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JEE Main Previous Year Questions (2025): d – and f – Block Elements

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JEE Main Previous Year Questions 
(2025): d – and f – Block Elements 
Q1: Niobium (???? ) and ruthenium (???? ) have " ?? " and " ?? " number of electrons in 
their respective ???? orbitals. The value of ?? + ?? is ____ . 
JEE Main 2025 (Online) 22nd January Evening Shift 
Ans: 11 
Solution: 
We need to determine the number of electrons each element has in its 4d orbitals and then add 
them together. 
1. Niobium ( Nb, Z = 41 ) 
The ground-state electronic configuration of niobium is: 
[Kr]4?? 4
5?? 1
. 
Hence, Niobium has 4 electrons in its 4d orbitals. 
2. Ruthenium ( Ru, Z = 44 ) 
The ground-state electronic configuration of ruthenium is: 
[Kr]4?? 7
5?? 1
. 
Hence, Ruthenium has 7 electrons in its 4d orbitals. 
3. Sum of 4d Electrons 
?? = 4 ( for Nb), ?? = 7 ( for Ru). 
Therefore, 
?? + ?? = 4 + 7 = 11. 
Ans: 11 
Q2: The molar mass of the water insoluble product formed from the fusion of 
chromite ore (???????? ?? ?? ?? ) with ????
?? ????
?? in presence of ?? ?? is ____ ?? ?????? -?? . 
JEE Main 2025 (Online) 29th January Morning Shift 
Ans: 160 
Solution: 
FeC
2
O
4
+ Na
2
CO
3
?
O
2
 
? 
The chemical reaction can be written as 
The insoluble product is Fe
2
O
3
. 
Molar mass of Fe
2
O
3
 
Fe (Atomic mass) ? 55.845amu 
Molar mass = 55.845 g mol
-1
 
O (Atomic mass) ? 15.999amu 
Page 2


JEE Main Previous Year Questions 
(2025): d – and f – Block Elements 
Q1: Niobium (???? ) and ruthenium (???? ) have " ?? " and " ?? " number of electrons in 
their respective ???? orbitals. The value of ?? + ?? is ____ . 
JEE Main 2025 (Online) 22nd January Evening Shift 
Ans: 11 
Solution: 
We need to determine the number of electrons each element has in its 4d orbitals and then add 
them together. 
1. Niobium ( Nb, Z = 41 ) 
The ground-state electronic configuration of niobium is: 
[Kr]4?? 4
5?? 1
. 
Hence, Niobium has 4 electrons in its 4d orbitals. 
2. Ruthenium ( Ru, Z = 44 ) 
The ground-state electronic configuration of ruthenium is: 
[Kr]4?? 7
5?? 1
. 
Hence, Ruthenium has 7 electrons in its 4d orbitals. 
3. Sum of 4d Electrons 
?? = 4 ( for Nb), ?? = 7 ( for Ru). 
Therefore, 
?? + ?? = 4 + 7 = 11. 
Ans: 11 
Q2: The molar mass of the water insoluble product formed from the fusion of 
chromite ore (???????? ?? ?? ?? ) with ????
?? ????
?? in presence of ?? ?? is ____ ?? ?????? -?? . 
JEE Main 2025 (Online) 29th January Morning Shift 
Ans: 160 
Solution: 
FeC
2
O
4
+ Na
2
CO
3
?
O
2
 
? 
The chemical reaction can be written as 
The insoluble product is Fe
2
O
3
. 
Molar mass of Fe
2
O
3
 
Fe (Atomic mass) ? 55.845amu 
Molar mass = 55.845 g mol
-1
 
O (Atomic mass) ? 15.999amu 
Molar mass = 15.999 g mol
-1
 
Molar mass of ?? ?? 2
?? 3
= 55.845 g mol
-1
× 2 + 15.999 g mol
-1
× 3 
= (111.69 + 47.997)gmol
-1
 
= 159.687 g mol
-1
˜ 160 g mol
-1
 
Q3: Consider the following reactions 
?? + ???????? Little 
 amount 
+ ?? ?? ????
?? ? ?????? ?? ????
?? + Side Products 
?????? ?? ????
?? (vapour) 
+ ???????? ? ?? + ???????? + ?? ?? ?? 
?? + ?? +
? ?? + ?? ?? ?? 
The number of terminal ' ?? ' present in the compound ' C ' is ____ 
JEE Main 2025 (Online) 3rd April Morning Shift 
Ans: 6 
Solution: 
Cr
2
O
7
2-
+ NaCl + H
2
SO
4
? CrO
2
Cl
2
 
