Page 1
PAGE # 1
PART : CHEMISTRY
SECTION – 1 : (Maximum Marks : 80)
Straight Objective Type (lh/ks oLrqfu"B izdkj)
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 20 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. V 34 . 0 º E
Cu / Cu
2 ? ?
V 522 . 0 º E
Cu / Cu
? ?
? ? ?
Cu / Cu
2 º E ?
(1) 0.158V (2) –0.158 V (3) 0.182 V (4) –0.182 V
Ans. (1)
Sol.
Cu
2+
º
1
E
Cu
+
0.522
Cu
0.34
2 × 0.34 = 522 . 0 1 E
º
1
? ?
522 . 0 – 68 . 0 E
º
1
?
158 . 0 E
º
1
?
2. Correct order of electron gain enthalpy (kJ/mole) of F, Cl, Br, I
F, Cl, Br, I dh bySDVªkWu xzg.k ,UFkSYih (kJ/eksy) dk lgh Øe gS \
(1) –296, – 325, – 333, – 349
(2) –333, – 349, – 325, –296
(3) –349, – 333, – 325, – 296
(4) –325, – 333, – 349, – 296
Ans. (2)
3. Arrange the following in order of their pKb value
fuEu dks buds pKb eku ds Øe O;ofLFkr dhft, &
(A)
N NH
N
(B) CH3 –NH –CH3 (C) CH3 –CH=NH
(1) A > B > C (2) B > A > C (3) C > B > A (4) B > C > A
Ans. (3)
Sol. Option "A" represent Guanadine, the conjugate acid of which is resonance stabilised. The option 'B' is
aliphatic amine, here the 'N' is sp
3
whereas in option 'C' the 'N' is sp
2
, hence B is more basic than C.
fodYi "A" xqokusfMu izdkj dk ;kSfxd iznf'kZr djrk gS ftldk la;qXeh vEy vuqukn }kjk LFkk;hd`r gSA fodYi (B)
,fyQsfVd ,ehu iznf'kZr djrk gSA ftlesa 'N' sp
3
ladfjr gS tcfd fodYi 'C' esa 'N' sp
2
ladfjr gSA vr% B, C dh
rqyuk esa vfèkd {kkjh; gksxkA
Page 2
PAGE # 1
PART : CHEMISTRY
SECTION – 1 : (Maximum Marks : 80)
Straight Objective Type (lh/ks oLrqfu"B izdkj)
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 20 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. V 34 . 0 º E
Cu / Cu
2 ? ?
V 522 . 0 º E
Cu / Cu
? ?
? ? ?
Cu / Cu
2 º E ?
(1) 0.158V (2) –0.158 V (3) 0.182 V (4) –0.182 V
Ans. (1)
Sol.
Cu
2+
º
1
E
Cu
+
0.522
Cu
0.34
2 × 0.34 = 522 . 0 1 E
º
1
? ?
522 . 0 – 68 . 0 E
º
1
?
158 . 0 E
º
1
?
2. Correct order of electron gain enthalpy (kJ/mole) of F, Cl, Br, I
F, Cl, Br, I dh bySDVªkWu xzg.k ,UFkSYih (kJ/eksy) dk lgh Øe gS \
(1) –296, – 325, – 333, – 349
(2) –333, – 349, – 325, –296
(3) –349, – 333, – 325, – 296
(4) –325, – 333, – 349, – 296
Ans. (2)
3. Arrange the following in order of their pKb value
fuEu dks buds pKb eku ds Øe O;ofLFkr dhft, &
(A)
N NH
N
(B) CH3 –NH –CH3 (C) CH3 –CH=NH
(1) A > B > C (2) B > A > C (3) C > B > A (4) B > C > A
Ans. (3)
Sol. Option "A" represent Guanadine, the conjugate acid of which is resonance stabilised. The option 'B' is
aliphatic amine, here the 'N' is sp
3
whereas in option 'C' the 'N' is sp
2
, hence B is more basic than C.
fodYi "A" xqokusfMu izdkj dk ;kSfxd iznf'kZr djrk gS ftldk la;qXeh vEy vuqukn }kjk LFkk;hd`r gSA fodYi (B)
,fyQsfVd ,ehu iznf'kZr djrk gSA ftlesa 'N' sp
3
ladfjr gS tcfd fodYi 'C' esa 'N' sp
2
ladfjr gSA vr% B, C dh
rqyuk esa vfèkd {kkjh; gksxkA
PAGE # 2
4. 1-Methylethylene oxide
HBr
excess
? ? ? ? ? X, Product 'X' will be –
1-esfFky,sfFkyhu vkWDlkbM vkf/kD; ? ? ? ? ? ?
vkf/kD; HBr
X, mRikn 'X' gksxk &
(1)
Br
Br
(2)
Br
Br
(3)
Br Br (4)
Br
Ans. (2)
Sol.
