Electromagnetic Waves and Light Properties
Wave Properties of Light
Speed of Light in Vacuum
\[ c = 3.00 \times 10^8 \text{ m/s} \]
- c = speed of light in vacuum (constant)
- This is the maximum speed at which all electromagnetic radiation travels in vacuum
Wave Equation
\[ c = f \lambda \]
- c = speed of light (3.00 × 108 m/s)
- f = frequency (Hz or s-1)
- λ = wavelength (m)
- This fundamental relationship applies to all electromagnetic radiation
- Frequency and wavelength are inversely proportional
Speed of Light in a Medium
\[ v = \frac{c}{n} \]
- v = speed of light in the medium (m/s)
- c = speed of light in vacuum (3.00 × 108 m/s)
- n = index of refraction of the medium (dimensionless)
- Light slows down when traveling through any medium (n > 1)
- For vacuum, n = 1; for air, n ≈ 1.00; for water, n ≈ 1.33; for glass, n ≈ 1.5
Wavelength in a Medium
\[ \lambda_{\text{medium}} = \frac{\lambda_{\text{vacuum}}}{n} \]
- Wavelength decreases when light enters a denser medium
- Frequency remains constant when light crosses medium boundaries
Energy and Photons
Photon Energy
\[ E = hf \]
- E = energy of a photon (J)
- h = Planck's constant = 6.626 × 10-34 J·s
- f = frequency (Hz)
- Energy is directly proportional to frequency
Photon Energy in Terms of Wavelength
\[ E = \frac{hc}{\lambda} \]
- E = energy of a photon (J)
- h = Planck's constant (6.626 × 10-34 J·s)
- c = speed of light (3.00 × 108 m/s)
- λ = wavelength (m)
- Energy is inversely proportional to wavelength
- Shorter wavelengths (like UV) have higher energy; longer wavelengths (like IR) have lower energy
Energy Using Electron Volts
\[ E \text{ (eV)} = \frac{1240 \text{ eV·nm}}{\lambda \text{ (nm)}} \]
- Useful approximation for MCAT calculations
- 1 eV = 1.6 × 10-19 J
- Wavelength must be in nanometers (nm)
Photon Momentum
\[ p = \frac{E}{c} = \frac{h}{\lambda} \]
- p = momentum of a photon (kg·m/s)
- E = energy (J)
- h = Planck's constant (6.626 × 10-34 J·s)
- λ = wavelength (m)
- Photons have momentum despite having zero rest mass
Electromagnetic Spectrum
Order of Electromagnetic Spectrum (Increasing Frequency/Energy)
- Radio waves (lowest energy, longest wavelength)
- Microwaves
- Infrared (IR)
- Visible light (ROYGBIV: Red, Orange, Yellow, Green, Blue, Indigo, Violet)
- Ultraviolet (UV)
- X-rays
- Gamma rays (highest energy, shortest wavelength)
Visible Light Spectrum
- Red: ~700 nm (lowest energy, longest wavelength)
- Orange: ~600 nm
- Yellow: ~580 nm
- Green: ~550 nm
- Blue: ~470 nm
- Violet: ~400 nm (highest energy, shortest wavelength)
- Visible spectrum: approximately 400-700 nm
Reflection
Law of Reflection
\[ \theta_i = \theta_r \]
- θi = angle of incidence (measured from the normal)
- θr = angle of reflection (measured from the normal)
- Both angles are measured from the normal (perpendicular) to the surface
- The incident ray, reflected ray, and normal all lie in the same plane
Mirror Equation
\[ \frac{1}{f} = \frac{1}{d_o} + \frac{1}{d_i} \]
- f = focal length (m or cm)
- do = object distance from mirror (m or cm)
- di = image distance from mirror (m or cm)
- Applies to both concave and convex mirrors
Sign Conventions for Mirrors:
- f is positive for concave (converging) mirrors
- f is negative for convex (diverging) mirrors
- di is positive for real images (in front of mirror)
- di is negative for virtual images (behind mirror)
- do is always positive for real objects
Magnification
\[ m = -\frac{d_i}{d_o} = \frac{h_i}{h_o} \]
- m = magnification (dimensionless)
- di = image distance (m or cm)
- do = object distance (m or cm)
- hi = image height (m or cm)
- ho = object height (m or cm)
Sign Conventions for Magnification:
- m > 0: upright image
- m <>: inverted image
- |m| > 1: enlarged/magnified image
