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QUESTION: 1

The unit of molar conductivity is:

Solution:

QUESTION: 2

The cell constant of a conductivity cell is defined as:

Where l = distance between electrodes and A = area of cross-section of each of the electrodes

Solution:

QUESTION: 3

Molar conductivity is defined as:

Where k = conductivity, G = conductance, l = distance between two electrodes and V_{m} = volume of solution containing 1 mol of electrolyte

Solution:

Where C = concentration of electrolyte

QUESTION: 4

For a dilute solution of a strong electrolyte, the variation of molar conductivity with concentration is given by:

Solution:

QUESTION: 5

Which of the following ion is expected to have least value of molar conductivity at infinite dilution in an aqueous solution:

Solution:

QUESTION: 6

Which of the following ion is expected to have highest value of molar conductivity at infinite dilution in an aqueous solution:

Solution:

H^{+} ions will have the maximum molar conductivity amongst the given cations due to Grothus conduction..

QUESTION: 7

The degree of dissociation of a weak electrolyte is given by:

Solution:

QUESTION: 8

Which of the following ion has highest molar conductivity at infinite dilution in an aqueous solution:

Solution:

QUESTION: 9

The equilibrium constant of acetic acid in an aqueous solution of concentration C is given by

Solution:

QUESTION: 10

Molar conductivity of Fe_{2}(SO_{4})_{3} is given by:

Solution:

QUESTION: 11

Equivalent conductivity of Fe_{2}(SO_{4})_{3} is related to molar conductivity by the expression:

Solution:

QUESTION: 12

Which of the following expressions is correct:

Solution:

QUESTION: 13

If x is the specific resistance of the electrolyte solution and y is he molarity of the solution, then is given by:

Solution:

Molar conductivity is defined as the conductivity of an electrolyte solution divided by the molar concentration of electrolyte.

QUESTION: 14

When a conductance cell was filled with a 0.0025 M solution of K_{2}SO_{4}, its resistance was 326 Ω. If cell constant is 0.2281 cm^{-1}, the specific conductance (Ω^{-1}cm^{-1}) of K_{2}SO_{4} solution is:

Solution:

QUESTION: 15

Equivalent conductance of 0.1 M HA (weak acid) solution is 10 cm^{2} equivalent^{–1}. The pH of HA solution is(molar conductivity at infinite dilution is 200).

Solution:

QUESTION: 16

For HCl solution at 25ºC, the equivalent conductivity at infinite dilution is 425 Ω^{-1} cm^{2} eq^{-1}. The specific conductance of a solution of HCl is 3.825 Ω^{-1} cm^{-1}. If the apparent degree of dissociat ion is 90%, the normality of solution is

Solution:

QUESTION: 17

The conductance at infinite dilution follow the order

Solution:

QUESTION: 18

The correct relation which depicts the Debye-Huckel Onsager Theory for strong electrolytes is:

Solution:

**Correct Answer :- B**

**Explanation :** The Debye-Huckel was proposed by Peter Debye and Erich Huckel as a theoretical explanation for departure from ideality in solutions of electrolytes.

further modified by Lars Onsager in 1927.

Onsagar was able to derive a theoretical expression to account for the empirical relation known as Kohlrausch's law for the molar conductivity, Am

Am = Am_{o} - K(c)^{½}

For stronger electrolytes

A_{m} = A_{m}^{o} - (A + BAm_{o})(c)^{1/2ac}

QUESTION: 19

The unit of A in Debye-Huckel-Onsager equation for strong electrolytes is:

Solution:

QUESTION: 20

Which of the following solutions will show the minimum value of transference number of Cl^{–1} ions:

Solution:

Because has maximum value of transference no. as co mpared to other cations. Hence will be minimum in 0.1 M HCl solution

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