Br
Br
O
HBr
O
H
? ?
Br
–
Br
OH
HBr
5. Correct order of Intermolecular forces
(1) Dipole – Dipole > Ion – Ion > Dipole – Ion
(2) Ion – Ion > Dipole – Dipole > Dipole – Ion
(3) Dipole – Ion > Dipole – Dipole > Ion – Ion
(4) Ion – Ion > Dipole – Ion > Dipole – Dipole
vUrjvkf.od cyksa dk lgh Øe gS &
(1) f}/kzqo – f}/kzqo > vk;u – vk;u > f}/kzqo – vk;u
(2) vk;u – vk;u > f}/kzqo – f}/kzqo > f}/kzqo – vk;u
(3) f}/kzqo – vk;u > f}/kzqo – f}/kzqo > vk;u – vk;u
(4) vk;u – vk;u > f}/kzqo – vk;u > f}/kzqo – f}/kzqo
Ans. (4)
6. Hex-3-ynal
4
(1)NaBH
? ??? ? ?
3
(2)PBr
? ?? ? ?
(3)Mg/Ether
? ?? ?? ? ?
2
(4)CO
? ?? ? ?
(5)H
?
? ? ? ? ? (X), formed product X will be:
gsDl-3-vkbuSy
4
(1)NaBH
? ??? ? ?
3
(2)PBr
? ?? ? ?
(3)Mg/Ether
? ?? ?? ? ?
2
(4)CO
? ?? ? ?
(5)H
?
? ? ? ? ? (X), izkIr mRikn X gksxk %
(1)
O
C –OH
(2)
C –OH
O
H
H
H
(3)
O
OH
(4)
O
OH
Ans. (1)
Sol.
CHO
4
NaBH
? ?? ? ?
OH
3
PBr
? ? ? ?
Br
Mg/Ether
COOH
H
?
? ? ? ?
O
C –O
2
CO
? ? ? ? MgBr
Page 3
PAGE # 1
PART : CHEMISTRY
SECTION – 1 : (Maximum Marks : 80)
Straight Objective Type (lh/ks oLrqfu"B izdkj)
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 20 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. V 34 . 0 º E
Cu / Cu
2 ? ?
V 522 . 0 º E
Cu / Cu
? ?
? ? ?
Cu / Cu
2 º E ?
(1) 0.158V (2) –0.158 V (3) 0.182 V (4) –0.182 V
Ans. (1)
Sol.
Cu
2+
º
1
E
Cu
+
0.522
Cu
0.34
2 × 0.34 = 522 . 0 1 E
º
1
? ?
522 . 0 – 68 . 0 E
º
1
?
158 . 0 E
º
1
?
2. Correct order of electron gain enthalpy (kJ/mole) of F, Cl, Br, I
F, Cl, Br, I dh bySDVªkWu xzg.k ,UFkSYih (kJ/eksy) dk lgh Øe gS \
(1) –296, – 325, – 333, – 349
(2) –333, – 349, – 325, –296
(3) –349, – 333, – 325, – 296
(4) –325, – 333, – 349, – 296
Ans. (2)
3. Arrange the following in order of their pKb value
fuEu dks buds pKb eku ds Øe O;ofLFkr dhft, &
(A)
N NH
N
(B) CH3 –NH –CH3 (C) CH3 –CH=NH
(1) A > B > C (2) B > A > C (3) C > B > A (4) B > C > A
Ans. (3)
Sol. Option "A" represent Guanadine, the conjugate acid of which is resonance stabilised. The option 'B' is
aliphatic amine, here the 'N' is sp
3
whereas in option 'C' the 'N' is sp
2
, hence B is more basic than C.
