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Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Chemistry MCQ


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10 Questions MCQ Test Physical Chemistry - Test: Mixtures of Variable Composition: Gibbs-Duhem Equation

Test: Mixtures of Variable Composition: Gibbs-Duhem Equation for Chemistry 2024 is part of Physical Chemistry preparation. The Test: Mixtures of Variable Composition: Gibbs-Duhem Equation questions and answers have been prepared according to the Chemistry exam syllabus.The Test: Mixtures of Variable Composition: Gibbs-Duhem Equation MCQs are made for Chemistry 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation below.
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Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 1

For a system of variable composition, the internal energy depends on

Detailed Solution for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 1

If some substance is added to the system, then energy of the system increases.

Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 2

The molal chemical potential is given by

Detailed Solution for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 2

The molal chemical potential signifies the change in internal energy per unit mole of a component when S,V and number of moles of all other components are constant.

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Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 3

An equation in Gibbs energy is be given by

Detailed Solution for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 3

For this we use G=U+pV-TS and here the summation is taken for all the components present in the system.

Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 4

Chemical potential is an extensive property.

Detailed Solution for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 4

Chemical potential is an intensive property.

Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 5

The Gibbs-Duhem equation is given by

Detailed Solution for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 5

This equation shows the relationship for simultaneous changes in p,T and chemical potential.

Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 6

If the composition of system does not change, then dU = TdS - pdV.

Detailed Solution for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 6

If the composition changes, then the relation includes many other terms.

Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 7

The Gibbs entropy equation is given by

Detailed Solution for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 7

Here summation is taken for all the components present in the system.

Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 8

The equation written for Gibbs energy can also be written for

Detailed Solution for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 8

From the equation dG = Vdp – SdT + Σ[(molal chemical potential)*dn], we can write similar equations for F and H..

Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 9

If the phase of a multi-component system is enlarged, which of the following will happen?

Detailed Solution for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 9

This depends on the type of property.

Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 10

For a phase which has only one constituent,

Detailed Solution for Test: Mixtures of Variable Composition: Gibbs-Duhem Equation - Question 10

This means that chemical potential is the molar Gibbs function and is a function of p and T only.

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