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Hydrocarbons: JEE Main Previous Year Questions (2021-2026)

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JEE Main Previous Year Questions (2021-2026): 
Hydrocarbons  
 
(January 2026) 
 
Q1: Arrange the following alkenes in decreasing order of stability. 
 
Choose the correct answer from the options given below: 
A: III > I > II > IV 
B: III > II > I > IV 
C: I > III > II > IV 
D: I > III > IV > II 
Answer: C 
Explanation: 
Page 2


JEE Main Previous Year Questions (2021-2026): 
Hydrocarbons  
 
(January 2026) 
 
Q1: Arrange the following alkenes in decreasing order of stability. 
 
Choose the correct answer from the options given below: 
A: III > I > II > IV 
B: III > II > I > IV 
C: I > III > II > IV 
D: I > III > IV > II 
Answer: C 
Explanation: 
 
Trans is more stable than cis. 
 
Q2: But-2-yne and hydrogen (one mole each) are separately treated with (i) Pd/C and (ii) 
Na/liq. NH
3
 to give the products X and Y respectively. 
 
Identify the incorrect statements. 
A. X and Y are stereoisomers. 
B. Dipole moment of X is zero. 
C. Boiling point of X is higher than Y . 
D. X and Y react with O3/Zn+H2O to give different products.  
Choose the correct answer from the options given below: 
A: B and D Only 
B: A and C Only 
C: A and B Only 
D: B and C Only 
Answer: A 
Explanation:  
Page 3


JEE Main Previous Year Questions (2021-2026): 
Hydrocarbons  
 
(January 2026) 
 
Q1: Arrange the following alkenes in decreasing order of stability. 
 
Choose the correct answer from the options given below: 
A: III > I > II > IV 
B: III > II > I > IV 
C: I > III > II > IV 
D: I > III > IV > II 
Answer: C 
Explanation: 
 
Trans is more stable than cis. 
 
Q2: But-2-yne and hydrogen (one mole each) are separately treated with (i) Pd/C and (ii) 
Na/liq. NH
3
 to give the products X and Y respectively. 
 
Identify the incorrect statements. 
A. X and Y are stereoisomers. 
B. Dipole moment of X is zero. 
C. Boiling point of X is higher than Y . 
D. X and Y react with O3/Zn+H2O to give different products.  
Choose the correct answer from the options given below: 
A: B and D Only 
B: A and C Only 
C: A and B Only 
D: B and C Only 
Answer: A 
Explanation:  
 
Dipole moment ? 0 
 
 
Q3: 
The ?nal product [B] is : 
A:  
Page 4


JEE Main Previous Year Questions (2021-2026): 
Hydrocarbons  
 
(January 2026) 
 
Q1: Arrange the following alkenes in decreasing order of stability. 
 
Choose the correct answer from the options given below: 
A: III > I > II > IV 
B: III > II > I > IV 
C: I > III > II > IV 
D: I > III > IV > II 
Answer: C 
Explanation: 
 
Trans is more stable than cis. 
 
Q2: But-2-yne and hydrogen (one mole each) are separately treated with (i) Pd/C and (ii) 
Na/liq. NH
3
 to give the products X and Y respectively. 
 
Identify the incorrect statements. 
A. X and Y are stereoisomers. 
B. Dipole moment of X is zero. 
C. Boiling point of X is higher than Y . 
D. X and Y react with O3/Zn+H2O to give different products.  
Choose the correct answer from the options given below: 
A: B and D Only 
B: A and C Only 
C: A and B Only 
D: B and C Only 
Answer: A 
Explanation:  
 
Dipole moment ? 0 
 
 
Q3: 
The ?nal product [B] is : 
A:  
B:  
C:  
D:  
Answer: A 
Explanation: 
 
 
Q4: Consider the following reaction: 
Page 5


JEE Main Previous Year Questions (2021-2026): 
Hydrocarbons  
 
(January 2026) 
 
Q1: Arrange the following alkenes in decreasing order of stability. 
 
Choose the correct answer from the options given below: 
A: III > I > II > IV 
B: III > II > I > IV 
C: I > III > II > IV 
D: I > III > IV > II 
Answer: C 
Explanation: 
 
Trans is more stable than cis. 
 
Q2: But-2-yne and hydrogen (one mole each) are separately treated with (i) Pd/C and (ii) 
Na/liq. NH
3
 to give the products X and Y respectively. 
 
Identify the incorrect statements. 
A. X and Y are stereoisomers. 
B. Dipole moment of X is zero. 
C. Boiling point of X is higher than Y . 
D. X and Y react with O3/Zn+H2O to give different products.  
Choose the correct answer from the options given below: 
A: B and D Only 
B: A and C Only 
C: A and B Only 
D: B and C Only 
Answer: A 
Explanation:  
 
Dipole moment ? 0 
 
 
Q3: 
The ?nal product [B] is : 
A:  
B:  
C:  
D:  
Answer: A 
Explanation: 
 
 
Q4: Consider the following reaction: 
The 
product Y formed is: 
A: 2-methylhex-3-yne 
B: 5-methylhex-2-yne 
C: Isopropylbut-1-yne 
D: 2-methylhex-2-yne 
Answer: A 
Explanation:  
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FAQs on Hydrocarbons: JEE Main Previous Year Questions (2021-2026)

1. How do I identify whether a hydrocarbon is alkane, alkene, or alkyne in JEE Main questions?
Ans. Alkanes contain only C-C single bonds (general formula CₙH₂ₙ₊₂), alkenes have at least one C=C double bond (CₙH₂ₙ), and alkynes contain C≡C triple bonds (CₙH₂ₙ₋₂). Check the molecular formula or structure diagram-the number of hydrogen atoms relative to carbon atoms reveals the unsaturation level. This distinction is fundamental for answering JEE previous year questions on hydrocarbon classification.
2. What are the most common isomerism patterns asked in JEE Main hydrocarbons questions from 2021-2026?
Ans. Structural isomerism (chain, position, functional group) and geometrical isomerism (cis-trans in alkenes) dominate JEE exam papers. Students frequently encounter questions requiring them to draw or identify all possible isomers of C₅H₁₀ or C₆H₁₂. Understanding branching patterns and double bond positions is essential for solving hydrocarbon previous year questions accurately.
3. Why do some alkenes show cis-trans isomerism while others don't in JEE chemistry?
Ans. Geometric isomerism occurs only when both carbons of a C=C double bond have different substituents (no symmetry). If either carbon bears identical groups, free rotation restriction doesn't create distinct isomers. This concept appears repeatedly in JEE Main previous year questions testing conceptual depth beyond mere nomenclature.
4. How should I approach combustion and addition reaction questions on JEE hydrocarbon papers?
Ans. For combustion: use CₙH₂ₘOₓ + O₂ → CO₂ + H₂O, then balance systematically. For addition reactions: alkenes and alkynes add H₂, halogens, or HX across unsaturated bonds following Markovnikov's rule. Most JEE questions test reaction sequence prediction rather than mere equation balancing-focus on mechanism and product formation.
5. Which aromaticity rules and benzene substitution patterns are most tested in JEE Main previous year hydrocarbons questions?
Ans. Hückel's rule (4n+2 π electrons), ortho/para/meta directing effects in monosubstituted benzene, and polysubstitution patterns dominate JEE papers. Candidates should master electrophilic aromatic substitution mechanisms and how electron-donating versus electron-withdrawing groups influence reactivity. Refer to mind maps and flashcards to memorise directing group classifications quickly.
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