fodYi "A" xqokusfMu izdkj dk ;kSfxd iznf'kZr djrk gS ftldk la;qXeh vEy vuqukn }kjk LFkk;hd`r gSA fodYi (B)
,fyQsfVd ,ehu iznf'kZr djrk gSA ftlesa 'N' sp
3
ladfjr gS tcfd fodYi 'C' esa 'N' sp
2
ladfjr gSA vr% B, C dh
rqyuk esa vfèkd {kkjh; gksxkA
PAGE # 2
4. 1-Methylethylene oxide
HBr
excess
? ? ? ? ? X, Product 'X' will be –
1-esfFky,sfFkyhu vkWDlkbM vkf/kD; ? ? ? ? ? ?
vkf/kD; HBr
X, mRikn 'X' gksxk &
(1)
Br
Br
(2)
Br
Br
(3)
Br Br (4)
Br
Ans. (2)
Sol.
Br
Br
O
HBr
O
H
? ?
Br
–
Br
OH
HBr
5. Correct order of Intermolecular forces
(1) Dipole – Dipole > Ion – Ion > Dipole – Ion
(2) Ion – Ion > Dipole – Dipole > Dipole – Ion
(3) Dipole – Ion > Dipole – Dipole > Ion – Ion
(4) Ion – Ion > Dipole – Ion > Dipole – Dipole
vUrjvkf.od cyksa dk lgh Øe gS &
(1) f}/kzqo – f}/kzqo > vk;u – vk;u > f}/kzqo – vk;u
(2) vk;u – vk;u > f}/kzqo – f}/kzqo > f}/kzqo – vk;u
(3) f}/kzqo – vk;u > f}/kzqo – f}/kzqo > vk;u – vk;u
(4) vk;u – vk;u > f}/kzqo – vk;u > f}/kzqo – f}/kzqo
Ans. (4)
6. Hex-3-ynal
4
(1)NaBH
? ??? ? ?
3
(2)PBr
? ?? ? ?
(3)Mg/Ether
? ?? ?? ? ?
2
(4)CO
? ?? ? ?
(5)H
?
? ? ? ? ? (X), formed product X will be:
gsDl-3-vkbuSy
4
(1)NaBH
? ??? ? ?
3
(2)PBr
? ?? ? ?
(3)Mg/Ether
? ?? ?? ? ?
2
(4)CO
? ?? ? ?
(5)H
?
? ? ? ? ? (X), izkIr mRikn X gksxk %
(1)
O
C –OH
(2)
C –OH
O
H
H
H
(3)
O
OH
(4)
O
OH
Ans. (1)
Sol.
CHO
4
NaBH
? ?? ? ?
OH
3
PBr
? ? ? ?
Br
Mg/Ether
COOH
H
?
? ? ? ?
O
C –O
2
CO
? ? ? ? MgBr
PAGE # 3
7.
Cl N2 N
CH3
CH3
+ SO3
? ?
Na
? ?
'X'
, formed product 'X' is used as:
(1) Lab test of Phenol
(2) Acid base titration indicator
(3) Food colouring
(4) It can be used as an alternative to detect amino acid in place of ninhydrin
Cl N2 N
CH3
CH3
+ SO3
? ?
Na
? ?
'X'
, izkIr mRikn 'X' dk mi;ksx fd;k tkrk gS \
(1) fQukWy ds iz;ksx'kkyk ijh{k.k esa
(2) vEy {kkj vuqekiu eas lwpd ds :i esa
(3) [kk| inkFkksaZ dksa jaxhu djus esa
(4) uhugkbMªhu ds LFkku ij ,ehuksa vEy ds fuèkkZj.k gsrq bldk mi;ksx fd;k tkrk gS
Ans. (2)
Sol.
+ N2
H3C
SO3
? ?
Methyl orange
N
H3C
N=N
H3C
SO3 N
H3C
Na
?
Methyl orange is used as an indicator in acid base titration.
esfFky vkWjsat dk mi;ksx vEy {kkj vuqekiu eas lwpd ds :i esa fd;k tkrk gSA
8. In which of the following Saytzeff product will not be formed as major product ?
fuEu eas ls dkSulh vfHkfØ;k esa eq[; mRikn lSRtSQ mRikn ugha gksxk \
(A)
OH
H
+
? ?
