EmSAT Achieve Exam  >  EmSAT Achieve Notes  >  Chemistry for EmSAT Achieve  >  What is Photoelectric Effect?

What is Photoelectric Effect? | Chemistry for EmSAT Achieve PDF Download

Table of contents
JEE Main 2024 Question Paper Solution Discussion Live
Understanding the Photoelectric Effect
Details of the Photoelectric Effect
Summary of the Photoelectric Effect
Understanding the Photoelectric Effect: Introduction to Photons
Essential Concepts of the Photoelectric Effect
Key Points to Remember
Einstein's Contributions towards the Photoelectric Effect
Properties of the Photon
Threshold Wavelength and Photoelectric Effect
Work Function or Threshold Energy (Φ)
Experimental Study of the Photoelectric Effect
Factors Affecting the Photoelectric Effect
Summary of Photoelectric Effect
Einstein's Explanation of the Photoelectric Effect
Different Graphs of the Photoelectric Equation
Applications of the Photoelectric Effect
Summary and Explanation
Test Your Knowledge on the Photoelectric Effect
Instructions:
Congratulations!
Your Quiz Result:

JEE Main 2024 Question Paper Solution Discussion Live

  • JEE
  • IIT JEE Study Material
  • Photoelectric Effect

Understanding the Photoelectric Effect

  • Definition: The photoelectric effect is a phenomenon where electrons are released from a metal's surface upon exposure to light. These emitted electrons are known as photoelectrons.
  • Key Point: The ejection of photoelectrons and their energy is influenced by the frequency of incident light.
  • Explanation: When light interacts with a metal's surface, photoelectrons are emitted due to absorbed energy, overcoming the metal's binding forces.

Details of the Photoelectric Effect

  • Process: The phenomenon occurs as surface electrons absorb light energy to break free from metallic nuclei attraction.
  • Illustration: An example demonstrating the emission of photoelectrons following the photoelectric effect.

Jump to

  • History of the Photoelectric Effect
  • Principle
  • Formula
  • Laws Governing the Photoelectric Effect
  • Experimental Study of the Photoelectric Effect
  • Einstein's Photoelectric Equation
  • Graphs
  • Applications
  • Solved Problems (Numericals)

Summary of the Photoelectric Effect

  • Introduction to the Photoelectric Effect:

    The photoelectric effect, initially explored by Wilhelm Ludwig Franz Hallwachs in 1887, was experimentally verified by Heinrich Rudolf Hertz. They discovered that when a surface is exposed to specific frequencies of electromagnetic radiation, electrons are emitted. This phenomenon involves the absorption of radiation by a material and the subsequent release of electrically charged particles.

  • Mechanism of the Photoelectric Effect:

    When light interacts with the surface of a metal during the photoelectric effect, it causes the ejection of electrons. These ejected electrons, known as photoelectrons (denoted by e–), contribute to the generation of a photoelectric current.

Understanding the Photoelectric Effect: Introduction to Photons

  • The photoelectric effect is a phenomenon that cannot be adequately explained by the wave nature of light. Instead, it finds its explanation in the particle nature of light.
  • Light is conceptualized as a flow of particles known as photons, which carry electromagnetic energy.
  • Each photon's energy is linked to the frequency of the light it comprises, as described by Planck's equation: E = hν = hc/λ.
  • Here, E represents the photon's energy, h is Planck's constant, ν stands for the frequency of the light, c is the speed of light in a vacuum, and λ denotes the light's wavelength.

Understanding Photon Energy Variation

  • Light of different frequencies carries photons with varying energies. For instance, blue light possesses a higher frequency than red light, indicating that a blue light photon carries more energy than a red light photon due to the shorter wavelength of blue light.

Threshold Energy Requirement for the Photoelectric Effect

  • To trigger the photoelectric effect, incident photons must possess adequate energy to surpass the attractive forces binding electrons to metal nuclei.
  • The minimum energy necessary to dislodge an electron from a metal is termed the threshold energy (symbolized by Φ).
  • For a photon to have energy equal to the threshold energy, its frequency must match the threshold frequency, the minimum frequency required for the photoelectric effect to manifest.
  • The threshold frequency is often denoted as νth, with the associated threshold wavelength represented as λth.

