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JEE Advanced Previous Year Questions (2021 - 2025): Amines

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 Page 1


 
Q1: List-I contains various reaction sequences and List-II contains different phenolic compounds. Match
each entry in List-I with the appropriate entry in List-II and choose the correct option.
Page 2


 
Q1: List-I contains various reaction sequences and List-II contains different phenolic compounds. Match
each entry in List-I with the appropriate entry in List-II and choose the correct option.
(a) P-2, Q-3, R-4, S-5
(b) P-2, Q-3, R-5, S-1
(c) P-3, Q-5, R-4, S-1
(d) P-3, Q-2, R-5, S-4      [JEE Advanced 2024 Paper 1]
Ans: (c)
Page 3


 
Q1: List-I contains various reaction sequences and List-II contains different phenolic compounds. Match
each entry in List-I with the appropriate entry in List-II and choose the correct option.
(a) P-2, Q-3, R-4, S-5
(b) P-2, Q-3, R-5, S-1
(c) P-3, Q-5, R-4, S-1
(d) P-3, Q-2, R-5, S-4      [JEE Advanced 2024 Paper 1]
Ans: (c)
Q2: The option(s) with correct sequence of reagents for the conversion of P to Q is (are)
(a) i) Lindlar's catalyst, H 2
ii) SnCl 2/HCl
iii) NaBH 4
iv) H 3O?
(b) i) Lindlar's catalyst, H 2
ii) H 3O?
iii) SnCl 2/HCl
iv) NaBH 4
(c) i) NaBH 4
ii) SnCl 2/HCl
iii) H 3O?
iv) Lindlar's catalyst, H 2
(d) i) Lindlar's catalyst, H 2
ii) NaBH 4
iii) SnCl 2/HCl
iv) H 3O?                     [JEE Advanced 2024 Paper 2]
Ans: (c), (d)
Page 4


 
Q1: List-I contains various reaction sequences and List-II contains different phenolic compounds. Match
each entry in List-I with the appropriate entry in List-II and choose the correct option.
(a) P-2, Q-3, R-4, S-5
(b) P-2, Q-3, R-5, S-1
(c) P-3, Q-5, R-4, S-1
(d) P-3, Q-2, R-5, S-4      [JEE Advanced 2024 Paper 1]
Ans: (c)
Q2: The option(s) with correct sequence of reagents for the conversion of P to Q is (are)
(a) i) Lindlar's catalyst, H 2
ii) SnCl 2/HCl
iii) NaBH 4
iv) H 3O?
(b) i) Lindlar's catalyst, H 2
ii) H 3O?
iii) SnCl 2/HCl
iv) NaBH 4
(c) i) NaBH 4
ii) SnCl 2/HCl
iii) H 3O?
iv) Lindlar's catalyst, H 2
(d) i) Lindlar's catalyst, H 2
ii) NaBH 4
iii) SnCl 2/HCl
iv) H 3O?                     [JEE Advanced 2024 Paper 2]
Ans: (c), (d)
Page 5


 
Q1: List-I contains various reaction sequences and List-II contains different phenolic compounds. Match
each entry in List-I with the appropriate entry in List-II and choose the correct option.
(a) P-2, Q-3, R-4, S-5
(b) P-2, Q-3, R-5, S-1
(c) P-3, Q-5, R-4, S-1
(d) P-3, Q-2, R-5, S-4      [JEE Advanced 2024 Paper 1]
Ans: (c)
Q2: The option(s) with correct sequence of reagents for the conversion of P to Q is (are)
(a) i) Lindlar's catalyst, H 2
ii) SnCl 2/HCl
iii) NaBH 4
iv) H 3O?
(b) i) Lindlar's catalyst, H 2
ii) H 3O?
iii) SnCl 2/HCl
iv) NaBH 4
(c) i) NaBH 4
ii) SnCl 2/HCl
iii) H 3O?
iv) Lindlar's catalyst, H 2
(d) i) Lindlar's catalyst, H 2
ii) NaBH 4
iii) SnCl 2/HCl
iv) H 3O?                     [JEE Advanced 2024 Paper 2]
Ans: (c), (d)
 
 
Numerical Type 
JEE Advanced 2023 Paper 2 Online 
Q1. A trinitro compound, 1,3,5-tris-(4-nitrophenyl)benzene, on complete reaction 
with an excess of ???? /?????? gives a major product, which on treatment with an 
excess of ???????? ?? /?????? at ?? °
?? provides ?? as the product. ?? , upon treatment with 
excess of ?? ?? ?? at room temperature, gives the product ?? . Bromination of ?? in 
aqueous medium furnishes the product ?? . The compound ?? upon treatment with 
an excess of phenol under basic conditions gives the product ?? . 
The molar mass difference between compounds ?? and ?? is ?????? ?? ?????? -?? and 
between compounds ?? and ?? is ?????? . ?? ?? ?????? -?? . 
The number of heteroatoms present in one molecule of ?? is 
[Use : Molar mass (in ???????? -?? ) : ?? = ?? , ?? = ???? , ?? = ???? , ?? = ???? , ???? = ???? , ???? = ???? . ?? 
Atoms other than ?? and ?? are considered as heteroatoms] 
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FAQs on JEE Advanced Previous Year Questions (2021 - 2025): Amines

1. What are the primary methods for synthesizing amines in organic chemistry?
Ans. The primary methods for synthesizing amines include: 1. Reduction of nitriles, nitro compounds, or amides using reducing agents like lithium aluminum hydride (LiAlH4) or catalytic hydrogenation. 2. Alkylation of ammonia or primary amines using alkyl halides. 3. Gabriel synthesis, which involves the reaction of phthalimide with an alkyl halide followed by hydrolysis to yield primary amines.
2. What is the importance of amines in pharmaceuticals?
Ans. Amines are crucial in the pharmaceutical industry as they serve as building blocks for many drugs. They are involved in the structure of neurotransmitters, hormones, and various therapeutic agents. Their ability to form hydrogen bonds and their basic nature enhance their biological activity, making them vital for drug design and development.
3. How do amines react with acids and what products are formed?
Ans. Amines react with acids to form ammonium salts. In this reaction, the lone pair of electrons on the nitrogen atom in the amine acts as a Lewis base, accepting a proton (H+) from the acid. The resulting product is a salt, which is typically ionic and soluble in water.
4. What is the difference between primary, secondary, and tertiary amines?
Ans. The classification of amines is based on the number of alkyl or aryl groups attached to the nitrogen atom: - Primary amines (1°) have one alkyl or aryl group (R-NH2). - Secondary amines (2°) have two alkyl or aryl groups (R2-NH). - Tertiary amines (3°) have three alkyl or aryl groups (R3-N).
5. What are the physical properties of amines compared to alcohols?
Ans. Amines generally have lower boiling points than alcohols of similar molecular weight due to the absence of hydrogen bonding in secondary and tertiary amines, which is present in alcohols. However, primary amines can form hydrogen bonds, resulting in higher boiling points than tertiary amines. Amines also have distinct odors and can be more basic than alcohols due to the nitrogen atom's lone pair.
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