(B)
Br
alc. KOH
? ?
(C)
Br
t BuO
–
K
+
? ?
(D)
H ? ?
O
OH
(1) Only dsoy C (2) Only dsoy B (3) A, C & D (4) B & D
Ans. (1)
Sol. (1)
OH
H
+
? ?
(2)
Br
alc. KOH
? ?
(3)
Br
t BuO
–
K
+
? ?
(4)
H ? ?
O
OH
H
O
Page 4
PAGE # 1
PART : CHEMISTRY
SECTION – 1 : (Maximum Marks : 80)
Straight Objective Type (lh/ks oLrqfu"B izdkj)
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 20 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. V 34 . 0 º E
Cu / Cu
2 ? ?
V 522 . 0 º E
Cu / Cu
? ?
? ? ?
Cu / Cu
2 º E ?
(1) 0.158V (2) –0.158 V (3) 0.182 V (4) –0.182 V
Ans. (1)
Sol.
Cu
2+
º
1
E
Cu
+
0.522
Cu
0.34
2 × 0.34 = 522 . 0 1 E
º
1
? ?
522 . 0 – 68 . 0 E
º
1
?
158 . 0 E
º
1
?
2. Correct order of electron gain enthalpy (kJ/mole) of F, Cl, Br, I
F, Cl, Br, I dh bySDVªkWu xzg.k ,UFkSYih (kJ/eksy) dk lgh Øe gS \
(1) –296, – 325, – 333, – 349
(2) –333, – 349, – 325, –296
(3) –349, – 333, – 325, – 296
(4) –325, – 333, – 349, – 296
Ans. (2)
3. Arrange the following in order of their pKb value
fuEu dks buds pKb eku ds Øe O;ofLFkr dhft, &
(A)
N NH
N
(B) CH3 –NH –CH3 (C) CH3 –CH=NH
(1) A > B > C (2) B > A > C (3) C > B > A (4) B > C > A
Ans. (3)
Sol. Option "A" represent Guanadine, the conjugate acid of which is resonance stabilised. The option 'B' is
aliphatic amine, here the 'N' is sp
3
whereas in option 'C' the 'N' is sp
2
, hence B is more basic than C.
fodYi "A" xqokusfMu izdkj dk ;kSfxd iznf'kZr djrk gS ftldk la;qXeh vEy vuqukn }kjk LFkk;hd`r gSA fodYi (B)
,fyQsfVd ,ehu iznf'kZr djrk gSA ftlesa 'N' sp
3
ladfjr gS tcfd fodYi 'C' esa 'N' sp
2
ladfjr gSA vr% B, C dh
rqyuk esa vfèkd {kkjh; gksxkA
PAGE # 2
4. 1-Methylethylene oxide
HBr
excess
? ? ? ? ? X, Product 'X' will be –
1-esfFky,sfFkyhu vkWDlkbM vkf/kD; ? ? ? ? ? ?
vkf/kD; HBr
X, mRikn 'X' gksxk &
(1)
Br
Br
(2)
Br
Br
(3)
Br Br (4)
Br
Ans. (2)
Sol.
Br
Br
O
HBr
O
H
? ?
Br
–
Br
OH
HBr
5. Correct order of Intermolecular forces
(1) Dipole – Dipole > Ion – Ion > Dipole – Ion
(2) Ion – Ion > Dipole – Dipole > Dipole – Ion
(3) Dipole – Ion > Dipole – Dipole > Ion – Ion
(4) Ion – Ion > Dipole – Ion > Dipole – Dipole
vUrjvkf.od cyksa dk lgh Øe gS &
(1) f}/kzqo – f}/kzqo > vk;u – vk;u > f}/kzqo – vk;u
(2) vk;u – vk;u > f}/kzqo – f}/kzqo > f}/kzqo – vk;u
(3) f}/kzqo – vk;u > f}/kzqo – f}/kzqo > vk;u – vk;u
(4) vk;u – vk;u > f}/kzqo – vk;u > f}/kzqo – f}/kzqo
Ans. (4)
6. Hex-3-ynal
4
(1)NaBH
? ??? ? ?
3
(2)PBr
? ?? ? ?
(3)Mg/Ether
? ?? ?? ? ?
