Page 1
Properties of Fluids
Definition of Fluid
A fluid is a substance which deforms continuously when subjected to external
shearing forces.
Characteristics of Fluid
1. It has no definite shape of its own, but conforms to the shape of the containing
vessel.
2. Even a small amount of shear force exerted on a fluid will cause it to undergo
a deformation which continues as long as the force continues to be applied.
3. It is interesting to note that a solid suffers strain when subjected to shear
forces whereas a fluid suffers Rate of Strain i.e. it flows under similar
circumstances.
Concept of Continuum
The concept of continuum is a kind of idealization of the continuous description of
matter where the properties of the matter are considered as continuous functions
of space variables. Although any matter is composed of several molecules, the
concept of continuum assumes a continuous distribution of mass within the matter
or system with no empty space, instead of the actual conglomeration of separate
molecules.
Describing a fluid flow quantitatively makes it necessary to assume that flow
variables (pressure, velocity etc.) and fluid properties vary continuously from one
point to another. Mathematical descriptions of flow on this basis have proved to be reliable
and treatment of fluid medium as a continuum has firmly become established.
For example density at a point is normally defined as
Here ? is the volume of the fluid element and m is the mass
If ? is very large ? is affected by the inhomogeneities in the fluid medium.
Considering another extreme if ? is very small, random movement of atoms (or
molecules) would change their number at different times. In the continuum
approximation point density is defined at the smallest magnitude of ? , before
statistical fluctuations become significant. This is called continuum limit and is
denoted by ? c.
One of the factors considered important in determining the validity of continuum
model is molecular density. It is the distance between the molecules which is
Page 4 of 307
Page 2
Properties of Fluids
Definition of Fluid
A fluid is a substance which deforms continuously when subjected to external
shearing forces.
Characteristics of Fluid
1. It has no definite shape of its own, but conforms to the shape of the containing
vessel.
2. Even a small amount of shear force exerted on a fluid will cause it to undergo
a deformation which continues as long as the force continues to be applied.
3. It is interesting to note that a solid suffers strain when subjected to shear
forces whereas a fluid suffers Rate of Strain i.e. it flows under similar
circumstances.
Concept of Continuum
The concept of continuum is a kind of idealization of the continuous description of
matter where the properties of the matter are considered as continuous functions
of space variables. Although any matter is composed of several molecules, the
concept of continuum assumes a continuous distribution of mass within the matter
or system with no empty space, instead of the actual conglomeration of separate
molecules.
Describing a fluid flow quantitatively makes it necessary to assume that flow
variables (pressure, velocity etc.) and fluid properties vary continuously from one
point to another. Mathematical descriptions of flow on this basis have proved to be reliable
and treatment of fluid medium as a continuum has firmly become established.
For example density at a point is normally defined as
Here ? is the volume of the fluid element and m is the mass
If ? is very large ? is affected by the inhomogeneities in the fluid medium.
Considering another extreme if ? is very small, random movement of atoms (or
molecules) would change their number at different times. In the continuum
approximation point density is defined at the smallest magnitude of ? , before
statistical fluctuations become significant. This is called continuum limit and is
denoted by ? c.
One of the factors considered important in determining the validity of continuum
model is molecular density. It is the distance between the molecules which is
Page 4 of 307
characterised by mean free path ( ? ). It is calculated by finding statistical average
distance the molecules travel between two successive collisions. If the mean free
path is very small as compared with some characteristic length in the flow domain
(i.e., the molecular density is very high) then the gas can be treated as a
continuous medium. If the mean free path is large in comparison to some
characteristic length, the gas cannot be considered continuous and it should be
analysed by the molecular theory.
A dimensionless parameter known as Knudsen number, K
n
= ? / L, where ? is the
mean free path and L is the characteristic length. It describes the degree of
departure from continuum.
Usually when K
n
> 0.01, the concept of continuum does not hold good.
Beyond this critical range of Knudsen number, the flows are known as
slip flow (0.01 < K
n
< 0.1),
transition flow (0.1 < K
n
< 10) and
free-molecule flow (K
n
> 10).
However, for the flow regimes considered in this course, K n is always less than 0.01
and it is usual to say that the fluid is a continuum.
Other factor which checks the validity of continuum is the elapsed time between
collisions. The time should be small enough so that the random statistical
description of molecular activity holds good.
In continuum approach, fluid properties such as density, viscosity, thermal
conductivity, temperature, etc. can be expressed as continuous functions of space
and time.
Ideal and Real Fluids
1. Ideal Fluid
An ideal fluid is one which has
no viscosity
no surface tension
and incompressible
2. Real Fluid
An Real fluid is one which has
viscosity
surface tension
and compressible
Naturally available all fluids are real fluid.
