Tricks on colour of ions (d block elements)
Some more formulae regarding chemistry
Ncert exempler solutions for d and f block
Multiple Choice Questions
Single Correct Answer Type
Question 1. Electronic configuration of a transition element X in 3 oxidation state is [Ar] 3d5. What is its atomic number?
(a) 25 (b) 26 (c) 27 (d) 24
Solution:
Question 2. The electronic configuration of Cu(II) is 3d9 whereas that of Cu(I) is 3d10. Which of the following is correct?
(a) Cu(II) is more stable .
(b) Cu(II) is less stable
(c) Cu(I) and Cu(II) are equally stable
(d) Stability of Cu(I) and Cu(I) depends on nature of copper salts.
Solution: (a) Cu(II) is more stable due to greater effective nuclear charge of Cu(II).
Question 3. Metallic radii of some transition elements are given below. Which of these elements will have highest density?
Solution: (d) On moving left to right along period, metallic radius decreases while mass increases. Decreases in metallic radius coupled with increase in atomic mass results in increase in density of metal.
Hence, among the given four choices Cu belongs to right side of Periodic Table in transition metal, and it has the highest density (89 g/cm3).
Question 4. Generally, transition elements form coloured salts due to the presence of unpaired electrons. Which of the following compound will be coloured in solid state?
(a) Ag2SO4 (b) CUF2 (c) ZnF2 (d) Cu2Cl2
Solution: (b) Cu2 has 1 unpaired electron in CuF2, hence, it is coloured in solid state.
Question 5. On addition of small amount of KMnO4 to concentrated H2SO4, a green oily compound is obtained which is highly explosive in nature. Identify the compound from the following:
(a) Mn2O7 (b) MnO2 (c) MnSO4 (d) Mn2O3
Solution: (a) 2KMnO4 2H2SO4(Conc ) –> Mn2O7 2KHSO4 H2O
Question 6. The magnetic nature of elements depend on the presence of unpaired electrons. Identify the configuration of transition element, which shows the highest magnetic moment.
(a) 3d7 (b) 3d5 (c) 3d8 (d) 3d2
Solution: (b) The greater the number of unpaired electron, the higher will be its value of magnetic moment. Since, 3d5 has 5 unpaired electrons hence highest magnetic moment.
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