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Test: Nomenclature of Coordination Compounds (December 25) - NEET MCQ


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Test: Nomenclature of Coordination Compounds (December 25) - Question 1

The IUPAC name of the compound [Cr(NH3)5(NCS)][ZnCI4] is

Detailed Solution for Test: Nomenclature of Coordination Compounds (December 25) - Question 1

The lUPAC name of [Cr(NH3)5(NCS)][ZnCI4] is pentammine isothiocyanatochromium (III) tetrachlorozincate (II).

Test: Nomenclature of Coordination Compounds (December 25) - Question 2

The IUPAC name of the complex [(CO)5Mn - Mn(CO)5] is

Detailed Solution for Test: Nomenclature of Coordination Compounds (December 25) - Question 2

Correct answer is C.  bis (pentacarbonylmanganese) (0)

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Test: Nomenclature of Coordination Compounds (December 25) - Question 3

The donor sites of EDTA ligand are

Detailed Solution for Test: Nomenclature of Coordination Compounds (December 25) - Question 3

Ethylenediaminetetraacetate ion (EDTA)4- is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion.

Test: Nomenclature of Coordination Compounds (December 25) - Question 4

What is the IUPAC name of compound NaBH4?

Detailed Solution for Test: Nomenclature of Coordination Compounds (December 25) - Question 4

The IUPAC name of NaBH4 is sodium tetrahydridoborate 

*Multiple options can be correct
Test: Nomenclature of Coordination Compounds (December 25) - Question 5

Direction (Q. Nos. 11-15) This section contains 5 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONE or MORE THAN ONE are correct.

Q. 

Which of the following complexes have correct name?

Detailed Solution for Test: Nomenclature of Coordination Compounds (December 25) - Question 5

Complexes K[Pt(NH3)Cl5] and [Ag(CN)2]- have been given their respective IUPAC names.

Test: Nomenclature of Coordination Compounds (December 25) - Question 6

Comprehension Type

Direction (Q. Nos. 16 and 17) This section contains a paragraph, describing theory, experiments, data, etc. Two questions have been related to the paragraph have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).

Passage

In naming complexes, cation is named first followed by anion. Non-ionic or neutral complexes are given a one word name. The cationic and neutral complex ions are named by writing ‘the number and name of the ligands followed by the name of the central metal ion with its oxidation number in roman numerals within the parenthesis. If the complex is anionic, name of the metals ends with ‘ate’. When the complex contain two or more metal atoms linked with the help of bridging ligand then each bridging ligand is started with μ.

Q. 

Name of [CoBr(NH3)4 NO2] is

Detailed Solution for Test: Nomenclature of Coordination Compounds (December 25) - Question 6

The correct name of [CoBr(NH3)4NO2] is tetramminebromonitrocobalt (II).

Test: Nomenclature of Coordination Compounds (December 25) - Question 7

In naming complexes, cation is named first followed by anion. Non-ionic or neutral complexes are given a one word name. The cationic and neutral complex ions are named by writing ‘the number and name of the ligands followed by the name of the central metal ion with its oxidation number in roman numerals within the parenthesis. If the complex is anionic, name of the metals ends with ‘ate’. When the complex contain two or more metal atoms linked with the help of bridging ligand then each bridging ligand is started with μ.

Q. 

The IUPAC name of [Ni(NH3)4] [NiCI4] is

Detailed Solution for Test: Nomenclature of Coordination Compounds (December 25) - Question 7

The IUPAC name of [Ni(NH3)4][NiCI4] is tetramminenickel (II) tetrachloronickelate (II).

*Answer can only contain numeric values
Test: Nomenclature of Coordination Compounds (December 25) - Question 8

The oxidation state of the central metai in the complex ion [Fe(EDTA)]- .


Detailed Solution for Test: Nomenclature of Coordination Compounds (December 25) - Question 8

In [Fe(EDTA)]-, Let the oxidation state is x then
x - 4 = - 1
⇒ x = 4 - 1 = 3

*Answer can only contain numeric values
Test: Nomenclature of Coordination Compounds (December 25) - Question 9

The complex potassium dicyanodioxalatonickelate (II) in solution produce....... ions.


Detailed Solution for Test: Nomenclature of Coordination Compounds (December 25) - Question 9

The structure of potassium dicyanodio xalatonickelate (II) is
K4[Ni(CN)2(ox)2].
K4[Ni(CN)2(ox)2] →  4K+ [Ni(CN)2(ox)2]- 
This produce 5 ions in solution.

Test: Nomenclature of Coordination Compounds (December 25) - Question 10

Formula of brown ring complex is

Detailed Solution for Test: Nomenclature of Coordination Compounds (December 25) - Question 10

The brown ring test for nitrates depend on the ability of Fe2+ to reduce nitrates to nitric oxide, which reacts with Fe2+ to form a brown coloured complex.

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