Viscosity
Definition: Viscosity is the property of a fluid which determines its resistance to
shearing stresses.
Cause of Viscosity: It is due to cohesion and molecular momentum exchange
between fluid layers.
Newton’s Law of Viscosity: It states that the shear stress (t) on a fluid element
layer is directly proportional to the rate of shear strain.
The constant of proportionality is called the co-efficient of viscosity.
Page 3
Properties of Fluids
Definition of Fluid
A fluid is a substance which deforms continuously when subjected to external
shearing forces.
Characteristics of Fluid
1. It has no definite shape of its own, but conforms to the shape of the containing
vessel.
2. Even a small amount of shear force exerted on a fluid will cause it to undergo
a deformation which continues as long as the force continues to be applied.
3. It is interesting to note that a solid suffers strain when subjected to shear
forces whereas a fluid suffers Rate of Strain i.e. it flows under similar
circumstances.
Concept of Continuum
The concept of continuum is a kind of idealization of the continuous description of
matter where the properties of the matter are considered as continuous functions
of space variables. Although any matter is composed of several molecules, the
concept of continuum assumes a continuous distribution of mass within the matter
or system with no empty space, instead of the actual conglomeration of separate
molecules.
Describing a fluid flow quantitatively makes it necessary to assume that flow
variables (pressure, velocity etc.) and fluid properties vary continuously from one
point to another. Mathematical descriptions of flow on this basis have proved to be reliable
and treatment of fluid medium as a continuum has firmly become established.
For example density at a point is normally defined as
Here ? is the volume of the fluid element and m is the mass
If ? is very large ? is affected by the inhomogeneities in the fluid medium.
Considering another extreme if ? is very small, random movement of atoms (or
molecules) would change their number at different times. In the continuum
approximation point density is defined at the smallest magnitude of ? , before
statistical fluctuations become significant. This is called continuum limit and is
denoted by ? c.
One of the factors considered important in determining the validity of continuum
model is molecular density. It is the distance between the molecules which is
Page 4 of 307
characterised by mean free path ( ? ). It is calculated by finding statistical average
distance the molecules travel between two successive collisions. If the mean free
path is very small as compared with some characteristic length in the flow domain
(i.e., the molecular density is very high) then the gas can be treated as a
continuous medium. If the mean free path is large in comparison to some
characteristic length, the gas cannot be considered continuous and it should be
analysed by the molecular theory.
A dimensionless parameter known as Knudsen number, K
n
= ? / L, where ? is the
mean free path and L is the characteristic length. It describes the degree of
departure from continuum.
Usually when K
n
> 0.01, the concept of continuum does not hold good.
Beyond this critical range of Knudsen number, the flows are known as
slip flow (0.01 < K
n
< 0.1),
transition flow (0.1 < K
n
< 10) and
free-molecule flow (K
n
> 10).
However, for the flow regimes considered in this course, K n is always less than 0.01
and it is usual to say that the fluid is a continuum.
Other factor which checks the validity of continuum is the elapsed time between
collisions. The time should be small enough so that the random statistical
description of molecular activity holds good.
In continuum approach, fluid properties such as density, viscosity, thermal
conductivity, temperature, etc. can be expressed as continuous functions of space
and time.
Ideal and Real Fluids
1. Ideal Fluid
An ideal fluid is one which has
no viscosity
no surface tension
and incompressible
2. Real Fluid
An Real fluid is one which has
viscosity
surface tension
and compressible
Naturally available all fluids are real fluid.
Viscosity
Definition: Viscosity is the property of a fluid which determines its resistance to
shearing stresses.
Cause of Viscosity: It is due to cohesion and molecular momentum exchange
between fluid layers.
Newton’s Law of Viscosity: It states that the shear stress (t) on a fluid element
layer is directly proportional to the rate of shear strain.
The constant of proportionality is called the co-efficient of viscosity.
When two layers of fluid, at a distance ‘dy’
apart, move one over the other at different
velocities, say u and u+du.
Velocity gradient =
du
dy
According to Newton’s law
du
dy
t 8
or
=
du
dy
t µ
Velocity Variation near a solid
boundary
Where
µ
= constant of proportionality and is known as co-efficient of Dynamic
viscosity or only Viscosity
As
du
dy
t
µ =
? ?
? ?
? ?
Thus viscosity may also be defined as the shear stress required
producing unit rate of shear strain.
Units of Viscosity
S.I. Units: Pa.s or N.s/m
2
C.G.S Unit of viscosity is Poise= dyne-sec/cm
2
One Poise= 0.1 Pa.s
1/100 Poise is called centipoises.