CrO
2
Cl
2
 (Vapour) +NaOH? 
Na
2
CrO
4
+ NaCl + H
2
O 
Na
2
CrO
4
+ H
?
? Na
2
Cr
2
O
7
+ H
2
O 
(C) 
Na
2
Cr
2
O
7
? 2Na
?
+ Cr
2
O
7
2-
 
 
No of terminal "O" = 6 
Q4: Among, ???? , ???? , ???? and Cu , identify the element with highest enthalpy of 
atomisation. The spin only magnetic moment value of that element in its +2 oxidation 
state is ____ BM (in nearest integer). 
JEE Main 2025 (Online) 3rd April Evening Shift 
Ans: 4 
Solution: 
 Sc Mn Co Cu 
Enthalpy of 
Atomisation (kJ/mole) 
326 281 425 339 
 
Page 3


JEE Main Previous Year Questions 
(2025): d – and f – Block Elements 
Q1: Niobium (???? ) and ruthenium (???? ) have " ?? " and " ?? " number of electrons in 
their respective ???? orbitals. The value of ?? + ?? is ____ . 
JEE Main 2025 (Online) 22nd January Evening Shift 
Ans: 11 
Solution: 
We need to determine the number of electrons each element has in its 4d orbitals and then add 
them together. 
1. Niobium ( Nb, Z = 41 ) 
The ground-state electronic configuration of niobium is: 
[Kr]4?? 4
5?? 1
. 
Hence, Niobium has 4 electrons in its 4d orbitals. 
2. Ruthenium ( Ru, Z = 44 ) 
The ground-state electronic configuration of ruthenium is: 
[Kr]4?? 7
5?? 1
. 
Hence, Ruthenium has 7 electrons in its 4d orbitals. 
3. Sum of 4d Electrons 
?? = 4 ( for Nb), ?? = 7 ( for Ru). 
Therefore, 
?? + ?? = 4 + 7 = 11. 
Ans: 11 
Q2: The molar mass of the water insoluble product formed from the fusion of 
chromite ore (???????? ?? ?? ?? ) with ????
?? ????
?? in presence of ?? ?? is ____ ?? ?????? -?? . 
JEE Main 2025 (Online) 29th January Morning Shift 
Ans: 160 
Solution: 
FeC
2
O
4
+ Na
2
CO
3
?
O
2
 
? 
The chemical reaction can be written as 
The insoluble product is Fe
2
O
3
. 
Molar mass of Fe
2
O
3
 
Fe (Atomic mass) ? 55.845amu 
Molar mass = 55.845 g mol
-1
 
O (Atomic mass) ? 15.999amu 
Molar mass = 15.999 g mol
-1
 
Molar mass of ?? ?? 2
?? 3
= 55.845 g mol
-1
× 2 + 15.999 g mol
-1
× 3 
= (111.69 + 47.997)gmol
-1
 
= 159.687 g mol
-1
˜ 160 g mol
-1
 
Q3: Consider the following reactions 
?? + ???????? Little 
 amount 
+ ?? ?? ????
?? ? ?????? ?? ????
?? + Side Products 
?????? ?? ????
?? (vapour) 
+ ???????? ? ?? + ???????? + ?? ?? ?? 
?? + ?? +
? ?? + ?? ?? ?? 
The number of terminal ' ?? ' present in the compound ' C ' is ____ 
JEE Main 2025 (Online) 3rd April Morning Shift 
Ans: 6 
Solution: 
Cr
2
O
7
2-
+ NaCl + H
2
SO
4
? CrO
2
Cl
2
 
CrO
2
Cl
2
 (Vapour) +NaOH? 
Na
2
CrO
4
+ NaCl + H
2
O 
Na
2
CrO
4
+ H
?
? Na
2
Cr
2
O
7
+ H
2
O 
(C) 
Na
2
Cr
2
O
7
? 2Na
?
+ Cr
2
O
7
2-
 
