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Test: Basic Concepts of Solutions(17 Sep) - JEE MCQ


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Test: Basic Concepts of Solutions(17 Sep) - Question 1

During dissolution when solute is added to the solvent, some solute particles separate out from the solution as a result of crystallisation. At the stage of equilibrium, the concentration of solute in the solution at given temperature and pressure

Detailed Solution for Test: Basic Concepts of Solutions(17 Sep) - Question 1

At dynamic equilibrium, number of solute particles going into the solution will be equal to solute particles separating out. Hence, the concentration of solute in the solution remains constant.

Test: Basic Concepts of Solutions(17 Sep) - Question 2

According to Henry's law the partial pressure of the gas in vapour phase (p) is proportional to the mole fraction of the gas (x) in the solution. For different gases the correct statement about Henry's constant is

Detailed Solution for Test: Basic Concepts of Solutions(17 Sep) - Question 2

p = KHx. Higher the value of KH at a given pressure, lower is the solubility of the gas in the liquid.

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Test: Basic Concepts of Solutions(17 Sep) - Question 3

H2S is a toxic gas used in qualitative analysis. If solubility of H2S in water at STPSTP is 0.195m, what is the value of KH?

Detailed Solution for Test: Basic Concepts of Solutions(17 Sep) - Question 3

No. of moles of H2S = 0.195
No. of moles of H2O = 1000/18 = 55.55mol
Mole fraction of H2S =
Pressure at STP = 0.987 bar
According to Henry’s law, p = KHx
or KH = pH2S/xH2S = 0.98/70.0035
= 282 bar

Test: Basic Concepts of Solutions(17 Sep) - Question 4

When a gas is bubbled through water at 298K, a very dilute solution of gas is obtained. Henry’s law constant for the gas is 100kbar. If gas exerts a pressure of 1bar1bar, the number of moles of gas dissolved in 11 litre of water is

Detailed Solution for Test: Basic Concepts of Solutions(17 Sep) - Question 4

p = KH × x

Mole fraction = Moles of gas/Total moles
Moles of H2O = 1000/18 = 55.55 (∵ 1L = 1000 g)
Mole fraction = (55.55 >>> x)

Test: Basic Concepts of Solutions(17 Sep) - Question 5

What is the mole fraction of glucose in 10% w/W glucose solution?

Detailed Solution for Test: Basic Concepts of Solutions(17 Sep) - Question 5

No. of moles of glucose = 10/180 = 0.0555 mol
No. of moles of water = 90/18 = 5 mol
Number of moles of solution = 5.0555 mol
Mole fraction of glucose = No. of moles of glucose/No. of moles of solution = 0.0555/5.0555 = 0.01

Test: Basic Concepts of Solutions(17 Sep) - Question 6

When 1.04g of BaCl2 is present in 105g of solution, the concentration of solution is:

Detailed Solution for Test: Basic Concepts of Solutions(17 Sep) - Question 6

ppm = 

= 10.4 ppm

Test: Basic Concepts of Solutions(17 Sep) - Question 7

What is the molarity of a solution containing 10 g of NaOH in 500 mL of solution?

Detailed Solution for Test: Basic Concepts of Solutions(17 Sep) - Question 7

No. of moles of NaOH = 10/40 = 0.25 mol

Test: Basic Concepts of Solutions(17 Sep) - Question 8

How many grams of NaOH are present in 250 mL of 0.5 M NaOH solution?

Detailed Solution for Test: Basic Concepts of Solutions(17 Sep) - Question 8

No. of moles of NaOH

Mass of NaOH = 40 × 0.125 = 5g

Test: Basic Concepts of Solutions(17 Sep) - Question 9

The density of a solution prepared by dissolving 120g of urea (mol. mass = 60u) in 1000g of water is 1.15g/mL. The molarity of this solution is

Detailed Solution for Test: Basic Concepts of Solutions(17 Sep) - Question 9

Mass of solute taken = 120g
Molecular mass of solute = 60u
Mass of solvent = 1000g
Density of solution = 1.15g/mL
Total mass of solution = 1000 + 120 = 1120g

Test: Basic Concepts of Solutions(17 Sep) - Question 10

The molality of 648 g of pure water is

Detailed Solution for Test: Basic Concepts of Solutions(17 Sep) - Question 10

Molality = no of moles of solute/mass of solvent in kg
Molar mass of water = 18 g
Mass of water = 648 g
No of moles of water = 648/18 = 36 mol

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