2
(4)CO
? ?? ? ?
(5)H
?
? ? ? ? ? (X), formed product X will be:
gsDl-3-vkbuSy
4
(1)NaBH
? ??? ? ?
3
(2)PBr
? ?? ? ?
(3)Mg/Ether
? ?? ?? ? ?
2
(4)CO
? ?? ? ?
(5)H
?
? ? ? ? ? (X), izkIr mRikn X gksxk %
(1)
O
C –OH
(2)
C –OH
O
H
H
H
(3)
O
OH
(4)
O
OH
Ans. (1)
Sol.
CHO
4
NaBH
? ?? ? ?
OH
3
PBr
? ? ? ?
Br
Mg/Ether
COOH
H
?
? ? ? ?
O
C –O
2
CO
? ? ? ? MgBr
PAGE # 3
7.
Cl N2 N
CH3
CH3
+ SO3
? ?
Na
? ?
'X'
, formed product 'X' is used as:
(1) Lab test of Phenol
(2) Acid base titration indicator
(3) Food colouring
(4) It can be used as an alternative to detect amino acid in place of ninhydrin
Cl N2 N
CH3
CH3
+ SO3
? ?
Na
? ?
'X'
, izkIr mRikn 'X' dk mi;ksx fd;k tkrk gS \
(1) fQukWy ds iz;ksx'kkyk ijh{k.k esa
(2) vEy {kkj vuqekiu eas lwpd ds :i esa
(3) [kk| inkFkksaZ dksa jaxhu djus esa
(4) uhugkbMªhu ds LFkku ij ,ehuksa vEy ds fuèkkZj.k gsrq bldk mi;ksx fd;k tkrk gS
Ans. (2)
Sol.
+ N2
H3C
SO3
? ?
Methyl orange
N
H3C
N=N
H3C
SO3 N
H3C
Na
?
Methyl orange is used as an indicator in acid base titration.
esfFky vkWjsat dk mi;ksx vEy {kkj vuqekiu eas lwpd ds :i esa fd;k tkrk gSA
8. In which of the following Saytzeff product will not be formed as major product ?
fuEu eas ls dkSulh vfHkfØ;k esa eq[; mRikn lSRtSQ mRikn ugha gksxk \
(A)
OH
H
+
? ?
(B)
Br
alc. KOH
? ?
(C)
Br
t BuO
–
K
+
? ?
(D)
H ? ?
O
OH
(1) Only dsoy C (2) Only dsoy B (3) A, C & D (4) B & D
Ans. (1)
Sol. (1)
OH
H
+
? ?
(2)
Br
alc. KOH
? ?
(3)
Br
t BuO
–
K
+
? ?
(4)
H ? ?
O
OH
H
O
PAGE # 4
9. Match the column
Column-I Column-II
(A) Thiamine (P) Scurvy
(B) Riboflavin (Q) Beri Beri
(C) Pyridoxine (R) Cheilosis
(D) Ascorbic acid (S) Convulsions
fuEu dk feyku dhft, &
dkWye-I dkWye-II
(A) Fkk;kehu (P) LdohZ
(B) jkbcks¶ysfou (Q) csjh csjh
(C) ikbjhMksDlhu (R) dhyksfll (Cheilosis)
(D) ,LdksfcZd vEy (S) ejksM+ iM+uk (Convulsions)
(1) A ??Q B ??R C ??P D ??S
(2) A ??Q B ??R C ??S D ??P
(3) A ??R B ??Q C ??S D ??P
(4) A ??R B ??Q C ??P D ??S
Ans. (2)
Sol.
