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Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE

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AMINES
Structure of amines: Trigonal Pyramidal
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE

Basicity of Amines
a) Aliphatic Amine:
Basic Strength:  NH3 < RNH2 < R2NH < R3N,
b) Aromatic Amine:  
Basic Strength:  NH3 > Ar- NH2 > Ar2- NH2
Benzene ring decreases the electron density over N atom due to resonance effect.
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE

Preparation of Amines
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE

Chemical Reactions
a)   Acylation:
RNH2 + R'COCl→ R'CO NHR an N-substituted amide
R2NH + R'COCl → R'CO.NR2 an N,N disubstituted amide
b)  Benzoylation (Schotten Baumann Reaction)
Primary amine reacts with benzoyl chloride to give the acylated product
c) Carbylamine Reaction (Given Only by Primary Amines):
C2H5NH+ CHCl3 + 3KOH → C2H5NC + 3KCl + 3H2O
C6H5 NH2 + CHCl+ 3KOH → C6H5NC + 3KCl + 3H2O
d)  Action with Aldehyde and Ketone:
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
f) Reaction with Carbonyl Chloride: C2H5 – NH2 + COCl2 → C2H5NCO + 2HCl
g) Hofmann Elimination: When a quaternary ammonium hydroxide is heated strongly (125° or higher) it decomposes to yield water, a tertiary amine and an alkene
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
h) The diazonium salts of amines:
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
i) Reaction of Tertiary amines with Nitrous acid:When a tertiary aliphatic amine is mixed with nitrous acid, an equilibrium is established among the tertiary amine, its salt, and an N-Nitrosoammonium compound.
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
j) Coupling Reactions of Arene Diazonium Salts:
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
k) Ring Substitution in Aromatic Amines:
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
l) Aniline -X rearrangement:
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
Such compounds are not much stable so the group X migrates mainly at p-position.

1. Fisher-Hepp rearrangement
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
2. Phenylhydroxylamine - p-aminophenol rearrangement.
Separation of a Mixture of Amines:
a) Hinsberg’s Method
Primary amine: RNH2 + C6H5SO2Cl ¾→ C6H5– SO2 – NH – R + HCl
C6H5– SO2 – NH – R : N-alkyl benzene sulfonamides
Dissolves in NaOH due to acidic H-attached to Nitrogen)                                                
Secondary amine
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
Tertiary amine : Tertiary amines do not react with Hinsberg’s reagent.
b) Hofmann’s Method:
The mixture of amines is treated with diethyloxalate, which forms a solid oxamide with primary amine, a liquid oxime ester with secondary amine. The tertiary amine does not react.
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE

Test for Amines
Primary amine is treated with a strong base in presence in chloroform, an isocyanide is formed and this isocyanide thus formed has a very foul smell.
Revision Notes: Organic Compounds Containing Nitrogen Notes | Study JEE Main & Advanced Mock Test Series - JEE
Secondary amine is converted into nitrosoamine by treating the amine with nitrous acid. The resultant solutions warmed with phenol and concentrated H2SO4, a brown or red colour is formed at first soon it changes to blue and then to green. The colour changes to red on dilution and further changes to greenish blue on treating with alkali.
Tertiary arylamines react with nitrous acid to form o-nitroso aromatic compound.

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