 
No of terminal "O" = 6 
Q4: Among, ???? , ???? , ???? and Cu , identify the element with highest enthalpy of 
atomisation. The spin only magnetic moment value of that element in its +2 oxidation 
state is ____ BM (in nearest integer). 
JEE Main 2025 (Online) 3rd April Evening Shift 
Ans: 4 
Solution: 
 Sc Mn Co Cu 
Enthalpy of 
Atomisation (kJ/mole) 
326 281 425 339 
 
Highest Co 
Co
+2
= (Ar)3 d
7
 
 
 
?? = 3
?? = v15 = 3.87
 
Nearest integer = 4 
Q5: Lanthanoid ions with ?? ?? ?? configuration are : 
(A) ????
?? +
 
(B) ????
?? +
 
(C) ????
?? +
 
(D) ????
?? +
 
(E) ????
?? +
 
Choose the correct answer from the options given below : 
JEE Main 2025 (Online) 22nd January Morning Shift 
Options: 
A. (B) and (E) only 
B. (B) and (C) only 
C. (A) and (D) only 
D. (A) and (B) only 
Ans: D 
Solution: 
Let's analyze the electron configurations of the given lanthanide ions. 
Europium (Eu) 
The neutral atom of Eu (atomic number 63) typically has the configuration: 
[Xe]4?? 7
6?? 2
. 
For Eu
2+
, two electrons are removed, usually from the 6?? orbital, resulting in: 
[Xe]4?? 7
. 
Thus, Eu
2+
 has a 4?? 7
 configuration. 
For Eu
3+
, three electrons are removed (the two 6?? electrons and one 4?? electron), giving: 
[Xe]4?? 6
. 
Therefore, Eu
3+
 does not have a 4?? 7
 configuration. 
Gadolinium (Gd) 
The neutral atom of Gd (atomic number 64) is usually represented as: 
[Xe]4?? 7
5?? 1
6?? 2
. 
For Gd
3+
, three electrons are removed (typically the 5?? 1
 and the two 6?? electrons), resulting in: 
[Xe]4?? 7
. 
Page 4


JEE Main Previous Year Questions 
(2025): d – and f – Block Elements 
Q1: Niobium (???? ) and ruthenium (???? ) have " ?? " and " ?? " number of electrons in 
their respective ???? orbitals. The value of ?? + ?? is ____ . 
JEE Main 2025 (Online) 22nd January Evening Shift 
Ans: 11 
Solution: 
We need to determine the number of electrons each element has in its 4d orbitals and then add 
them together. 
1. Niobium ( Nb, Z = 41 ) 
The ground-state electronic configuration of niobium is: 
[Kr]4?? 4
5?? 1
. 
Hence, Niobium has 4 electrons in its 4d orbitals. 
2. Ruthenium ( Ru, Z = 44 ) 
The ground-state electronic configuration of ruthenium is: 
[Kr]4?? 7
5?? 1
. 
Hence, Ruthenium has 7 electrons in its 4d orbitals. 
3. Sum of 4d Electrons 
?? = 4 ( for Nb), ?? = 7 ( for Ru). 
Therefore, 
?? + ?? = 4 + 7 = 11. 
Ans: 11 
Q2: The molar mass of the water insoluble product formed from the fusion of 
chromite ore (???????? ?? ?? ?? ) with ????
?? ????
?? in presence of ?? ?? is ____ ?? ?????? -?? . 
JEE Main 2025 (Online) 29th January Morning Shift 
Ans: 160 
Solution: 
FeC
2
O
4
+ Na
2
CO
3
?
O
2
 
? 
The chemical reaction can be written as 
The insoluble product is Fe
2
O
3
. 
Molar mass of Fe
2
O
3
 
Fe (Atomic mass) ? 55.845amu 
Molar mass = 55.845 g mol
-1
 
O (Atomic mass) ? 15.999amu 
Molar mass = 15.999 g mol
-1
 
Molar mass of ?? ?? 2
?? 3
= 55.845 g mol
-1
× 2 + 15.999 g mol
-1
× 3 
= (111.69 + 47.997)gmol
-1
 