Dynamic viscosity of water at 20
o
C is approx= 1 cP
Kinematic Viscosity
It is the ratio between the dynamic viscosity and density of fluid and denoted by
Mathematically
dynamic viscosity
density
µ
?
?
= =
Units of Kinematic Viscosity
S.I units: m
2
/s
C.G.S units: stoke = cm
2
/sec
One stoke = 10
-4
m
2
/s
Page 4
Properties of Fluids
Definition of Fluid
A fluid is a substance which deforms continuously when subjected to external
shearing forces.
Characteristics of Fluid
1. It has no definite shape of its own, but conforms to the shape of the containing
vessel.
2. Even a small amount of shear force exerted on a fluid will cause it to undergo
a deformation which continues as long as the force continues to be applied.
3. It is interesting to note that a solid suffers strain when subjected to shear
forces whereas a fluid suffers Rate of Strain i.e. it flows under similar
circumstances.
Concept of Continuum
The concept of continuum is a kind of idealization of the continuous description of
matter where the properties of the matter are considered as continuous functions
of space variables. Although any matter is composed of several molecules, the
concept of continuum assumes a continuous distribution of mass within the matter
or system with no empty space, instead of the actual conglomeration of separate
molecules.
Describing a fluid flow quantitatively makes it necessary to assume that flow
variables (pressure, velocity etc.) and fluid properties vary continuously from one
point to another. Mathematical descriptions of flow on this basis have proved to be reliable
and treatment of fluid medium as a continuum has firmly become established.
For example density at a point is normally defined as
Here ? is the volume of the fluid element and m is the mass
If ? is very large ? is affected by the inhomogeneities in the fluid medium.
Considering another extreme if ? is very small, random movement of atoms (or
molecules) would change their number at different times. In the continuum
approximation point density is defined at the smallest magnitude of ? , before
statistical fluctuations become significant. This is called continuum limit and is
denoted by ? c.
One of the factors considered important in determining the validity of continuum
model is molecular density. It is the distance between the molecules which is
Page 4 of 307
characterised by mean free path ( ? ). It is calculated by finding statistical average
distance the molecules travel between two successive collisions. If the mean free
path is very small as compared with some characteristic length in the flow domain
(i.e., the molecular density is very high) then the gas can be treated as a
continuous medium. If the mean free path is large in comparison to some
characteristic length, the gas cannot be considered continuous and it should be
analysed by the molecular theory.
A dimensionless parameter known as Knudsen number, K
n
= ? / L, where ? is the
mean free path and L is the characteristic length. It describes the degree of
departure from continuum.
Usually when K
n
> 0.01, the concept of continuum does not hold good.
Beyond this critical range of Knudsen number, the flows are known as
slip flow (0.01 < K
n
< 0.1),
transition flow (0.1 < K
n
< 10) and
free-molecule flow (K
n
> 10).
However, for the flow regimes considered in this course, K n is always less than 0.01
and it is usual to say that the fluid is a continuum.
Other factor which checks the validity of continuum is the elapsed time between
collisions. The time should be small enough so that the random statistical
description of molecular activity holds good.
In continuum approach, fluid properties such as density, viscosity, thermal
conductivity, temperature, etc. can be expressed as continuous functions of space
and time.
Ideal and Real Fluids
1. Ideal Fluid
An ideal fluid is one which has
no viscosity
no surface tension
and incompressible
2. Real Fluid
An Real fluid is one which has
viscosity
surface tension
and compressible
Naturally available all fluids are real fluid.
Viscosity
Definition: Viscosity is the property of a fluid which determines its resistance to
shearing stresses.
Cause of Viscosity: It is due to cohesion and molecular momentum exchange
between fluid layers.
Newton’s Law of Viscosity: It states that the shear stress (t) on a fluid element
layer is directly proportional to the rate of shear strain.
The constant of proportionality is called the co-efficient of viscosity.
When two layers of fluid, at a distance ‘dy’
apart, move one over the other at different
velocities, say u and u+du.
Velocity gradient =
du
dy
According to Newton’s law
du
dy
t 8
or
=
du
dy
t µ
Velocity Variation near a solid
boundary
Where
µ
= constant of proportionality and is known as co-efficient of Dynamic
viscosity or only Viscosity
As
du
dy
t
µ =
? ?
? ?
? ?
Thus viscosity may also be defined as the shear stress required
producing unit rate of shear strain.
Units of Viscosity
S.I. Units: Pa.s or N.s/m
2
C.G.S Unit of viscosity is Poise= dyne-sec/cm
2
One Poise= 0.1 Pa.s
1/100 Poise is called centipoises.