- |m| <>: reduced/diminished image
Focal Length and Radius of Curvature
\[ f = \frac{R}{2} \]
- f = focal length (m or cm)
- R = radius of curvature (m or cm)
- The focal point is located halfway between the center of curvature and the mirror surface
- For concave mirrors: f and R are positive
- For convex mirrors: f and R are negative
Power of a Mirror
\[ P = \frac{1}{f} \]
- P = power (diopters, D = m-1)
- f = focal length (must be in meters)
- Positive power indicates a converging mirror
- Negative power indicates a diverging mirror
Refraction
Snell's Law
\[ n_1 \sin\theta_1 = n_2 \sin\theta_2 \]
- n1 = index of refraction of first medium (dimensionless)
- θ1 = angle of incidence in first medium (measured from normal)
- n2 = index of refraction of second medium (dimensionless)
- θ2 = angle of refraction in second medium (measured from normal)
- Light bends toward the normal when entering a denser medium (n2 > n1)
- Light bends away from the normal when entering a less dense medium (n2 <>1)
Critical Angle and Total Internal Reflection
\[ \sin\theta_c = \frac{n_2}{n_1} \]
- θc = critical angle
- n1 = index of refraction of the denser medium (where light originates)
- n2 = index of refraction of the less dense medium
- This formula only applies when n1 > n2 (light going from denser to less dense medium)
- When θ1 ≥ θc, total internal reflection occurs (no refraction, 100% reflection)
- Applications: fiber optics, prisms, diamonds
Lenses - Thin Lens Equation
\[ \frac{1}{f} = \frac{1}{d_o} + \frac{1}{d_i} \]
- f = focal length (m or cm)
- do = object distance from lens (m or cm)
- di = image distance from lens (m or cm)
- Same form as mirror equation but different sign conventions
Sign Conventions for Lenses:
- f is positive for converging lenses (convex)
- f is negative for diverging lenses (concave)
- di is positive for real images (opposite side of lens from object)
- di is negative for virtual images (same side of lens as object)
- do is positive for real objects (always for simple problems)
Magnification for Lenses
\[ m = -\frac{d_i}{d_o} = \frac{h_i}{h_o} \]
- Same formula as mirrors
- m > 0: upright image
- m <>: inverted image
Lensmaker's Equation
\[ \frac{1}{f} = (n-1)\left(\frac{1}{R_1} - \frac{1}{R_2}\right) \]
- f = focal length of the lens
- n = index of refraction of the lens material
- R1 = radius of curvature of first surface
- R2 = radius of curvature of second surface
- R is positive if the center of curvature is on the side where light exits
- R is negative if the center of curvature is on the side where light enters
Power of a Lens
\[ P = \frac{1}{f} \]
- P = power (diopters, D = m-1)
- f = focal length (must be in meters)
- Positive power indicates a converging (convex) lens
- Negative power indicates a diverging (concave) lens
Combined Power of Thin Lenses in Contact
\[ P_{\text{total}} = P_1 + P_2 + P_3 + ... \]
- Powers add algebraically when lenses are in contact
- Equivalent to: \( \frac{1}{f_{\text{total}}} = \frac{1}{f_1} + \frac{1}{f_2} + \frac{1}{f_3} + ... \)
Dispersion
Index of Refraction Wavelength Dependence
- Index of refraction varies with wavelength: n = n(λ)
- Generally, shorter wavelengths (violet) have higher n than longer wavelengths (red)
- This causes white light to separate into colors when passing through a prism
- Dispersion: separation of light into component colors due to wavelength-dependent refraction
Interference and Diffraction
Double-Slit Interference (Young's Experiment)
Condition for Bright Fringes (Constructive Interference)
\[ d\sin\theta = m\lambda \]
- d = distance between slits (m)
- θ = angle from central axis to the fringe
- m = order of the bright fringe (m = 0, ±1, ±2, ±3, ...)