= 159.687 g mol
-1
˜ 160 g mol
-1
 
Q3: Consider the following reactions 
?? + ???????? Little 
 amount 
+ ?? ?? ????
?? ? ?????? ?? ????
?? + Side Products 
?????? ?? ????
?? (vapour) 
+ ???????? ? ?? + ???????? + ?? ?? ?? 
?? + ?? +
? ?? + ?? ?? ?? 
The number of terminal ' ?? ' present in the compound ' C ' is ____ 
JEE Main 2025 (Online) 3rd April Morning Shift 
Ans: 6 
Solution: 
Cr
2
O
7
2-
+ NaCl + H
2
SO
4
? CrO
2
Cl
2
 
CrO
2
Cl
2
 (Vapour) +NaOH? 
Na
2
CrO
4
+ NaCl + H
2
O 
Na
2
CrO
4
+ H
?
? Na
2
Cr
2
O
7
+ H
2
O 
(C) 
Na
2
Cr
2
O
7
? 2Na
?
+ Cr
2
O
7
2-
 
 
No of terminal "O" = 6 
Q4: Among, ???? , ???? , ???? and Cu , identify the element with highest enthalpy of 
atomisation. The spin only magnetic moment value of that element in its +2 oxidation 
state is ____ BM (in nearest integer). 
JEE Main 2025 (Online) 3rd April Evening Shift 
Ans: 4 
Solution: 
 Sc Mn Co Cu 
Enthalpy of 
Atomisation (kJ/mole) 
326 281 425 339 
 
Highest Co 
Co
+2
= (Ar)3 d
7
 
 
 
?? = 3
?? = v15 = 3.87
 
Nearest integer = 4 
Q5: Lanthanoid ions with ?? ?? ?? configuration are : 
(A) ????
?? +
 
(B) ????
?? +
 
(C) ????
?? +
 
(D) ????
?? +
 
(E) ????
?? +
 
Choose the correct answer from the options given below : 
JEE Main 2025 (Online) 22nd January Morning Shift 
Options: 
A. (B) and (E) only 
B. (B) and (C) only 
C. (A) and (D) only 
D. (A) and (B) only 
Ans: D 
Solution: 
Let's analyze the electron configurations of the given lanthanide ions. 
Europium (Eu) 
The neutral atom of Eu (atomic number 63) typically has the configuration: 
[Xe]4?? 7
6?? 2
. 
For Eu
2+
, two electrons are removed, usually from the 6?? orbital, resulting in: 
[Xe]4?? 7
. 
Thus, Eu
2+
 has a 4?? 7
 configuration. 
For Eu
3+
, three electrons are removed (the two 6?? electrons and one 4?? electron), giving: 
[Xe]4?? 6
. 
Therefore, Eu
3+
 does not have a 4?? 7
 configuration. 
Gadolinium (Gd) 
The neutral atom of Gd (atomic number 64) is usually represented as: 
[Xe]4?? 7
5?? 1
6?? 2
. 
For Gd
3+
, three electrons are removed (typically the 5?? 1
 and the two 6?? electrons), resulting in: 
[Xe]4?? 7
. 
So, Gd
3+
 has a 4?? 7
 configuration. 
Terbium (Tb) 
The neutral atom of Tb (atomic number 65) typically has the configuration: 
[Xe]4?? 9
6?? 2
. 
For Tb
3+
, removal of three electrons gives: 
[Xe]4?? 8
. 
Hence, Tb
3+
 does not have a 4?? 7
 configuration. 
Samarium (Sm) 
The neutral atom of Sm (atomic number 62) generally has: 
[Xe]4?? 6
6?? 2
. 
For Sm
2+
, after removal of two electrons (likely from the 6?? orbital), the configuration is: 
[Xe]4?? 6
. 
Therefore, Sm
2+
 does not have a 4?? 7
 configuration. 
Thus, the ions with a 4?? 7
 configuration are: 
(A) Eu
2+
 
(B) Gd
3+
 
The correct answer is: Option D - (A) and (B) only. 
Q6: The correct set of ions (aqueous solution) with same colour from the following is: 
JEE Main 2025 (Online) 23rd January Morning Shift 
Options: 
A. V
2+
, Cr
3+
, Mn
3+
 
