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Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - JEE MCQ


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20 Questions MCQ Test - Revisal Problems (Past 13 Years) JEE Main (Thermodynamics)

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Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 1

Direction (Q. Nos. 1-20) This section contains 20 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.

Q. The amount of heat evolved when 500 cm3 of 0.1 M HCI is mixed with 200 cm3 of 0.2 M NaOH is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 2

Given, ΔfH°(NH3) = -46.1 kJ mol-1 and ΔfH° of the following reaction is -187.6kJ
N2H4(g) + H2(g) → 2NH3(g)

Q. Thus, ΔfH° (N2H4) is

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Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 3

In the following reaction,

This value is much higher than the heat of neutralisation of strong acid with strong base (-57.3 kJ mol-1) . This is because

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 4

For the above reaction, 2NO(g) + O2(g) → 2NO2(g)

Select incorrect relation

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 5

At what temperature will the equilibrium constant for the formation of NOCI(g) be

Keq = Kp = 1.0 x 103

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 6

For the reaction at 298 K

Thus ΔG° for the given reaction is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 7

Methane is a commercial source of H2 through the reaction

Based on the following thermochemical equations (II to IV)

Q. ΔH of equation (I) is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 8

Given,

Thus, for the reaction



Thus, for the reaction

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 9

Vapour pressure of a liquid is 10 mm at 300 K, 20 mm at 400 K. What is the vapour pressure at 500 K?

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 10

The combustion of hydrogen-oxygen mixture is used to produce very high temperatures (= 2500 °C) needed for certain types of welding operations.

Q. Quantity of heat, (in kJ) evolved when a 180 g mixture containing equal parts of H2 and O2 mass is burned, is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 11

Due to dissolution of ammonium chloride in H2O, temperature falls rapidly. Thus, 

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 12

The standard heat of combustion of benzoic acid, C6H5COOH(s), at 1 bar and 298 K is -329.3 kJ mol-1. The standard heat of combustion at constant volume is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 13

Bond dissociation energies of H—H, O=O, O—H and O—O are x1, x2, x3, and x4 respectively.

Thus, heat of formation of H2O2(g) is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 14

Thus, melting point of NaCI (s) is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 15

Quantity of work (in joules) done by the gas if it expands against a constant pressure of 0.980 atm and the change in volume (Δ/) is 25.0 L, is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 16

The combustion of 1.0 g of sucrose (C12H22O11) in a bomb calorimeter causes the temperature to rise from 25.0°C to 28.5°C. The heat of combustion of sucrose is (heat capacity of the calorimeter system is 4.90 kJ K-1

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 17

A gas, while expanding absorbs 25 J of heat and does 243 J of work. Thus, ΔE (change in internal energy) for the gas is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 18

1.0 L of liquid water freezes under a constant pressure of 1.0 atm and forms 1.1 L of ice.

Thus, work done is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 19

In the following adiabatic expansion of 1 mole of CO2 gas, temperature T is

Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 20

For the dissociation of PCI5(g)

Slope of the linear curve is such that θ = tan-1 (-1.5)

Q. Thus, ΔH° is 

Detailed Solution for Revisal Problems (Past 13 Years) JEE Main (Thermodynamics) - Question 20
Tan (theta) =-1.5, according to the graph, tan (theta) =logk/1/T=Tlogk , and we know, dH=-2.303×dn×RTlogk=-2.303×1×8.31×(-1.5)=28.72
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