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Test: Energy of Activation - NEET MCQ


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22 Questions MCQ Test Chemistry Class 12 - Test: Energy of Activation

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Test: Energy of Activation - Question 1

Direction (Q. Nos. 1-12) This section contains 12 multiple choice questions. Each question has four choices (a), (b), (c) and (cl), out of which ONLY ONE is correct.

Q.

The rate of a reaction doubles when its temperature changes from 300 K to 310 K. Activation energy of such a reaction will be (Given, R = 8.314 J K-1 mol-1, log2 = 0.3010).

Detailed Solution for Test: Energy of Activation - Question 1


Test: Energy of Activation - Question 2

In the following reaction

N2O  N2+O

k = (5.0 x 1011 L mol-1 s-1) e -29000R/T, Ea (energy o f activation) is 

Detailed Solution for Test: Energy of Activation - Question 2

By Arrhenius equation


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Test: Energy of Activation - Question 3

Rate of a reaction can be expressed by Arrhenius equation as k = Ae-EalRT. In this equation, Ea represents.

Detailed Solution for Test: Energy of Activation - Question 3


Ea (activation energy) is the energy required to activate the reactant so that they may collide and give the final product. Below point B, the reactants will not react at all.

Test: Energy of Activation - Question 4

In the upper atmosphere, form ation of H2O2 takes place as

H2O+O → 2OH → H202

ΔH0 = 72.0 Kj mol-1 ; E= 77.0 kJ mol-1

Ea for the bim olecular recombination of two OH radicals to form H2O and O is

Detailed Solution for Test: Energy of Activation - Question 4



Test: Energy of Activation - Question 5

How much rate is affected in the presence of catalyst at 300 K?

Detailed Solution for Test: Energy of Activation - Question 5

k(no catalyst) = Ae -Ea/RT 

∴ 

Thus, rate is affected (28.03) times.
k1 (no catalyst) = Ae-Ea/RT
k2 (with catalyst) = Ae-(Ea - 2)/RT 

Test: Energy of Activation - Question 6

For a reaction,

A → Product

t50  = 100 min at temprature T1

and t50 = 80 min at temprature T2

Thus, 

Detailed Solution for Test: Energy of Activation - Question 6

On increasing temperature, number of collisions hence kinetic energy increases.

Thus, 


Thus rate of the reaction or rate constant increases with increase in temperature.
Half-life of any reaction
Thus, half-life decreases with increase in temperature, reaction may be exothermic or endothermic.
Thus,   

Test: Energy of Activation - Question 7

Rate constant (k) of a reaction has least value at

Detailed Solution for Test: Energy of Activation - Question 7

k varies with temperature as given by Arrhenius equation
 

k has least value at low 7 and high Ea.

Test: Energy of Activation - Question 8

Two reactions with different activation energies have the same rate at room temperature. Which statement correctly describes the rates of these two reactions at the same higher temperature?

Detailed Solution for Test: Energy of Activation - Question 8



If temperature is increased to T`,

If 
Thus, reaction with smaller activation energy will be faster on increasing temperature.

Test: Energy of Activation - Question 9

The activation energy of the reaction at a given temperature is found to (2.303 RT) J mol-1. The ratio of rate constant to the Arrhenius factor is

Detailed Solution for Test: Energy of Activation - Question 9





Test: Energy of Activation - Question 10

From the given figure, select the correct statement about activation energy.

Activation energy of

Detailed Solution for Test: Energy of Activation - Question 10

Energy required to take the reactant to the activated state is (E1 + E2). Since, reactions is endothermic, product is less stable.

Test: Energy of Activation - Question 11

The rate of a chemical reaction doubles for every 10°C rise of temperature. If the tem perature is raised by 50°C, the rate of the reaction increases by about

[AIEEE 2011]

Detailed Solution for Test: Energy of Activation - Question 11

Number of ten degrees in 
Increase in rate due to 10° rise in temperature = 2
Increase in rate due to 50° rise in temperature = 25 = 32 times

Test: Energy of Activation - Question 12

A reactant A forms two products B and C as given

A  B, Activation energy Ea1

A  C, Activation energy Ea2

if Ea2 = 2Ea1, then k1 and K2 are related as 

[AIEEE 2011]

Detailed Solution for Test: Energy of Activation - Question 12






∴ 

Test: Energy of Activation - Question 13

Direction (Q. No. 14) Choices for the correct combination of elements from Column I and Column II are given as options (a), (b), (c) and (d), out of which one is correct.