B. Ti
4+
, V
4+
, Mn
2+
 
C. Sc
3+
, Ti
3+
, Cr
2+
 
D. Zn
2+
, V
3+
, Fe
3+
 
Ans: A 
Solution: 
(1) V
2+
 (Violet), Cr
3+
 (Violet), Mn
3+
 (Violet) 
(2) Zn
2+
 (Colourless), V
3+
 (Green), Fe
3+
 (Yellow) 
(3) Ti
4+
 (Colourless), V
4+
 (Blue), Mn
2+
 (Pink) 
(4) Sc
3+
 (Colourless), Ti
3+
 (Purple), Cr
2+
 (Blue) 
Q7: Consider the following reactions 
?? ?? ????
?? ?? ?? ?
?????? 
-?? ?? ?? 
[?? ] ?
?? ?? ????
?? 
-?? ?? ?? 
[ ?? ] + ?? ?? ????
?? 
The products [?? ] and [?? ], respectively are : 
JEE Main 2025 (Online) 23rd January Evening Shift 
Options: 
A. K
2
Cr(OH )
6
 and Cr
2
O
3
 
B. K
2
CrO
4
 and Cr
2
O
3
 
C. K
2
CrO
4
 and K
2
Cr
2
O
7
 
D. K
2
CrO
4
 and CrO 
Page 5


JEE Main Previous Year Questions 
(2025): d – and f – Block Elements 
Q1: Niobium (???? ) and ruthenium (???? ) have " ?? " and " ?? " number of electrons in 
their respective ???? orbitals. The value of ?? + ?? is ____ . 
JEE Main 2025 (Online) 22nd January Evening Shift 
Ans: 11 
Solution: 
We need to determine the number of electrons each element has in its 4d orbitals and then add 
them together. 
1. Niobium ( Nb, Z = 41 ) 
The ground-state electronic configuration of niobium is: 
[Kr]4?? 4
5?? 1
. 
Hence, Niobium has 4 electrons in its 4d orbitals. 
2. Ruthenium ( Ru, Z = 44 ) 
The ground-state electronic configuration of ruthenium is: 
[Kr]4?? 7
5?? 1
. 
Hence, Ruthenium has 7 electrons in its 4d orbitals. 
3. Sum of 4d Electrons 
?? = 4 ( for Nb), ?? = 7 ( for Ru). 
Therefore, 
?? + ?? = 4 + 7 = 11. 
Ans: 11 
Q2: The molar mass of the water insoluble product formed from the fusion of 
chromite ore (???????? ?? ?? ?? ) with ????
?? ????
?? in presence of ?? ?? is ____ ?? ?????? -?? . 
JEE Main 2025 (Online) 29th January Morning Shift 
Ans: 160 
Solution: 
FeC
2
O
4
+ Na
2
CO
3
?
O
2
 
? 
The chemical reaction can be written as 
The insoluble product is Fe
2
O
3
. 
Molar mass of Fe
2
O
3
 
Fe (Atomic mass) ? 55.845amu 
Molar mass = 55.845 g mol
-1
 
O (Atomic mass) ? 15.999amu 
Molar mass = 15.999 g mol
-1
 
Molar mass of ?? ?? 2
?? 3
= 55.845 g mol
-1
× 2 + 15.999 g mol
-1
× 3 
= (111.69 + 47.997)gmol
-1
 
= 159.687 g mol
-1
˜ 160 g mol
-1
 
Q3: Consider the following reactions 
?? + ???????? Little 
 amount 
+ ?? ?? ????
?? ? ?????? ?? ????
?? + Side Products 
?????? ?? ????
?? (vapour) 
+ ???????? ? ?? + ???????? + ?? ?? ?? 
?? + ?? +
? ?? + ?? ?? ?? 
The number of terminal ' ?? ' present in the compound ' C ' is ____ 
JEE Main 2025 (Online) 3rd April Morning Shift 
Ans: 6 
Solution: 
Cr
2
O
7
2-
+ NaCl + H
2
SO
4
? CrO
2
Cl
2
 
CrO
2
Cl
2
 (Vapour) +NaOH? 
Na
2
CrO
4
+ NaCl + H
2
O 
Na
2
CrO
4
+ H
?
? Na
2
Cr
2
O
7
+ H
2
O 
(C) 
Na
2
Cr
2
O
7
? 2Na
?
+ Cr
2
O
7
2-
 