Dynamic viscosity of water at 20
o
C is approx= 1 cP
Kinematic Viscosity
It is the ratio between the dynamic viscosity and density of fluid and denoted by
Mathematically
dynamic viscosity
density
µ
?
?
= =
Units of Kinematic Viscosity
S.I units: m
2
/s
C.G.S units: stoke = cm
2
/sec
One stoke = 10
-4
m
2
/s
Thermal diffusivity and molecular diffusivity have same dimension, therefore, by
analogy, the kinematic viscosity is also referred to as the momentum diffusivity of
the fluid, i.e. the ability of the fluid to transport momentum.
Classification of Fluids
1. Newtonian Fluids
These fluids follow Newton’s viscosity equation.
For such fluids viscosity does not change with rate of deformation.
2. Non- Newtonian Fluids
These fluids does not follow Newton’s viscosity equation.
Such fluids are relatively uncommon e.g. Printer ink, blood, mud, slurries, polymer
solutions.
Non-Newtonian Fluid (
dy
du
µ t ?
)
Purely Viscous Fluids Visco-elastic
Fluids
Time - Independent Time - Dependent Visco-elastic
Fluids
E
dy
du
a µ t + =
Example: Liquid-
solid
combinations in
pipe flow.
1. Pseudo plastic Fluids
1 ; <
?
?
?
?
?
?
?
?
= n
dy
du
n
µ t
Example: Blood, milk
2. Dilatant Fluids
1 ; >
?
?
?
?
?
?
?
?
= n
dy
du
n
µ t
Example: Butter
3. Bingham or Ideal
Plastic Fluid
n
o
dy
du
?
?
?
?
?
?
?
?
+ = µ t t
Example: Water
suspensions of clay and
flash
1.Thixotropic Fluids
) (t f
dy
du
n
+
?
?
?
?
?
?
?
?
= µ t
f(t)is
decreasing
Example: Printer ink;
crude oil
2. Rheopectic Fluids
) (t f
dy
du
n
+
?
?
?
?
?
?
?
?
= µ t
f(t)is
increasing
Example: Rare liquid solid
suspension
Page 5
Properties of Fluids
Definition of Fluid
A fluid is a substance which deforms continuously when subjected to external
shearing forces.
Characteristics of Fluid
1. It has no definite shape of its own, but conforms to the shape of the containing
vessel.
2. Even a small amount of shear force exerted on a fluid will cause it to undergo
a deformation which continues as long as the force continues to be applied.
3. It is interesting to note that a solid suffers strain when subjected to shear
forces whereas a fluid suffers Rate of Strain i.e. it flows under similar
circumstances.
Concept of Continuum
The concept of continuum is a kind of idealization of the continuous description of
matter where the properties of the matter are considered as continuous functions
of space variables. Although any matter is composed of several molecules, the
concept of continuum assumes a continuous distribution of mass within the matter
or system with no empty space, instead of the actual conglomeration of separate
molecules.
Describing a fluid flow quantitatively makes it necessary to assume that flow
variables (pressure, velocity etc.) and fluid properties vary continuously from one
point to another. Mathematical descriptions of flow on this basis have proved to be reliable
and treatment of fluid medium as a continuum has firmly become established.
For example density at a point is normally defined as
Here ? is the volume of the fluid element and m is the mass
If ? is very large ? is affected by the inhomogeneities in the fluid medium.
Considering another extreme if ? is very small, random movement of atoms (or
molecules) would change their number at different times. In the continuum
approximation point density is defined at the smallest magnitude of ? , before
statistical fluctuations become significant. This is called continuum limit and is
denoted by ? c.
One of the factors considered important in determining the validity of continuum
model is molecular density. It is the distance between the molecules which is
Page 4 of 307
characterised by mean free path ( ? ). It is calculated by finding statistical average
distance the molecules travel between two successive collisions. If the mean free
path is very small as compared with some characteristic length in the flow domain
(i.e., the molecular density is very high) then the gas can be treated as a
continuous medium. If the mean free path is large in comparison to some
characteristic length, the gas cannot be considered continuous and it should be
analysed by the molecular theory.
A dimensionless parameter known as Knudsen number, K
n
= ? / L, where ? is the
mean free path and L is the characteristic length. It describes the degree of
departure from continuum.
Usually when K
n
> 0.01, the concept of continuum does not hold good.
Beyond this critical range of Knudsen number, the flows are known as
slip flow (0.01 < K
n
< 0.1),
transition flow (0.1 < K
n
< 10) and
free-molecule flow (K
n
> 10).