Essential Concepts of the Photoelectric Effect

  • Threshold Energy
  • Threshold Frequency

Relationship between Incident Photon Frequency and Emitted Photoelectron Kinetic Energy

When a photon's energy interacts with a metal surface, it can lead to the emission of a photoelectron. This process can be described with the following equation:

Energy of Photon (Ephoton) = Threshold Energy (Φ) + Kinetic Energy of Electron (Eelectron)

Equation Representation

This relationship can be mathematically expressed as:

Ephoton = Φ + ½mev^2

Where:

  • Ephoton represents the energy of the incident photon (equal to hυ)
  • Φ denotes the threshold energy of the metal surface (equal to hυth)
  • Eelectron represents the kinetic energy of the photoelectron (equal to ½mev^2, where me = Mass of electron = 9.1*10^-31kg)

Photon Energy and Emission Scenarios

Understanding the relationship between photon energy and electron emission is crucial:

  • If photon energy is less than the threshold energy, no photoelectrons are emitted due to insufficient energy to overcome attractive forces.
  • When photon frequency matches the threshold frequency, photoelectrons are emitted, but with zero kinetic energy.

Effect of Incident Light Frequency on Photoelectron Kinetic Energy

An illustration demonstrating how the frequency of incident light influences photoelectron kinetic energy is provided for clarity.

Understanding the Photoelectric Effect

  • When red light shines on a metal surface, the photoelectric effect doesn't occur because the frequency of red light is below the metal's threshold frequency.
  • Green light, however, triggers the photoelectric effect on the metal surface, leading to the emission of photoelectrons.
  • Blue light also induces the photoelectric effect, with emitted photoelectrons having higher kinetic energies compared to green light. This difference is due to the higher frequency of blue light.

Key Points to Remember

  • The threshold energy required for the photoelectric effect varies among different metals due to varying electron-binding forces.
  • The photoelectric effect can also occur in non-metals, although the threshold frequencies for non-metallic substances are generally high.

It's fascinating to note how different light frequencies impact the photoelectric effect, shedding light on the behavior of electrons in various materials.

Einstein's Contributions towards the Photoelectric Effect

  • The photoelectric effect refers to the process where electrons are emitted from the surface of materials, typically metals, upon exposure to light. This phenomenon is pivotal in elucidating the quantum properties of light and electrons.
  • Albert Einstein provided a groundbreaking explanation for the photoelectric effect through his extensive research. He proposed that this effect occurs due to light energy being transmitted in distinct quantized packets.
  • Einstein's significant contributions in this area led to him being awarded the Nobel Prize in 1921 for his remarkable insights.
  • According to Einstein's theory, each photon carries an energy denoted by E, which can be expressed as E = hν.
  • Here, E represents the energy of the photon in joules, h symbolizes Planck's constant (6.626 x 10^-34 J·s), and ν corresponds to the frequency of the photon in hertz.

Properties of the Photon

  • A photon possesses quantum numbers all equal to zero.
  • Devoid of mass or charge, photons remain unaffected by magnetic and electric fields.
  • Traveling at the speed of light in a vacuum, photons exhibit high velocity.
  • When matter interacts with radiation, the latter behaves as discrete particles known as photons.
  • Considered virtual particles, photons exhibit energy directly proportional to their frequency and inversely proportional to their wavelength.
  • The relationship between the momentum and energy of photons is defined as E = p.c, where p represents the magnitude of momentum and c symbolizes the speed of light.

Definition of the Photoelectric Effect

The photoelectric effect refers to the process where metals emit electrons upon exposure to light of specific frequencies.

Understanding the Photoelectric Effect

  • The Core Principle of the Photoelectric Effect: The photoelectric effect is rooted in the fundamental law of energy conservation.

Essential Condition for the Photoelectric Effect

  • Threshold Frequency (\( \gamma_{th} \)): This denotes the minimum frequency of light required to trigger the photoelectric effect. Each metal has a specific threshold frequency, which varies between different metals.
  • Significance of Threshold Frequency: When the frequency of incident light (\( \gamma \)) matches the threshold frequency (\( \gamma_{th} \)):
    • If \( \gamma < \gamma_{th}="" \):="" no="" photoelectrons="" are="" ejected,="" hence="" no="" photoelectric="" effect="" />
    • If \( \gamma = \gamma_{th} \): Photoelectrons are released with zero kinetic energy.
    • If \( \gamma > \gamma_{th} \): Photoelectrons are emitted from the surface with kinetic energy.
  • Threshold Wavelength (\( \lambda_{th} \)): This identifies the maximum wavelength of incident light that can cause electron emission from a metal surface.
  • Calculation of Threshold Wavelength: \( \lambda_{th} = \frac{c}{\gamma_{th}} \), where \( c \) is the speed of light.
  • Effect of Wavelength on Photoelectron Emission:
    • Wavelengths beyond the threshold value do not induce photoelectron emission.

