii) → (r), (iii) → (p), (iv) → (s)

*Answer can only contain numeric values
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 25

One Integer Value Correct Type

Direction (Q. Nos. 25 -29) This section contains 5 questions. When worked out will result in an integer from 0 to 9 (both inclusive).

Q. 

The value of ‘n‘ in the molecular formula BenAI2Si6O18 is .........


Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 25

Beryl is Be3 AI2Si6O18. To balance the charge on all atoms n = 3
(2n + 6 + 24 - 36 - 0)

*Answer can only contain numeric values
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 26

In blue vitriol the number of water molecules directly bonded to Cu2+ ion are


Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 26

Cu is cordinated with 4 water molecules and two more oxygen atoms fron Sulphate ion. Now fifth water molecule is hydrogen bonded and is deeply embedded in crystal.

*Answer can only contain numeric values
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 27

The number of oxide ores among Rutile. Beryl, Tinstone, Pyrolusite, Chromite, Corundum, Chalcosite, Gypsum, Cryolite, Feldspar and Pitche blende


Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 27

Oxide ores are Rutile (TiO2), Tinstone (SnO2),
Pyrolusite (MnO2), Chromite(FeCr2O4), Corundum (Al2O3), Pitche blende (U3O8)
Beryl (3BeO.Al2O3.6SiO2), Chalcosite (Cu2S), Gypsum (CaSO4.2H2O, Cryolite(Na3AIF6), Feldspar (KAISi3O8)

*Answer can only contain numeric values
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 28

In German silver the percentage of silver is


Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 28

German silver (Cu, Zn and Ni)

*Answer can only contain numeric values
Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 29

How many of the following metals can be refined by vapour phase refining?
Zr, Zn, Cd, Hg, Ni, Co, Pt, Fe, Ti


Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 29

Among the given metals, Zr, Ti, Ni can be refined by vapour phase refining.

Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 30

Statement Type

Direction (Q. No. 30) This section is based on Statement I and Statement II. Select the correct answer from the codes given below.

Q. 

Statement I : F2 is manufactured by electrolysis of KHF2 but here anhydrous HF is used as solvent in place of water.
Statement II : In the presence of anhydrous HF, more F2 is produced.

Detailed Solution for Revisal Problems (Past 13 Year) JEE Advanced (Metallurgy) - Question 30

F2 produced, violently reacts with water.

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