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Important Alkyl Halide Formulas for JEE and NEET

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?  Points to remember in Alkyl halide
Nucleophilic substitution Reaction (S
N
1, S
N
2)
S
N
1 reaction :
R?X + H
2
O 
3
AgNO
???? ?
 R
+
 + AgX?
?? ?
ROH (R may rearrange)
Alkylhalide are hydrolysed to alcohol very slowly by water, but rapidly by
silver oxide suspended in boiling water.
S
N
2 reaction :
Mechanism :  
HO   R ? X 
?
 
?? ?
 
? ?
X
....
R
....
O H
? ?
 
?? ?
HO ? R + X
?
HO
?
 + 
C
b
d
X
a
?? ?
 
b
d
a
? ?
X
....
C
....
O H
? ?
?? ?
 
C
HO
d
b
a
 + X
?
      
  
             
          
           
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