By understanding these concepts, we can appreciate how different frequencies and wavelengths of light influence the photoelectric effect, shedding light on this fascinating phenomenon in physics.

Understanding the Photoelectric Effect

The photoelectric effect is a phenomenon in physics where electrons are emitted from a material when it is exposed to light. Let's break down the key concepts related to the photoelectric effect:

Threshold Wavelength and Photoelectric Effect

  • When the wavelength of incident light (λ) is less than the threshold wavelength (λTh), the photoelectric effect occurs, and the ejected electron gains kinetic energy.
  • If the wavelength of light is equal to the threshold wavelength (λ = λTh), only the photoelectric effect happens, with the ejected electron having zero kinetic energy.
  • When the wavelength is greater than the threshold wavelength (λ > λTh), no photoelectric effect takes place.

Work Function or Threshold Energy (Φ)

The work function, also known as the threshold energy (Φ), is the minimum amount of energy required to remove an electron from a conductor to just outside its surface in a vacuum.

Mathematically, Φ = hνTh = hc/λTh.

The work function is specific to each metal. Consider the following scenarios based on the energy of an incident photon (E):

  • If E is less than Φ, no photoelectric effect occurs.
  • When E equals Φ, only the photoelectric effect happens, but the ejected electron has zero kinetic energy.
  • If E is greater than Φ, the photoelectric effect takes place, and the ejected electron gains kinetic energy.

Understanding the Photoelectric Effect

The photoelectric effect, as explained by Albert Einstein, reveals essential relationships between light and electrons.

Key Formula: Photoelectric Effect

The formula states that the energy of a photon equals the energy required to remove an electron plus the kinetic energy of the emitted electron.

  • Photon energy (hν) = Work function (W) + Maximum kinetic energy of ejected electrons (E)
  • Where:
    • h: Planck's constant
    • ν: Frequency of the incident photon
    • W: Work function
    • E: Maximum kinetic energy of ejected electrons (1/2 mv^2)

Laws Governing the Photoelectric Effect

  • Photoelectric current is directly proportional to light intensity for a given frequency (γ > γTh).
  • Every material has a threshold frequency below which no photoelectrons are emitted, regardless of light intensity.
  • Increasing the frequency of incident light above the threshold boosts the maximum kinetic energy of photoelectrons.
  • Maximum kinetic energy is unaffected by light intensity, and photo-emission occurs instantly.

Experimental Study of the Photoelectric Effect

The photoelectric effect is investigated through an experimental setup involving an evacuated glass tube containing two zinc plates, C and D. Plate C functions as the anode, while plate D serves as the photosensitive plate.

Both plates are connected to a battery (B) and an ammeter (A). When radiation strikes plate D through a quartz window (W), electrons are emitted from the plate, leading to the flow of current in the circuit. This phenomenon is termed as photocurrent. Plate C can be maintained at a desired potential (positive or negative) relative to plate D.

Characteristics of the Photoelectric Effect

  • The threshold frequency for the photoelectric effect varies depending on the material and differs across different materials.
  • The photoelectric current is directly proportional to the intensity of light falling on the photosensitive plate.
  • The kinetic energy of the emitted photoelectrons is directly linked to the frequency of the incident light.
  • The stopping potential required to halt the emitted photoelectrons is directly proportional to the frequency of the incident light, and this process occurs instantaneously.

Factors Affecting the Photoelectric Effect

  • The intensity of incident radiation.
  • A potential difference between the metal plate and collector.
  • Frequency of incident radiation.
  • Effects of Intensity of Incident Radiation on Photoelectric Effect

    Effects of Intensity of Incident Radiation on Photoelectric Effect
  • When the intensity of light changes while keeping the frequency and potential constant, the photoelectric current is observed.
  • Increasing the intensity of light leads to a proportional increase in the photoelectric current, indicating more photoelectrons being emitted per second.
  • Effects of Potential Difference between the Metal Plate and the Collector on the Photoelectric Effect

  • By varying the potential difference between the plates while keeping frequency and intensity constant, the impact on the photoelectric current is studied.
  • Gradually increasing the positive potential of the collector relative to the metal plate results in an increase in the photoelectric current, up to a specific characteristic value.
  • Summary of Photoelectric Effect

