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Test: Chemical reactions for aldehydes and ketones - JEE MCQ


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20 Questions MCQ Test Chemistry for JEE Main & Advanced - Test: Chemical reactions for aldehydes and ketones

Test: Chemical reactions for aldehydes and ketones for JEE 2024 is part of Chemistry for JEE Main & Advanced preparation. The Test: Chemical reactions for aldehydes and ketones questions and answers have been prepared according to the JEE exam syllabus.The Test: Chemical reactions for aldehydes and ketones MCQs are made for JEE 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Test: Chemical reactions for aldehydes and ketones below.
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Test: Chemical reactions for aldehydes and ketones - Question 1


Product (B) is:

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Test: Chemical reactions for aldehydes and ketones - Question 2


(Q)
(R) , Structure of is:

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Test: Chemical reactions for aldehydes and ketones - Question 3

What is the product of the following reaction?

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Test: Chemical reactions for aldehydes and ketones - Question 4


Product (B) in this reaction is:

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Test: Chemical reactions for aldehydes and ketones - Question 5
Which one of the following is not formed by aldol condensation of a mixture of ethanal and propanal?
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Hex-3-enal requires a larger aldehyde or ketone as one of the reactants to provide the necessary carbon chain length. Ethanal and propanal do not provide sufficient carbon atoms to form hex-3enal.
Test: Chemical reactions for aldehydes and ketones - Question 6
The number of aldehydes that undergo cannizaro reaction from the following are Phenyl ethanal, Methanal, 2 Methoxy propanal, Trichoro ethanal
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Compounds that do not have -hydrogens undergo cannizzaro reaction.
Such compounds are:-

Test: Chemical reactions for aldehydes and ketones - Question 7
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Test: Chemical reactions for aldehydes and ketones - Question 8


Identify appropriate reagents for the above reaction:

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Test: Chemical reactions for aldehydes and ketones - Question 9
The starting compounds needed to make the following compound?
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Test: Chemical reactions for aldehydes and ketones - Question 10


most likely the compound X is

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Reaction of 4,4 -dialkylcyclohexadienone with an acid to form phenol with the migration of one of the alkyl groups to the adjacent carbon is known as dienone-phenol rearrangement.

Test: Chemical reactions for aldehydes and ketones - Question 11

The reagents employed to carry the following transformation

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Test: Chemical reactions for aldehydes and ketones - Question 12
What is the product of the following reaction?
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Only-CHO group reacts with ion and the reaction is
Test: Chemical reactions for aldehydes and ketones - Question 13
What is the product of the following reaction?
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Test: Chemical reactions for aldehydes and ketones - Question 14
In the following reaction, the product is
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Aldehydes lacking atom, undergo Cannizzaro reaction if treated with concentrated alkali (NaOH), i.e., one mole of the aldehyde is reduced to alcohol and other mole is oxidised to salt of acid. Thus, the given aldehyde (glyoxal) undergoes intramolecular Cannizzaro reaction, ie. its half part is oxidised and half is reduced.
Test: Chemical reactions for aldehydes and ketones - Question 15
3-hydroxybutanal is formed when reacts with in dilute solution. What are and ?
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Aldehydes having -H-atoms undergoes aldol condensation in the presence of dil. and yield -hydroxy aldehydes.

Test: Chemical reactions for aldehydes and ketones - Question 16
Amongst the following compounds, the one that will not respond to Cannizzaro reaction upon treatment with alkali is
Detailed Solution for Test: Chemical reactions for aldehydes and ketones - Question 16
For a carbonyl group to give Cannizaro reaction, it should not have an -hydrogen atom. Among the given compound and HCHO respond
to Cannizaro reaction but do not due to the following reason.


When hydroxyl group attacks the carbonyl group a tetrahedral intermediate forms. This tetrahedral intermediate will revert to a carbonyl compound by
expelling the best leaving group. The CCl carbonium is resonance stabilised therefore it is better leaving group than OH. These initial products exchange a proton to give ion of carboxylic acid and trichloromethane ().
Test: Chemical reactions for aldehydes and ketones - Question 17


What is ?

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It is an example of intramolecular cannizzaro reaction.

Test: Chemical reactions for aldehydes and ketones - Question 18
What is the product of the following reaction.
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It is an example of intramolecular aldol condensation
Test: Chemical reactions for aldehydes and ketones - Question 19
The most reactive compound towards formation of cyanohydrin on treatment with KCN followed by acidification is
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group is electron withdrawing which enchances the addition of ion (a nucleophili additon reaction).
Test: Chemical reactions for aldehydes and ketones - Question 20
What is D in the following sequence of reactions?
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