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Page 1 Kinetic Theory Page 2 Kinetic Theory In t r o d u c t io n The behaviour of gases has fascinated scientists for centuries. Early thinkers (Boyle, Newton, Dalton) explained gases as tiny moving particles. Maxwell and Boltzmann developed the kinetic theory of gases in the 19th century. In gases, interatomic forces are negligible as particles are far apart (unlike solids and liquids). Kinetic theory successfully explains: Pressure and temperature Gas laws Specific heats Viscosity Diffusion All these phenomena connect to molecular motion. Page 3 Kinetic Theory In t r o d u c t io n The behaviour of gases has fascinated scientists for centuries. Early thinkers (Boyle, Newton, Dalton) explained gases as tiny moving particles. Maxwell and Boltzmann developed the kinetic theory of gases in the 19th century. In gases, interatomic forces are negligible as particles are far apart (unlike solids and liquids). Kinetic theory successfully explains: Pressure and temperature Gas laws Specific heats Viscosity Diffusion All these phenomena connect to molecular motion. Molecular Nature of Matter Atomic Hypothesis Richard Feynman famously highlighted the atomic hypothesis: "All things are made of atoms 4 tiny particles in constant motion, attracting each other at a distance and repelling when squeezed." Historical Context This idea, known since ancient times in India (Kanada's Vaiseshika philosophy) and Greece (Democritus), was scientifically formulated by John Dalton in the 19th century. Dalton's atomic theory explained how elements combine in definite ratios. Modern Evidence Modern evidence 4 like observations from electron microscopes 4 confirms that matter consists of molecules spaced at varying distances: In solids, atoms are packed closely (around 2 Å apart). In liquids, atoms are still close but free to move. In gases, atoms are far apart with large mean free paths (thousands of Å). This molecular picture explains properties like compressibility, flow, and dispersion in gases. Page 4 Kinetic Theory In t r o d u c t io n The behaviour of gases has fascinated scientists for centuries. Early thinkers (Boyle, Newton, Dalton) explained gases as tiny moving particles. Maxwell and Boltzmann developed the kinetic theory of gases in the 19th century. In gases, interatomic forces are negligible as particles are far apart (unlike solids and liquids). Kinetic theory successfully explains: Pressure and temperature Gas laws Specific heats Viscosity Diffusion All these phenomena connect to molecular motion. Molecular Nature of Matter Atomic Hypothesis Richard Feynman famously highlighted the atomic hypothesis: "All things are made of atoms 4 tiny particles in constant motion, attracting each other at a distance and repelling when squeezed." Historical Context This idea, known since ancient times in India (Kanada's Vaiseshika philosophy) and Greece (Democritus), was scientifically formulated by John Dalton in the 19th century. Dalton's atomic theory explained how elements combine in definite ratios. Modern Evidence Modern evidence 4 like observations from electron microscopes 4 confirms that matter consists of molecules spaced at varying distances: In solids, atoms are packed closely (around 2 Å apart). In liquids, atoms are still close but free to move. In gases, atoms are far apart with large mean free paths (thousands of Å). This molecular picture explains properties like compressibility, flow, and dispersion in gases. Behaviour of Gases Ideal Gas Approximation: Gases are simpler to study because the particles interact only when they collide. At low pressures and high temperatures, real gases approximate an ideal gas, satisfying: PV = KT. Where T is temperature in kelvin and K is a constant for the given gas. Molecular Connection: Connecting this with the number of molecules: K = NkB kB is Boltzmann's constant. Page 5 Kinetic Theory In t r o d u c t io n The behaviour of gases has fascinated scientists for centuries. Early thinkers (Boyle, Newton, Dalton) explained gases as tiny moving particles. Maxwell and Boltzmann developed the kinetic theory of gases in the 19th century. In gases, interatomic forces are negligible as particles are far apart (unlike solids and liquids). Kinetic theory successfully explains: Pressure and temperature Gas laws Specific heats Viscosity Diffusion All these phenomena connect to molecular motion. Molecular Nature of Matter Atomic Hypothesis Richard Feynman famously highlighted the atomic hypothesis: "All things are made of atoms 4 tiny particles in constant motion, attracting each other at a distance and repelling when squeezed." Historical Context This idea, known since ancient times in India (Kanada's Vaiseshika philosophy) and Greece (Democritus), was scientifically formulated by John Dalton in the 19th century. Dalton's atomic theory explained how elements combine in definite ratios. Modern Evidence Modern evidence 4 like observations from electron microscopes 4 confirms that matter consists of molecules spaced at varying distances: In solids, atoms are packed closely (around 2 Å apart). In liquids, atoms are still close but free to move. In gases, atoms are far apart with large mean free paths (thousands of Å). This molecular picture explains properties like compressibility, flow, and dispersion in gases. Behaviour of Gases Ideal Gas Approximation: Gases are simpler to study because the particles interact only when they collide. At low pressures and high temperatures, real gases approximate an ideal gas, satisfying: PV = KT. Where T is temperature in kelvin and K is a constant for the given gas. Molecular Connection: Connecting this with the number of molecules: K = NkB kB is Boltzmann's constant. Avogadro's Hypothesis: This leads to Avogadro's hypothesis 4 equal volumes of gases at the same temperature and pressure contain the same number of molecules. Ideal Gas Equation: The ideal gas equation: PV = ¿RT ¿ = number of moles R = universal gas constant T = absolute temperature Dalton's Law: Dalton's law of partial pressures states that the total pressure of a gas mixture equals the sum of the partial pressures of its components.Read More
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1. What is the kinetic theory of gases? | ![]() |
2. How does temperature affect the kinetic energy of gas particles? | ![]() |
3. What is the relationship between pressure and volume in the kinetic theory of gases? | ![]() |
4. How does the number of gas particles affect the pressure of a gas? | ![]() |
5. What is the relationship between the root mean square speed of gas particles and temperature? | ![]() |