    • Photoelectric Current and Saturation Current: When the potential exceeds the characteristic value, the photoelectric current remains constant, reaching its maximum known as saturation current.
    • Effect of Frequency on Photoelectric Effect:
      • Constant Intensity, Variable Frequency: Keeping light intensity fixed while changing frequency affects the cutoff potential/stopping potential of the metal. The cutoff potential is directly proportional to the frequency of the incident light.
      • Kinetic Energy Variation: The kinetic energy of photoelectrons increases in direct proportion to the frequency of incident light, ensuring that the photoelectrons are completely stopped. To prevent photoelectrons from reaching the collector, the potential between the metal plate and collector must be reversed and increased (negative value).

    Einstein's Explanation of the Photoelectric Effect

    • Einstein's theory on the photoelectric effect describes how electrons absorb photons, either completely or partially, leading to various outcomes.
    • When a photon collides with electrons, it can be entirely or partially absorbed. The absorbed energy is utilized in specific ways by the electrons.

    Key Concepts Explained by Einstein's Photoelectric Equation

    • The frequency of incident light directly influences the kinetic energy of electrons. Higher frequency light results in electrons with higher kinetic energy.
    • On the other hand, the wavelength of incident light is inversely proportional to the kinetic energy of electrons.
    • If the frequency or wavelength of the incident light matches certain thresholds, there might be no emission of photoelectrons.
    • The intensity of radiation refers to the number of photons in the light beam. More intense light means more photons, but intensity does not affect photon energy.
    • Increasing radiation intensity boosts the rate of emission, but it does not alter the kinetic energy of the emitted electrons. Consequently, the photoelectric current increases with more emitted electrons.

    Different Graphs of the Photoelectric Equation

    • Photoelectric current vs Retarding potential for different voltages
    • Photoelectric current vs Retarding potential for different intensities
    • Electron current vs Light Intensity
    • Stopping potential vs Frequency
    • Electron current vs Light frequency
    • Electron kinetic energy vs Light frequency

    Applications of the Photoelectric Effect

    Below are the applications of the photoelectric effect explained in detail:

    • Generation of Electricity: When light falls on solar panels, it causes the emission of electrons, generating electrical energy.
    • Photocells in Cameras: Photocells use the photoelectric effect to measure light and adjust camera settings accordingly.
    • Automated Doors: Photoelectric sensors are used in automated doors to detect motion and open or close the door.
    • Particle Detectors: The photoelectric effect is utilized in particle detectors to identify and study subatomic particles.
    • Utilization of Photoelectric Effect:
      • Solar Panels: Photovoltaic cells in solar panels convert sunlight into electricity by harnessing the photoelectric effect. The panels consist of specific metal combinations that facilitate electricity generation across a broad range of light wavelengths.
      • Motion and Position Sensors: These sensors employ a photoelectric material in conjunction with UV or IR LEDs. When an object obstructs the light between the LED and the sensor, a change in potential difference is detected, enabling motion and position detection.
      • Lighting Sensors: Commonly found in devices like smartphones, lighting sensors adjust screen brightness automatically based on ambient light levels. The sensors operate by measuring the intensity of light, which influences the current generated through the photoelectric effect.
      • Digital Cameras: Equipped with photoelectric sensors, digital cameras can capture and process light information by responding to different colors of light. This functionality enables the detection and recording of images.
      • X-Ray Photoelectron Spectroscopy (XPS): XPS utilizes X-rays to analyze surfaces by measuring the kinetic energies of emitted electrons. It provides crucial insights into surface chemistry, including elemental and chemical compositions.
      • Applications in Various Devices:
        • Burglar Alarms: Photoelectric cells play a key role in burglar alarm systems, detecting changes in light levels.
        • Photomultipliers: These devices utilize the photoelectric effect to detect minimal levels of light, crucial in sensitive light detection applications.
        • Video Camera Tubes: In the early days of television, video camera tubes employed photoelectric cells to capture and transmit visual information.
        • Night Vision Technology: Devices like night vision goggles leverage the photoelectric effect to enhance visibility in low-light conditions.
        • Scientific Contributions:
          • Nuclear Processes: The photoelectric effect contributes to the study of certain nuclear processes, aiding in chemical analysis by providing characteristic energy signatures from emitted electrons.