  Rate constant {k) of a reaction is given by

Match the given property in Column I with its related value in Column II and select answer from codes given:

Detailed Solution for Test: Energy of Activation - Question 13

By Arrhenius equation, 

∴  
Thus, (i)→(r)

Unit of k is in min-1.

Thus, (ii)→(p)
At 500 K, 
k = 10 min-1

∴ 
10 min-1 (0.2M) = 2 M min-1
Thus (iii)→(q)


Thus, (iv)→(s)

Test: Energy of Activation - Question 14

Direction (Q. Nos. 15-18)This section contains 2 paragraphs, which describing theory, experiments, data, etc. Four questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).

Passage I

For the displacement reaction,

[Co(NH3)5Cl]2+ (aq) + H2O (l) → [Co(NH3)5H2O]3+ + Cl- (aq)

The rate constant is given by

Q. 

Rate constant at 25°C is 

Detailed Solution for Test: Energy of Activation - Question 14






Test: Energy of Activation - Question 15

Passage I

For the displacement reaction,

[Co(NH3)5Cl]2+ (aq) + H2O (l) → [Co(NH3)5H2O]3+ + Cl- (aq)

The rate constant is given by

Q. 

Energy of activation for this reaction is

Detailed Solution for Test: Energy of Activation - Question 15


At 298 K, log k (min-1)




Test: Energy of Activation - Question 16

Passage II

For the opposing reaction,

Ea (forward reaction) = 100 kJ mol-1

Pre-exponential factor A = 1.0 x 1010 M-1s-1

Q. 

The value of k1 and k2 at 700K respectively are

Detailed Solution for Test: Energy of Activation - Question 16




Also,

=345 M-1s-1




∴ 
 

Test: Energy of Activation - Question 17

Passage II

For the opposing reaction,

Ea (forward reaction) = 100 kJ mol-1

Pre-exponential factor A = 1.0 x 1010 M-1s-1

Q. 

The rate constant (k1) for the forward reaction at 1000 K is

Detailed Solution for Test: Energy of Activation - Question 17




Also,
 
345 m-1s-1




∴ 
 

*Answer can only contain numeric values
Test: Energy of Activation - Question 18

Direction (Q. Nos. 19-21) This section contains 3 questions. When worked out will result in one integer from 0 to 9 (both inclusive).

At room temperature (27°C) milk turns sour in about 64 h. In a refrigerator at -3°C, milk can be stored x times as long before it sours. The activation energy of the reaction that causes the souring of milk is 11.231 kcal mol-1.
What is the value of x?


Detailed Solution for Test: Energy of Activation - Question 18

Rate of souring of milk at 27°C (300 K) is  times faster than at-3°C(270K).
∴ 
∴ 
11.231 kcal mol-1 = 2.303 x 2 x10-3 kcal mol-1k-1

*Answer can only contain numeric values
Test: Energy of Activation - Question 19

The Arrhenius equations for the rate constant of decomposition of methyi nitrite and ethyl nitrite are


Find the temperature (in °C), at which rate contants are equal.


Detailed Solution for Test: Energy of Activation - Question 19

Both are first order reactions (unit of k beings-1)






 
 

*Answer can only contain numeric values
Test: Energy of Activation - Question 20

For the following sequence of reactions

Thus, observed Ea is .....kJ mol-1.


Detailed Solution for Test: Energy of Activation - Question 20





∴ 

*Multiple options can be correct
Test: Energy of Activation - Question 21

This section contains 2 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONE or MORE THAN ONE are correct.

Select the correct statement(s) about collision theory of reaction rates.

Detailed Solution for Test: Energy of Activation - Question 21

All the given facts (a), (b), (c) and (d) are true for Collision Theory.

*Multiple options can be correct
Test: Energy of Activation - Question 22

Consider the endothermic reaction,  X→Y

Heat o f reaction = ΔH with Ef = activation energy of the forw ard reaction.
Eb = activation energy of the backward reaction.
Then

Detailed Solution for Test: Energy of Activation - Question 22

Given reaction is an endothermic reaction ΔH > 0.

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