Vitamins Deficiency Diseases
Vitamin B1 (Thiamine) Beri Beri
Vitamin B2 (Riboflavin) Cheilosis
Vitamin B6 (Pyridoxine) Convulsions
Vitamin C (Ascorbic acid) Scurvy
foVkehu ghurk tfur jksx
foVkehu B1 (Fkk;kehu) csjh csjh
foVkehu B2 (jkbcks¶ysfou) dhyksfll
foVkehu B6 (ikbjhMksDlhu) ejksM+ iM+uk
foVkehu C (,LdksfcZd vEy) LdohZ
10. Atomic radius of Ag is similar to
Ag dh ijek.kq f=kT;k fdlds leku gksrh gS \
(1) Cu (2) Hg (3) Au (4) Ni
Ans. (3)
11. Correct IUPAC name of ? ? ? ? Cl ) NH CH ( Cl NH Pt
2 3 2 3
is:
(1) Bis(ammine)chlorido(methylamine)platinum(II) chloride
(2) Diamminechlorido(methylamine)platinum(II) chloride
(3) Diamminechlorido(aminomethyl)platinum(II) chloride
(4) Chloridobis(ammine)methylamineplatinum(II) chloride
? ? ? ? Cl ) NH CH ( Cl NH Pt
2 3 2 3
dk lgh IUPAC uke gS %
(1) fcl(,sEehu)DyksjkbMksa(esfFky,sehu)IysfVue(II) DyksjkbM
(2) MkbZ,sEehuDyksjkbMks(esfFky,sehu)IysfVue(II) DyksjkbM
(3) MkbZ,sEehuDyksjkbMks(,sehuksesfFky)IysfVue(II) DyksjkbM
(4) DyksjkbMksfcl(,sEehu)esfFky,sehuIysfVue(II) DyksjkbM
Ans. (2)
Page 5
PAGE # 1
PART : CHEMISTRY
SECTION – 1 : (Maximum Marks : 80)
Straight Objective Type (lh/ks oLrqfu"B izdkj)
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 20 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. V 34 . 0 º E
Cu / Cu
2 ? ?
V 522 . 0 º E
Cu / Cu
? ?
? ? ?
Cu / Cu
2 º E ?
(1) 0.158V (2) –0.158 V (3) 0.182 V (4) –0.182 V
Ans. (1)
Sol.
Cu
2+
º
1
E
Cu
+
0.522
Cu
0.34
2 × 0.34 = 522 . 0 1 E
º
1
? ?
522 . 0 – 68 . 0 E
º
1
?
158 . 0 E
º
1
?
2. Correct order of electron gain enthalpy (kJ/mole) of F, Cl, Br, I
F, Cl, Br, I dh bySDVªkWu xzg.k ,UFkSYih (kJ/eksy) dk lgh Øe gS \
(1) –296, – 325, – 333, – 349
(2) –333, – 349, – 325, –296
(3) –349, – 333, – 325, – 296
(4) –325, – 333, – 349, – 296
Ans. (2)
3. Arrange the following in order of their pKb value
fuEu dks buds pKb eku ds Øe O;ofLFkr dhft, &
(A)
N NH
N
(B) CH3 –NH –CH3 (C) CH3 –CH=NH
(1) A > B > C (2) B > A > C (3) C > B > A (4) B > C > A
Ans. (3)
Sol. Option "A" represent Guanadine, the conjugate acid of which is resonance stabilised. The option 'B' is
aliphatic amine, here the 'N' is sp
3
whereas in option 'C' the 'N' is sp
2
, hence B is more basic than C.
fodYi "A" xqokusfMu izdkj dk ;kSfxd iznf'kZr djrk gS ftldk la;qXeh vEy vuqukn }kjk LFkk;hd`r gSA fodYi (B)
,fyQsfVd ,ehu iznf'kZr djrk gSA ftlesa 'N' sp
3
ladfjr gS tcfd fodYi 'C' esa 'N' sp
2
ladfjr gSA vr% B, C dh
rqyuk esa vfèkd {kkjh; gksxkA
PAGE # 2
4. 1-Methylethylene oxide
HBr
excess
? ? ? ? ? X, Product 'X' will be –
1-esfFky,sfFkyhu vkWDlkbM vkf/kD; ? ? ? ? ? ?
vkf/kD; HBr
X, mRikn 'X' gksxk &
(1)
Br
Br
(2)
Br
Br
(3)
Br Br (4)
Br
Ans. (2)
Sol.
Br
Br
O
HBr
O
H
? ?
