Direction (Q. Nos. 1-10) This section contains 10 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.
Q.
Which of the following statement is correct about the hydride of group 16 elements?
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The acid having a sulp hur atom with a lone pair of electrons on it, is
Charring of cane sugar by sulphuric acid shows ...... property of the acid.
xSo2 + yMnO-4 + zH2O → Mn2+ + SO42- + H+ . In this, three values of x, y, z are
Among the following oxyacids of sulphur, which one has more than one oxidation state for sulphur?
In SO3 molecule, 3 oxygen atoms are attached to sulphur atom through double bonds. Hence, the molecules consist 3π-bonds. The types of pi-bonds present in SO3 molecule are
Which of the following is known as C aro’s acid?
Direction (Q. No. 11) This section is based on Statements I and Statements II. Select the correct answer from the codes given below.
Q.
Statement I : In Caro’s acid (H2SO5), the oxidation state of sulphur is found to be +8.
Statement II : In Caro’s acid, sulphur atom is attached to four oxygen atoms directly.
Direction (Q. Nos. 12-15) This section contains 4 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONE or MORE THAN ONE are correct.
Q.
The incorrect statements among the following are
The chemical species having sp2-hybridisation for the central atom is
Which of the following is/are the correct statement(s) about sodium thiosulphate?
Direction (Q. Nos. 16 and 17) This section contains a paragraph, describing theory, experiments, data, etc. Two questions related to the paragraph have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).
Passage
Hydrated sodium thiosulphate, Na2S2O3 .5H2O is called hypo. It can be prepared by Spring’s reaction by adding iodine to a mixture of sodium sulphide and sodium sulphite.
Na2S + Na2SO3 + I2 → 2NaI + Na2S2O3 (Spring's reaction)
It is an efflorescent substance and at 215°C, it is completely dehydrated to Na2S2O3. Its reaction with iodine is used fo r the iodometric estimation of oxidising agents like CuSO4, CaOCI2, KMnO4, MnO2, etc., which on reaction with KI liberate I2. It is used in the bleaching industry to destroy excess chlorine on fabrics. It is used in photography as fixer since, it dissolves unexposed AgBr on the film.
Q.
Select the incorrect statement regarding hypo.
Passage
Hydrated sodium thiosulphate, Na2S2O3 .5H2O is called hypo. It can be prepared by Spring’s reaction by adding iodine to a mixture of sodium sulphide and sodium sulphite.
Na2S + Na2SO3 + I2 → 2NaI + Na2S2O3 (Spring's reaction)
It is an efflorescent substance and at 215°C, it is completely dehydrated to Na2S2O3. Its reaction with iodine is used fo r the iodometric estimation of oxidising agents like CuSO4, CaOCI2, KMnO4, MnO2, etc., which on reaction with KI liberate I2. It is used in the bleaching industry to destroy excess chlorine on fabrics. It is used in photography as fixer since, it dissolves unexposed AgBr on the film.
Q.
In Na2S4O6, sulphur has different oxidation states. They are
Direction (Q. Nos. 18-20) Choices for the correct combination of elements from Column I and Column II are given as options (a), (b), (c) and (d), out of which one is correct.
Q.
Match the Column I with Column II and mark the correct option from the codes given below.
Match the Column I with Column II and mark the correct option from the codes given below.
Match the Column I with Column II and mark the correct option from the codes given below.
Direction (Q. Nos. 21-25) This section contains 5 questions. When worked out will result in an integer from 0 to 9 (both inclusive).
Q.
The number of S—S bonds in sulphur trioxide trimer (S3O9) are
The number of metal sulphides precipitated by passing H2S in acidic medium among
ZnS, PbS, CuS, NiS, MnS, CdS, CoS, HgS, SnS.
The number of chemical species having sp3-hybridisation.
SO3, SO2, SOCI2, SO2CI2, O3, SF2, SF4,
Number of molecules having non-zero dipole moment in
O3, SO3, SF4, SF6, H2S, CS2, SO2, H2O and H2O2.
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