- λ = wavelength of light (m)
- m = 0 corresponds to the central bright fringe
- Path difference = mλ for constructive interference
Condition for Dark Fringes (Destructive Interference)
\[ d\sin\theta = \left(m + \frac{1}{2}\right)\lambda \]
- m = 0, ±1, ±2, ±3, ...
- Path difference = (m + ½)λ for destructive interference
- Dark fringes occur between bright fringes
Fringe Spacing (Small Angle Approximation)
\[ y = \frac{m\lambda L}{d} \]
- y = distance from central maximum to mth bright fringe
- L = distance from slits to screen
- d = slit separation
- λ = wavelength
- m = fringe order
- Valid when θ is small (typically when L >> d)
Distance Between Adjacent Bright Fringes
\[ \Delta y = \frac{\lambda L}{d} \]
- Spacing between consecutive bright fringes is uniform
- Larger wavelength → larger spacing
- Larger slit separation → smaller spacing
Single-Slit Diffraction
Condition for Dark Fringes (Minima)
\[ a\sin\theta = m\lambda \]
- a = width of the single slit (m)
- θ = angle to the dark fringe
- m = order of the minimum (m = ±1, ±2, ±3, ...; note m ≠ 0)
- λ = wavelength (m)
- Central maximum is at m = 0, which is bright
- First minimum occurs at m = ±1
Width of Central Maximum
\[ w = \frac{2\lambda L}{a} \]
- w = width of central bright fringe
- L = distance from slit to screen
- a = slit width
- λ = wavelength
- Narrower slits produce wider diffraction patterns
Thin Film Interference
Path Difference in Thin Films
\[ 2nt = m\lambda \quad \text{(constructive if no phase change or both surfaces have phase change)} \]
\[ 2nt = \left(m + \frac{1}{2}\right)\lambda \quad \text{(constructive if one surface has phase change)} \]
- n = index of refraction of the film
- t = thickness of the film
- λ = wavelength in vacuum
- m = 0, 1, 2, 3, ...
Phase Change Upon Reflection
- Light reflects with a 180° (π) phase change when reflecting off a medium with higher index of refraction (nreflected > nincident)
- No phase change when reflecting off a medium with lower index of refraction
- Must account for phase changes at both surfaces of the film
Minimum Thickness for Constructive Interference (One Phase Change)
\[ t_{\text{min}} = \frac{\lambda}{4n} \]
- When one surface causes a phase change
- This is for m = 0 (first order)
Polarization
Malus's Law
\[ I = I_0 \cos^2\theta \]
- I = intensity of light after passing through polarizer
- I0 = intensity of polarized light incident on polarizer
- θ = angle between incident light's polarization direction and polarizer axis
- When θ = 0°, maximum transmission (I = I0)
- When θ = 90°, no transmission (I = 0)
Unpolarized Light Through First Polarizer
\[ I = \frac{I_0}{2} \]
- Unpolarized light passing through a polarizer has its intensity reduced by half
- The transmitted light is now polarized along the polarizer axis
Brewster's Angle
\[ \tan\theta_B = \frac{n_2}{n_1} \]
- θB = Brewster's angle (angle of incidence)
- n1 = index of refraction of first medium
- n2 = index of refraction of second medium
- At Brewster's angle, reflected light is completely polarized perpendicular to the plane of incidence
- The reflected and refracted rays are perpendicular to each other
Photoelectric Effect
Work Function and Threshold Frequency
\[ E_{\text{photon}} = \phi + KE_{\text{max}} \]
\[ hf = \phi + KE_{\text{max}} \]
- h = Planck's constant (6.626 × 10-34 J·s)
- f = frequency of incident light (Hz)
- φ = work function (minimum energy needed to eject electron) (J or eV)
- KEmax = maximum kinetic energy of ejected electron (J or eV)