 
No of terminal "O" = 6 
Q4: Among, ???? , ???? , ???? and Cu , identify the element with highest enthalpy of 
atomisation. The spin only magnetic moment value of that element in its +2 oxidation 
state is ____ BM (in nearest integer). 
JEE Main 2025 (Online) 3rd April Evening Shift 
Ans: 4 
Solution: 
 Sc Mn Co Cu 
Enthalpy of 
Atomisation (kJ/mole) 
326 281 425 339 
 
Highest Co 
Co
+2
= (Ar)3 d
7
 
 
 
?? = 3
?? = v15 = 3.87
 
Nearest integer = 4 
Q5: Lanthanoid ions with ?? ?? ?? configuration are : 
(A) ????
?? +
 
(B) ????
?? +
 
(C) ????
?? +
 
(D) ????
?? +
 
(E) ????
?? +
 
Choose the correct answer from the options given below : 
JEE Main 2025 (Online) 22nd January Morning Shift 
Options: 
A. (B) and (E) only 
B. (B) and (C) only 
C. (A) and (D) only 
D. (A) and (B) only 
Ans: D 
Solution: 
Let's analyze the electron configurations of the given lanthanide ions. 
Europium (Eu) 
The neutral atom of Eu (atomic number 63) typically has the configuration: 
[Xe]4?? 7
6?? 2
. 
For Eu
2+
, two electrons are removed, usually from the 6?? orbital, resulting in: 
[Xe]4?? 7
. 
Thus, Eu
2+
 has a 4?? 7
 configuration. 
For Eu
3+
, three electrons are removed (the two 6?? electrons and one 4?? electron), giving: 
[Xe]4?? 6
. 
Therefore, Eu
3+
 does not have a 4?? 7
 configuration. 
Gadolinium (Gd) 
The neutral atom of Gd (atomic number 64) is usually represented as: 
[Xe]4?? 7
5?? 1
6?? 2
. 
For Gd
3+
, three electrons are removed (typically the 5?? 1
 and the two 6?? electrons), resulting in: 
[Xe]4?? 7
. 
So, Gd
3+
 has a 4?? 7
 configuration. 
Terbium (Tb) 
The neutral atom of Tb (atomic number 65) typically has the configuration: 
[Xe]4?? 9
6?? 2
. 
For Tb
3+
, removal of three electrons gives: 
[Xe]4?? 8
. 
Hence, Tb
3+
 does not have a 4?? 7
 configuration. 
Samarium (Sm) 
The neutral atom of Sm (atomic number 62) generally has: 
[Xe]4?? 6
6?? 2
. 
For Sm
2+
, after removal of two electrons (likely from the 6?? orbital), the configuration is: 
[Xe]4?? 6
. 
Therefore, Sm
2+
 does not have a 4?? 7
 configuration. 
Thus, the ions with a 4?? 7
 configuration are: 
(A) Eu
2+
 
(B) Gd
3+
 
The correct answer is: Option D - (A) and (B) only. 
Q6: The correct set of ions (aqueous solution) with same colour from the following is: 
JEE Main 2025 (Online) 23rd January Morning Shift 
Options: 
A. V
2+
, Cr
3+
, Mn
3+
 
B. Ti
4+
, V
4+
, Mn
2+
 
C. Sc
3+
, Ti
3+
, Cr
2+
 
D. Zn
2+
, V
3+
, Fe
3+
 
Ans: A 
Solution: 
(1) V
2+
 (Violet), Cr
3+
 (Violet), Mn
3+
 (Violet) 
(2) Zn
2+
 (Colourless), V
3+
 (Green), Fe
3+
 (Yellow) 
(3) Ti
4+
 (Colourless), V
4+
 (Blue), Mn
2+
 (Pink) 
(4) Sc
3+
 (Colourless), Ti
3+
 (Purple), Cr
2+
 (Blue) 
Q7: Consider the following reactions 
?? ?? ????
?? ?? ?? ?
?????? 
-?? ?? ?? 
[?? ] ?
?? ?? ????
?? 
-?? ?? ?? 
[ ?? ] + ?? ?? ????
?? 
The products [?? ] and [?? ], respectively are : 
JEE Main 2025 (Online) 23rd January Evening Shift 
Options: 
A. K
2
Cr(OH )
6
 and Cr
2
O
3
 