Br
–
Br
OH
HBr
5. Correct order of Intermolecular forces
(1) Dipole – Dipole > Ion – Ion > Dipole – Ion
(2) Ion – Ion > Dipole – Dipole > Dipole – Ion
(3) Dipole – Ion > Dipole – Dipole > Ion – Ion
(4) Ion – Ion > Dipole – Ion > Dipole – Dipole
vUrjvkf.od cyksa dk lgh Øe gS &
(1) f}/kzqo – f}/kzqo > vk;u – vk;u > f}/kzqo – vk;u
(2) vk;u – vk;u > f}/kzqo – f}/kzqo > f}/kzqo – vk;u
(3) f}/kzqo – vk;u > f}/kzqo – f}/kzqo > vk;u – vk;u
(4) vk;u – vk;u > f}/kzqo – vk;u > f}/kzqo – f}/kzqo
Ans. (4)
6. Hex-3-ynal
4
(1)NaBH
? ??? ? ?
3
(2)PBr
? ?? ? ?
(3)Mg/Ether
? ?? ?? ? ?
2
(4)CO
? ?? ? ?
(5)H
?
? ? ? ? ? (X), formed product X will be:
gsDl-3-vkbuSy
4
(1)NaBH
? ??? ? ?
3
(2)PBr
? ?? ? ?
(3)Mg/Ether
? ?? ?? ? ?
2
(4)CO
? ?? ? ?
(5)H
?
? ? ? ? ? (X), izkIr mRikn X gksxk %
(1)
O
C –OH
(2)
C –OH
O
H
H
H
(3)
O
OH
(4)
O
OH
Ans. (1)
Sol.
CHO
4
NaBH
? ?? ? ?
OH
3
PBr
? ? ? ?
Br
Mg/Ether
COOH
H
?
? ? ? ?
O
C –O
2
CO
? ? ? ? MgBr
PAGE # 3
7.
Cl N2 N
CH3
CH3
+ SO3
? ?
Na
? ?
'X'
, formed product 'X' is used as:
(1) Lab test of Phenol
(2) Acid base titration indicator
(3) Food colouring
(4) It can be used as an alternative to detect amino acid in place of ninhydrin
Cl N2 N
CH3
CH3
+ SO3
? ?
Na
? ?
'X'
, izkIr mRikn 'X' dk mi;ksx fd;k tkrk gS \
(1) fQukWy ds iz;ksx'kkyk ijh{k.k esa
(2) vEy {kkj vuqekiu eas lwpd ds :i esa
(3) [kk| inkFkksaZ dksa jaxhu djus esa
(4) uhugkbMªhu ds LFkku ij ,ehuksa vEy ds fuèkkZj.k gsrq bldk mi;ksx fd;k tkrk gS
Ans. (2)
Sol.
+ N2
H3C
SO3
? ?
Methyl orange
N
H3C
N=N
H3C
SO3 N
H3C
Na
?
Methyl orange is used as an indicator in acid base titration.
esfFky vkWjsat dk mi;ksx vEy {kkj vuqekiu eas lwpd ds :i esa fd;k tkrk gSA
8. In which of the following Saytzeff product will not be formed as major product ?
fuEu eas ls dkSulh vfHkfØ;k esa eq[; mRikn lSRtSQ mRikn ugha gksxk \
(A)
OH
H
+
? ?
(B)
Br
alc. KOH
? ?
(C)
Br
t BuO
–
K
+
? ?
(D)
H ? ?
O
OH
(1) Only dsoy C (2) Only dsoy B (3) A, C & D (4) B & D
Ans. (1)
Sol. (1)
OH
H
+
? ?
(2)
Br
alc. KOH
? ?
(3)
Br
t BuO
–
K
+
? ?
(4)
H ? ?
O
OH
H
O
PAGE # 4
9. Match the column
Column-I Column-II
(A) Thiamine (P) Scurvy
(B) Riboflavin (Q) Beri Beri
(C) Pyridoxine (R) Cheilosis
(D) Ascorbic acid (S) Convulsions
fuEu dk feyku dhft, &
dkWye-I dkWye-II
(A) Fkk;kehu (P) LdohZ
(B) jkbcks¶ysfou (Q) csjh csjh
(C) ikbjhMksDlhu (R) dhyksfll (Cheilosis)
(D) ,LdksfcZd vEy (S) ejksM+ iM+uk (Convulsions)
(1) A ??Q B ??R C ??P D ??S
(2) A ??Q B ??R C ??S D ??P
(3) A ??R B ??Q C ??S D ??P
(4) A ??R B ??Q C ??P D ??S
Ans. (2)
Sol.