    Understanding the Photoelectric Effect

    • Threshold Wavelength and Maximum Kinetic Energy
      • In a photoelectric effect experiment, if the threshold wavelength of incident light is 260 nm, the maximum kinetic energy of emitted electrons can be calculated using the formula Kmax = hc/λ - hc/λ0.
      • For instance, if E (in eV) = 1237/λ (nm), the maximum kinetic energy of emitted electrons in this scenario would be 1.5 eV.
    • Change in Wavelength and Stopping Potential
      • When the wavelength of light incident on a metal changes from 300 nm to 400 nm in a photoelectric experiment with (hc/e = 1240 nm-V), there is a decrease in the stopping potential.
      • The decrease in stopping potential can be determined using the formula V1 - V2 = (hc/e) × [(λ2 - λ1)/(λ1λ2)].
      • For example, in this case, the decrease in stopping potential during the photoelectric experiment is found to be 1V.
    • Effect of Ultraviolet Light on Metal Plate
      • Electrons are emitted from plate 1 when ultraviolet light with a wavelength of 230 nm shines on a metal plate.
      • These electrons cross to plate 2, causing a current to flow through the wire connecting the two plates.
      • By gradually increasing the battery voltage until the current drops to zero, it is observed that the battery voltage at this point is 1.30 V.

    Summary and Explanation

    • Energy of Photons: The energy of photons in a light beam is calculated using the formula E = hf, where E is the energy, h is Planck's constant, and f is the frequency of the light. For a given frequency of 1.25 × 10^15 Hz, the energy of each photon is determined to be 5.17 eV.
    • Maximum Kinetic Energy of Electrons: The maximum kinetic energy of emitted electrons corresponds to the stopping potential, which is 1.30V in this scenario. Therefore, the maximum kinetic energy of the electrons is also 1.30 eV.

    Understanding the Photoelectric Effect

    • When light of a certain frequency is considered, the photoelectric current typically increases with the intensity of light. However, this relationship holds true only if the frequency surpasses a specific threshold.
    • Below the threshold frequency, even with high-intensity light, the emission of photoelectrons halts completely.
    • As the frequency of incident light increases, the maximum kinetic energy of a photoelectron also increases. This effect occurs when the frequency exceeds the threshold limit. Notably, the maximum kinetic energy remains unaffected by changes in light intensity.
    • The stopping potential refers to the negative potential applied to the opposing electrode when the photoelectric current diminishes to zero.
    • The threshold frequency signifies the point at which the photoelectric current ceases below a specific frequency of incident light.
    • The photoelectric effect serves as evidence supporting the particle nature of light, highlighting its quantum characteristics.

    Test Your Knowledge on the Photoelectric Effect

    Q5

    Assess your comprehension of this concept by tackling a few multiple-choice questions. Click 'Start Quiz' to begin!

    Instructions:

    • Select the correct answer and click on the "Finish" button
    • Check your score and answers at the end of the quiz

    Congratulations!

    For all JEE related queries and study materials, visit EduRev.

    Your Quiz Result:

    0 out of 0 are wrong

    0

    Request OTP on

    Leave a Comment

    Cancel reply

    • Share
    • ShareShare
    • Call Us
    The document What is Photoelectric Effect? | Chemistry for EmSAT Achieve is a part of the EmSAT Achieve Course Chemistry for EmSAT Achieve.
    All you need of EmSAT Achieve at this link: EmSAT Achieve
    195 videos|213 docs|157 tests

    Top Courses for EmSAT Achieve

    195 videos|213 docs|157 tests
    Download as PDF
    Explore Courses for EmSAT Achieve exam

    Top Courses for EmSAT Achieve

    Signup for Free!
    Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
    10M+ students study on EduRev
    Related Searches

    Exam

    ,

    Semester Notes

    ,

    What is Photoelectric Effect? | Chemistry for EmSAT Achieve

    ,

    What is Photoelectric Effect? | Chemistry for EmSAT Achieve

    ,

    Previous Year Questions with Solutions

    ,

    study material

    ,

    past year papers

    ,

    Viva Questions

    ,

    Summary

    ,

    Extra Questions

    ,

    What is Photoelectric Effect? | Chemistry for EmSAT Achieve

    ,

    Important questions

    ,

    shortcuts and tricks

    ,

    Objective type Questions

    ,

    Sample Paper

    ,

    video lectures

    ,

    pdf

    ,

    practice quizzes

    ,

    ppt

    ,

    Free

    ,

    MCQs

    ,

    mock tests for examination

    ;