Threshold Frequency
\[ f_0 = \frac{\phi}{h} \]
- f0 = threshold frequency (minimum frequency to eject electrons)
- If f <>0, no electrons are ejected regardless of intensity
- If f ≥ f0, electrons are ejected
Threshold Wavelength
\[ \lambda_0 = \frac{c}{f_0} = \frac{hc}{\phi} \]
- λ0 = maximum wavelength that can eject electrons
- If λ > λ0, no electrons are ejected
Maximum Kinetic Energy
\[ KE_{\text{max}} = \frac{1}{2}mv_{\text{max}}^2 = hf - \phi \]
- m = mass of electron (9.11 × 10-31 kg)
- vmax = maximum velocity of ejected electron
- Excess photon energy beyond work function becomes kinetic energy
Stopping Potential
\[ eV_s = KE_{\text{max}} \]
\[ V_s = \frac{hf - \phi}{e} \]
- Vs = stopping potential (voltage needed to stop most energetic electrons)
- e = elementary charge (1.6 × 10-19 C)
- Stopping potential is independent of light intensity
Key Photoelectric Effect Principles
- Photon energy (not intensity) determines if electrons are ejected
- Intensity determines the number of electrons ejected per second (rate)
- Higher frequency light produces electrons with greater kinetic energy
- Electron emission is instantaneous (no time delay)
- Each photon can eject at most one electron (one-to-one interaction)
Radiation Intensity
Intensity of Electromagnetic Radiation
\[ I = \frac{P}{A} \]
- I = intensity (W/m2)
- P = power (W)
- A = area (m2)
- Intensity is power per unit area
Intensity from a Point Source
\[ I = \frac{P}{4\pi r^2} \]
- r = distance from point source
- Intensity follows inverse square law
- Doubling the distance reduces intensity to 1/4
Inverse Square Law
\[ \frac{I_1}{I_2} = \frac{r_2^2}{r_1^2} \]
- Intensity is inversely proportional to the square of the distance
Optical Instruments
The Human Eye
Power of the Eye
\[ P = P_{\text{cornea}} + P_{\text{lens}} \]
- Total power is the sum of cornea and lens powers
- Most refraction occurs at the cornea
- The lens provides fine-tuning (accommodation)
Near Point
- Normal near point: approximately 25 cm
- Closest distance at which the eye can focus
- Increases with age (presbyopia)
Far Point
- Normal far point: infinity
- Farthest distance at which the eye can focus
- Finite far point indicates myopia (nearsightedness)
Vision Correction
Myopia (Nearsightedness)
- Far point is closer than infinity
- Corrected with diverging (concave) lens
- Lens power is negative
Hyperopia (Farsightedness)
- Near point is farther than 25 cm
- Corrected with converging (convex) lens
- Lens power is positive
Simple Magnifier
\[ m = \frac{25 \text{ cm}}{f} \]
- m = angular magnification
- f = focal length of the lens (cm)
- 25 cm represents the near point of normal vision
- Object should be placed at or just inside the focal point
Compound Microscope
\[ m = m_o \times m_e = -\frac{L \times 25\text{ cm}}{f_o \times f_e} \]
- m = total magnification
- mo = magnification of objective lens
- me = magnification of eyepiece
- L = tube length (distance between focal points of objective and eyepiece)
- fo = focal length of objective lens
- fe = focal length of eyepiece
- Negative sign indicates inverted image
Refracting Telescope
\[ m = -\frac{f_o}{f_e} \]
- m = angular magnification
- fo = focal length of objective lens (long)
- fe = focal length of eyepiece (short)
- Negative sign indicates inverted image
- Larger fo and smaller fe produce greater magnification
Telescope Length
\[ L = f_o + f_e \]
- L = length of telescope
- Sum of focal lengths when adjusted for viewing distant objects