However, for the flow regimes considered in this course, K n is always less than 0.01
and it is usual to say that the fluid is a continuum.
Other factor which checks the validity of continuum is the elapsed time between
collisions. The time should be small enough so that the random statistical
description of molecular activity holds good.
In continuum approach, fluid properties such as density, viscosity, thermal
conductivity, temperature, etc. can be expressed as continuous functions of space
and time.
Ideal and Real Fluids
1. Ideal Fluid
An ideal fluid is one which has
no viscosity
no surface tension
and incompressible
2. Real Fluid
An Real fluid is one which has
viscosity
surface tension
and compressible
Naturally available all fluids are real fluid.
Viscosity
Definition: Viscosity is the property of a fluid which determines its resistance to
shearing stresses.
Cause of Viscosity: It is due to cohesion and molecular momentum exchange
between fluid layers.
Newton’s Law of Viscosity: It states that the shear stress (t) on a fluid element
layer is directly proportional to the rate of shear strain.
The constant of proportionality is called the co-efficient of viscosity.
When two layers of fluid, at a distance ‘dy’
apart, move one over the other at different
velocities, say u and u+du.
Velocity gradient =
du
dy
According to Newton’s law
du
dy
t 8
or
=
du
dy
t µ
Velocity Variation near a solid
boundary
Where
µ
= constant of proportionality and is known as co-efficient of Dynamic
viscosity or only Viscosity
As
du
dy
t
µ =
? ?
? ?
? ?
Thus viscosity may also be defined as the shear stress required
producing unit rate of shear strain.
Units of Viscosity
S.I. Units: Pa.s or N.s/m
2
C.G.S Unit of viscosity is Poise= dyne-sec/cm
2
One Poise= 0.1 Pa.s
1/100 Poise is called centipoises.
Dynamic viscosity of water at 20
o
C is approx= 1 cP
Kinematic Viscosity
It is the ratio between the dynamic viscosity and density of fluid and denoted by
Mathematically
dynamic viscosity
density
µ
?
?
= =
Units of Kinematic Viscosity
S.I units: m
2
/s
C.G.S units: stoke = cm
2
/sec
One stoke = 10
-4
m
2
/s
Thermal diffusivity and molecular diffusivity have same dimension, therefore, by
analogy, the kinematic viscosity is also referred to as the momentum diffusivity of
the fluid, i.e. the ability of the fluid to transport momentum.
Classification of Fluids
1. Newtonian Fluids
These fluids follow Newton’s viscosity equation.
For such fluids viscosity does not change with rate of deformation.
2. Non- Newtonian Fluids
These fluids does not follow Newton’s viscosity equation.
Such fluids are relatively uncommon e.g. Printer ink, blood, mud, slurries, polymer
solutions.
Non-Newtonian Fluid (
dy
du
µ t ?
)
Purely Viscous Fluids Visco-elastic
Fluids
Time - Independent Time - Dependent Visco-elastic
Fluids
E
dy
du
a µ t + =
Example: Liquid-
solid
combinations in
pipe flow.
1. Pseudo plastic Fluids
1 ; <
?
?
?
?
?
?
?
?
= n
dy
du
n
µ t
Example: Blood, milk
2. Dilatant Fluids
1 ; >
?
?
?
?
?
?
?
?
= n
dy
du
n
µ t
Example: Butter
3. Bingham or Ideal
Plastic Fluid
n
o
dy
du
?
?
?
?
?
?
?
?
+ = µ t t
Example: Water
suspensions of clay and
flash
1.Thixotropic Fluids
) (t f
dy
du
n
+
?
?
?
?
?
?
?
?
= µ t
f(t)is
decreasing
Example: Printer ink;
crude oil
2. Rheopectic Fluids
) (t f
dy
du
n
+
?
?
?
?
?
?
?
?
= µ t
f(t)is
increasing
Example: Rare liquid solid
suspension
Fig. Shear stress and deformation rate relationship of different fluids
Effect of Temperature on Viscosity
With increase in temperature
Viscosity of liquids decrease
Viscosity of gasses increase
Note: 1. Temperature responses are neglected in case of Mercury.
2. The lowest viscosity is reached at the critical temperature.
Effect of Pressure on Viscosity
Pressure has very little effect on viscosity.
But if pressure increases intermolecular gap decreases then cohesion increases so
viscosity would be increase.
Surface tension
Surface tension is due to cohesion between particles at the surface.
Capillarity action is due to both cohesion and adhesion.
Surface tension
The tensile force acting on the surface of a liquid in contact with a gas or on the
surface between two immiscible liquids such that the contact surface behaves like
a membrane under tension.
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