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Test: Chemistry Minor Mock Test- 1 (March 16) - NEET MCQ


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Test: Chemistry Minor Mock Test- 1 (March 16) - Question 1

Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon:

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 1

Is → As it is the ground state

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 2

Direction (Q. Nos. 1-15) This section contains 15 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.

Q. Which of the following is least likely to behave as Lewis base?

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 2

Electron rich species are called lewis base. Among the given, BF3 is an electron deficient species, so have a capacity of electrons accepting instead of donating that's why it is least likely to act as a lewis base. It is a lewis acid. 

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Test: Chemistry Minor Mock Test- 1 (March 16) - Question 3

Which of the following molecules are expected to exhibit intermolecular H-bonding

I. Acetic acid

II. o-nitrophenol

III. m-nitrophenol

IV. o-boric acid

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 3



Test: Chemistry Minor Mock Test- 1 (March 16) - Question 4

Consider the following properties. 

    

Select intensive and extensive properties.

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 4

Intensive means that the property is mass independent. We can see that Boiling point, pH, EMF of cell and surface tension are intensive pont . 
While Extensive property  depends on mass and in given options Volume and entropy are mass dependents.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 5

The Value of (n2 + n1) and for He+ ion in atomic spectrum are 4 and 8 respectively. The wavelength of emitted photon when electron jump from n2 to n1 is

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 5


Test: Chemistry Minor Mock Test- 1 (March 16) - Question 6

Metalloids show the properties of

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 6

Metalloids shows both the properties of metals as well as non metals.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 7

The critical temperature of water is higher than that of O2 because the H2O molecules has :

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 7

⇒ H2O is polar molecule
⇒ Hence  H2O has higher critical temp

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 8

Among the alkali metals cesium is the most reactive because

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 8

Among the alkali metals cesium is the most reactive because the outermost electron is more loosely bound than the outermost electron of the other alkali metals.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 9

For the reaction 
Fe2 O3 (s) + 3 CO (g) → 2 Fe (g) + 3 CO2,
224 g of CO is available to react with 400 g Fe2O3, the yield of iron and CO2, are:

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 9

Moles of CO =8 moles Moles of Fe2O3= 2.5 moles.

3 moles of CO is needed for 1 mole of Fe2O3 so 8 moles of CO will require 2.66 mole of Fe2O3 so Fe2O3 is limiting reagent.

1 mole of Fe2O3 produce 2 mole of Fe so 2.5 mole of Fe2O3will produce 5 mole of Fe = 280g of Fe.

Also 1 mole of Fe2O3 also produce 3 mole of CO2 so 2.5 mole of Fe2O3 will produce 7.5 mole of CO2=330g.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 10

An element belongs to Group 15 and third period of the periodic table. Its electronic configuration will be

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 10

group is 15 so total valence electrons will be 5 while period is 3rd so n value of valence shell will be 3.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 11

The third line in Balmer series corresponds to an electronic transition between which Bohr's orbits in hydrogen :

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 11

Balmer means transition to n = 2
1. line → 3 to 2
2. line → 4 to 2
3. line → 5 to 2

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 12

For an endothermic reaction when ΔH represents the enthalpy of the reaction in kJ mol-1, the minimum value for the energy of activation will be

[IIT JEE 1992]

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 12

In endothermic reactions, the energy of reactants is less than that of the products. Potential energy diagram for endothermic reactions is,

 

Where Ea = activation energy of forwarding reaction

Ea' = activation energy of backwards reaction

ΔH = enthalpy of the reaction

 

From the above diagram,

Ea = Ea' + ΔH

Thus, Ea > ΔH

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 13

56 g of iron reacts with dilute H2SO4 at 27° C . W ork done (in cals) in

I. closed vessel of fixed volume and
II. an open vessel is

    

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 13

Use ∆H=∆U+∆NgRT FOR 1. we need to find work done in constant volume that is ∆U which will be 0 as it is nCv∆T and since ∆T is zero so ∆U is zero .
For 2. we need to Find ∆H =∆U+∆NgRT Since ∆U is zero so∆H=∆NgRT 
R=2 T =300and ∆Ng is = -1

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 14

A measured temperature is 1000F on Fahrenheit scale, then what is this reading be on Celsius scale:

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 14

C-0/100-0 = F-32/180.
C/5= F-32/9.
C/5= 100-32/9.
C/5= 68/9.
C= 68×5/9.
C= 340/9.
C= 37.77.
C= 37.8

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 15

For the following process, H2 (g) → 2 H(g), it absorbs 436 kJ mol-1. Thus,

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 15

In this process, one molecule of hydrogen gas dissociated into two gaseous atoms i.e. the number of gaseous particles increase leading to  a more disordered state. 
.Breaking of bond requires energy

It is not mentioned that the process is isobaric. If we assume that process is isobaric because volume can not remain constant as number of gaseous particles are increased, then change in internal energy = 436 kJ mol-1. The data of absorption gives us the value of q.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 16

The light radiations with discrete quantities of energy are called ___________ .