B. K
2
CrO
4
 and Cr
2
O
3
 
C. K
2
CrO
4
 and K
2
Cr
2
O
7
 
D. K
2
CrO
4
 and CrO 
Ans: C 
Solution: 
 
Q8: Match List - I with List - II 
 List - I  List - II 
(A) Bronze (I) Cu, Ni 
(B) Brass (II) Fe, Cr, Ni, C 
(C) UK silver coin (III) Cu, Zn 
(D) Stainless steel (IV) Cu, Sn 
Choose the correct answer from the options given below : 
JEE Main 2025 (Online) 23rd January Evening Shift 
Options: 
A. (A)-(IV), (B)-(II), (C)-(III), (D)-(I) 
B. (A)-(IV), (B)-(III), (C)-(I), (D)-(II) 
C. (A)-(III), (B)-(I), (C)-(IV), (D)-(II) 
D. (A)-(III), (B)-(IV), (C)-(II), (D)-(I) 
Ans: B 
Solution: 
To match the items from List I to List II, we need to understand the composition of each 
material: 
Bronze is an alloy composed of copper (Cu) and tin(Sn). 
Brass is an alloy made of copper ( Cu ) and zinc ( Zn ). 
The UK silver coin primarily consists of copper ( Cu ) and nickel ( Ni ). 
Stainless steel is an alloy that includes iron ( Fe ), chromium ( Cr ), nickel ( Ni ), and carbon ( C ). 
Based on these definitions, the correct matches are: 
(A) Bronze corresponds to (IV) Cu, Sn 
(B) Brass corresponds to (III) Cu, Zn 
(C) UK silver coin corresponds to (I) Cu, Ni 
(D) Stainless steel corresponds to (II) Fe, Cr, Ni, C 
These pairings illustrate the composition of each material and ensure accurate alignment 
between List I and List II. 
Q9: Which of the following ions is the strongest oxidizing agent? (Atomic Number of 
???? = ???? , ???? = ???? , ???? = ???? , ???? = ???? ) 
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FAQs on JEE Main Previous Year Questions (2025): d – and f – Block Elements

1. What are the key characteristics of d-block elements?
Ans. D-block elements, also known as transition metals, are characterized by the presence of d-orbitals that are progressively filled with electrons as one moves across the period in the periodic table. They typically exhibit multiple oxidation states, form colored compounds, and have catalytic properties. Additionally, they are good conductors of heat and electricity, and they often have high melting and boiling points.
2. How do f-block elements differ from d-block elements in terms of electronic configuration?
Ans. F-block elements consist of the lanthanides and actinides, and they are characterized by the filling of f-orbitals. While d-block elements fill their d-orbitals, f-block elements fill their f-orbitals. The general electronic configuration for f-block elements is [Xe]6s²4f¹⁻¹⁴ for lanthanides and [Rn]7s²5f¹⁻¹⁴ for actinides. This difference in electronic configuration leads to distinct chemical properties and reactivity compared to d-block elements.
3. Why are transition metals known for their catalytic properties?
Ans. Transition metals are known for their catalytic properties due to their ability to change oxidation states easily and form various intermediate complexes. Their partially filled d-orbitals allow them to bind with substrates and facilitate chemical reactions by lowering the activation energy. This makes them effective catalysts in many industrial processes, including the Haber process for ammonia synthesis and catalytic converters in automobiles.
4. What are some common oxidation states of transition metals?
Ans. Transition metals can exhibit multiple oxidation states due to the involvement of both d and s electrons in bonding. Common oxidation states include +1, +2, +3, and +4; however, some metals can even reach +6 or +7 states. For example, iron can exist in +2 (Fe²⁺) and +3 (Fe³⁺) states, while manganese can exist in +2, +4, and +7 states. The ability to exhibit various oxidation states contributes to the diverse chemistry of transition metals.
5. How do the properties of lanthanides and actinides differ?
Ans. Lanthanides and actinides differ in several ways, including their atomic and ionic radii, magnetic properties, and chemical reactivity. Lanthanides generally exhibit similar chemical properties and are less reactive compared to actinides. Actinides, on the other hand, are more complex in their chemistry due to the presence of more unstable isotopes and a greater range of oxidation states. Additionally, actinides are radioactive, while most lanthanides are stable.
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