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Test: Preparation and Properties of Monohalides(18 Nov) - JEE MCQ


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Test: Preparation and Properties of Monohalides(18 Nov) - Question 1

Which one of the following is more reactive towards reaction?

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Bimolecular nucleophilic substitution reaction involves reaction between reactant and nucleophile simultaneously without the formation of carbocation. Less hindered species are more reactive towards reaction. As is least hindered alkyl halide, it will show more fast reaction towards reaction.
Test: Preparation and Properties of Monohalides(18 Nov) - Question 2

Benzene reacts with -propyl chloride in the presence of anhydrous to give

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Test: Preparation and Properties of Monohalides(18 Nov) - Question 3

What is the product of the following reaction ?

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Test: Preparation and Properties of Monohalides(18 Nov) - Question 4
Identify and in the following reaction

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Ethyl chloride can be converted into ethyl alcohol either by using aqueous alkali or by moist .

Test: Preparation and Properties of Monohalides(18 Nov) - Question 5
Consider the reactions
(i)
(ii)
The mechanism of reactions (i) & (ii) are respectively
Detailed Solution for Test: Preparation and Properties of Monohalides(18 Nov) - Question 5
and
Since rearrangement do not occur in the given nucleophilic substitution reactions, therefore carbocations are not the intermediate in these reactions. Thus both the reactions occur by mechanism.
Test: Preparation and Properties of Monohalides(18 Nov) - Question 6
How many stable alkenes on reaction with HCl will produce
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Test: Preparation and Properties of Monohalides(18 Nov) - Question 7
Number of ambidentate nucleophiles among the following
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Test: Preparation and Properties of Monohalides(18 Nov) - Question 8
Number of substrates which will show rearrangement is
Detailed Solution for Test: Preparation and Properties of Monohalides(18 Nov) - Question 8
By analyzing each substrate, we find that substrates (I), (II), (IV), (VI), (VII), (VIII), and (IX) can all undergo rearrangement. So number of substates is 6.
Test: Preparation and Properties of Monohalides(18 Nov) - Question 9


How many structures for are possible?

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Test: Preparation and Properties of Monohalides(18 Nov) - Question 10
Which one of the following compounds most readily undrgoes substitution by mechanism?
Detailed Solution for Test: Preparation and Properties of Monohalides(18 Nov) - Question 10
The increasing order of the nucleophilic substitution by mechanism is tert
alkyl halide sec alkyl halide primary alkyl halide.
Compound B is primary alkyl halide.
Hence it most readily undergoes substitution by mechanism.
Note: compound is also primary alkyl halide but in it, the carbon attached to is more hindered.
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