Direction (Q. Nos. 1-8) This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct. Q, Which of the following pairs of compounds can be used as starting material in the synthesis of 2-phenyl-2-pentanol?

CH 3 — (CH 2 ) 2 — CH 2 Br and C 6 H 5 COOH

(CH 3 ) 2 CHCH 2 Br and PhCOCH 3

PhBr and (CH 3 ) 2 CHCH 2 COCH 3

Ethanol is converted into ethoxy ethane,

by heating excess of ethanol with conc. H 2 SO 4 at 413 K or 140ºC

by heating Ethanol with excess of conc. H 2 SO 4 at 443 K

by treating with conc. H 2 SO 4 at room temperature

by treating with conc. H 2 SO 4 at 273 K

In the reaction given below, The final major organic product is

Primary alcohol can easily be prepared from primary alkyl halide via S N 2 reaction with aqueous NaOH. However, similar method does not work for the preparation of tertiary alcohol. Which reaction can be used for the efficient preparation of tertiary alcohol {tertiary butanol) from tertiary butyl bromide?

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