Vitamins Deficiency Diseases
Vitamin B1 (Thiamine) Beri Beri
Vitamin B2 (Riboflavin) Cheilosis
Vitamin B6 (Pyridoxine) Convulsions
Vitamin C (Ascorbic acid) Scurvy
foVkehu ghurk tfur jksx
foVkehu B1 (Fkk;kehu) csjh csjh
foVkehu B2 (jkbcks¶ysfou) dhyksfll
foVkehu B6 (ikbjhMksDlhu) ejksM+ iM+uk
foVkehu C (,LdksfcZd vEy) LdohZ
10. Atomic radius of Ag is similar to
Ag dh ijek.kq f=kT;k fdlds leku gksrh gS \
(1) Cu (2) Hg (3) Au (4) Ni
Ans. (3)
11. Correct IUPAC name of ? ? ? ? Cl ) NH CH ( Cl NH Pt
2 3 2 3
is:
(1) Bis(ammine)chlorido(methylamine)platinum(II) chloride
(2) Diamminechlorido(methylamine)platinum(II) chloride
(3) Diamminechlorido(aminomethyl)platinum(II) chloride
(4) Chloridobis(ammine)methylamineplatinum(II) chloride
? ? ? ? Cl ) NH CH ( Cl NH Pt
2 3 2 3
dk lgh IUPAC uke gS %
(1) fcl(,sEehu)DyksjkbMksa(esfFky,sehu)IysfVue(II) DyksjkbM
(2) MkbZ,sEehuDyksjkbMks(esfFky,sehu)IysfVue(II) DyksjkbM
(3) MkbZ,sEehuDyksjkbMks(,sehuksesfFky)IysfVue(II) DyksjkbM
(4) DyksjkbMksfcl(,sEehu)esfFky,sehuIysfVue(II) DyksjkbM
Ans. (2)
PAGE # 5
12. Vapour pressure of pure CS2 and CH3COCH3 are 512 mm of Hg and 312 mm of Hg respectively. Total
vapour pressure of mixture is 600 mm of Hg then find incorrect statement:
(1) B A
B B
A A
? ? ? ?
?
?
?
? ? ?
? ? ?
(2) Does not obey Raoult's law
(3) Endothermic solution
(4) after adding 100 ml of each, then net volume is less than 200 ml
'kq) CS2 rFkk CH3COCH3 dk ok"i nkc Øe'k% 512 mm Hg rFkk 312 mm Hg gSA buds feJ.k dk dqy ok"i nkc
600 mm Hg gS rc vlR; dFku dh igpku dhft, &
(1) B A
B B
A A
? ? ? ?
?
?
?
? ? ?
? ? ?
(2) jkmYV fu;e dh vuqikyuk ugha djrk gSA
(3) Å"ek'kks"kh foy;u
(4) izR;sd ds 100 ml feykus ij ifj.kkeh vk;ru 200 ml ls de ik;k tkrk gSA
Ans. (4)
Sol. Above mixture of liquids show positive deviation from Raoult's Law
mijksDr feJ.k jkmYV fu;e ls /kukRed fopyu n'kkZrk gSA
13. Purest form of commercial iron is:
(1) Wrought iron (2) Cast iron (3) Pig iron (4) Iron scrap + pig iron
vkS|ksfxd ykSgs dk 'kq)r~e :i gS &
(1) fiVok ykSgk (Wrought iron) (2) <yok ykSgk (Cast iron)
(3) dPpk ykSgk (Pig iron) (4) jn~nh ykSgk + dPpk ykSgk (Iron scrap + pig iron)
Ans. (1)
Sol. Purest form is wrought iron.
vkS|ksfxd ykSgs dk 'kq)r~e :I fiVok ykSgk (Wrought iron) gSA
14.
COOH
Cl
(x)
OH
Cl
(y)
NH2
Cl
(z)
Mixture of above three organic compound was subjected to aq NaHCO3 and followed by dil NaOH.
compounds which will be soluble in given solvent will be :
(1) x in aq NaHCO3 and y in dil. NaOH.
(2) x in aq NaHCO3 and z in dil. NaOH.
(3) y in aq NaHCO3 and x in dil. NaOH.
(4) y is aq NaHCO3 and z in dil. NaOH.
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