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 16

A photon is the quantum of electromagnetic radiation. The term quantum is the smallest elemental unit of a quantity, or the smallest discrete amount of something. Thus, one quantum of electromagnetic energy is called a photon. The plural of quantum is quanta.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 17

Compound with maximum ionic character is formed from :

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 17

for maximum ionic character,
* IE of cation must be less
* EA of anion must be larger
⇒ CS and  F
⇒ (B)

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 18

Suppose the elements X and Y combine to form two compounds XY2 and X3Y2. When 0.1 mole of XY2 weighs 10 g and 0.05 mole of X3Y2 weighs 9 g, the atomic weights of X and Y are

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 18

Let atomic weight of x = Mx
atomic weight of y = M

we know, 
mole = weight /atomic weight 
a/c to question, 

mole of xy2 = 0.1 
so, 
0.1 = 10g/( Mx +2My

Mx + 2My = 100g -------(1)

for x3y2 ; mole of x3y2 = 0.05 

0.05 = 9/( 3Mx + 2My

3Mx + 2My = 9/0.05 = 9 × 20 = 180 g ---(2) 
solve eqns (1) and (2)

2Mx = 80 
Mx = 40g/mol 

and My = 30g/mole

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 19

The molar mass of C6H10O is

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 19

Molar mass = 6(12) + 10(1) + 5(16) = 162g

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 20

In the following reaction,

Species behaving as Bronsted-Lowry acids are

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 20

Bronsted lowry acids are those acids which donate H+. In the reaction, A and D are giving H+. So, these both are bronsted lowry acid.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 21

The energy of electron is maximum at :

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 21

An electron bound to the nucleus by the mutual attraction between unlike charges, has a negative energy. Its most tightly bound to the nucleus nearer it is to the nucleus. That is an electron has least energy when it is in the n=1 shell. As the electron moves away from the nucleus its energy becomes less and less negative, i.e. its energy increases. When the electron is not under the attractive Coulomb force of the nucleus its potential energy is zero and whatever energy it has now, is kinetic energy, which is always positive. So farther the electron more energy it has.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 22

Which of the following will produce a buffer solution when mixed in equal volumes ?

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 22

For a buffer, we need to have a weak base/acid and its salt. Here, we have a weak base and so we will need its salt. In option c, concentration of strong acid is less than base. So we will have both a weak base and its salt. Therefore, only option c gives us a buffer solution.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 23

Direction (Q. Nos. 1-15) This section contains 15 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE option is correct.

Q. 
Assign the sign of work done (based on SI convention) in the following chemical changes taking place against external atmospheric pressure :


    

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 23

Work done = - (change in moles) RT For work done positive change in moles negative and vice versa We only cosider the moles that are in gass phase.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 24

In the modern periodic table

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 24

Horizontal rows are periods while vertical column are groups.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 25

Choose one of the following in th increasing order of bond length

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 25

As the size increases bond length also increases.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 26

Which one of the following molecular hydrides acts as a Lewis acid?

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 26

B2H6 is an electron deficient species. Soit will act as Lewis acid.

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 27

The orbital angular momentum of an electron in 2s orbital is :

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 27

Orbital Angular momentum is given by [√l(l+1)]×h/2π
For s orbital, we have l = 0
Therefore orbital angular momentum = 0

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 28

One mole of an ideal gas is put through a series of changes as shown in the figure in which 1,2,3 mark the three stages of the system. Pressure at the stages 1, 2, and 3 respectively will be (in bar)

   

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 28

Applying ideal gas eqn. at 1
p×22.4 = 1×0.0821×298        (since vol. Is in L. R should haave constaant with lit in it.)
p = 1.09 atm. To convert it into bar, we multiply it by 1.01 or we have 1.03 bar
Similarly at 2 and 3, we get value of pressure at 2 and 3. 
The most closest answer is option d

Test: Chemistry Minor Mock Test- 1 (March 16) - Question 29

The ratio of the energy of a photon of 2000 Å wavelength radiation to that of 4000 Å radiation is

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 29


Test: Chemistry Minor Mock Test- 1 (March 16) - Question 30

SI units for Base Physical Quantities of length, mass and current are

Detailed Solution for Test: Chemistry Minor Mock Test- 1 (March 16) - Question 30

M, Kg, A are SI units.

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