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Electrochemistry - Chemistry MCQ


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20 Questions MCQ Test - Electrochemistry

Electrochemistry for Chemistry 2024 is part of Chemistry preparation. The Electrochemistry questions and answers have been prepared according to the Chemistry exam syllabus.The Electrochemistry MCQs are made for Chemistry 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Electrochemistry below.
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Electrochemistry - Question 1

For  cell reaction will be spontaneous if:

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Electrochemistry - Question 2

Equivalent conductance of saturated BaSO4 is 400 ohm-1cm2 equivalemt-1 and specific conductance is 8 x 10-5 ohm-1cm-1. Hence, ksp of BaSO4 is:

Detailed Solution for Electrochemistry - Question 2

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Electrochemistry - Question 3

For a cell reaction, E (at 25oC) = 1.26V, n = 2 and ΔS = -96.5JK-1mol-1. E at 85oC by assuming ΔS to be independent of temperature is _____ (V). [Given F = 96500 Cmol-1] (Round off to two decimal places).


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Electrochemistry - Question 4

Given for the reaciton, for which ΔHo = -3.0 kcal. The molar entropies are 6.5 cal/K for M, -22.2 cal/K for M+3, 31.2 cal/k for H2 and -10.0cal/K for H+.
The value of Eo for the half cell,  is ______[Round off to two decimal places]


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Electrochemistry - Question 5

The resistance of decinormal solution of a salt occupying a volume between two platinum electrodes 1.80 cm apart and 5.4 cm2 area was found to be 32 ohm. The value of  is

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Electrochemistry - Question 6

The value of 
Given : 

The required electrode reaction is 

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Electrochemistry - Question 7

A current of 0.5A is passed through molten AlCl3 for 40 min. The mass of the aluminum deposited at the cathode is (Al = 27)

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Electrochemistry - Question 8

At 180C the mobilities of NH+4 and ClO-4 ions are 6.6 x 10-4 and 5.7 x 10-4 cm2 volt-1s-1 at infinite dilution. The value of equivalent conductance of ammonium perchlorate solution at infinite dilution

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Electrochemistry - Question 9

For the reaction,
H2(g)(1atm) + 2AgCL(s) = 2Ag(s) + 2H+(aq)(0.1M)+2Cl-(aq)(0.1M)
 The emf of the cell is _____volt.(Round off to two decimal placs)


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Electrochemistry - Question 10

The variation of equivalent conductance of strong electrolyte with  is correctly shown in the figure

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With dilution λeq increases in a straight line for strong electrolyte.

Electrochemistry - Question 11

According to Debye Huckel limiting law the mean activity coefficient of 0.5 x 10-4 mol / kg CaCl2 is at 25oC

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Electrochemistry - Question 12

Given that, E0(Fe3+,Fe) = -0.04V and E0(Fe2+,Fe) = -0.44V, the value of E0(Fe3+,Fe2+) is _______ (in V). (round off to two decimal places).


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Electrochemistry - Question 13

The solubility product of AgBr(s) is 5 x 10-13 at 298k. If the standard reduction potential of the half cell  The standard reduction potential  (in volts) is _____ (round off to two decimal places).


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Electrochemistry - Question 14

The concentration of a MgSO4 solution having the same ionic strength as that of a 0.1M Na2SO4 solution is ____(Round off to three decimal places)


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Electrochemistry - Question 15

The temperature coefficient of the cell is  Choose the incorrect statement(S)

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 = 0 then |ΔH| > |nFE| endothermic reaction (Wrong relation)

Electrochemistry - Question 16

The standard electrode potential Eo at a fixed temperature and in a given medium is dependent on

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Depend only electrode reaction and electrode composition

Electrochemistry - Question 17

At 273K, the calorimetric determination of ΔH for the reaction,
Zn(s) + 2AgCl(s) → ZnCl2(aq) + Ag(s)
yielded -217.78 kJ mol-1, while the emf of the corresponding cell was 1.015 V. The  of the cell is

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Electrochemistry - Question 18

The Zn2+|Zn half cell (Eθ = -0.762V) is connected to a Cu2+ | Cu halff cell (Eo = 0.340V). The value of log10K, where K is the equilibrium constant is [Given : (2.303 RT/F) = 0.06]

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Electrochemistry - Question 19

An electrochemical cell consists of two half-cell reactions

The mass of copper (in grams) dissolved on passing 0.5 A current for 1 hour is 
[Given: atoms mass of Cu is 63.6; F = 96500C mol-1]

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Electrochemistry - Question 20

According to the Dubye-Huckel limiting law, if the concendration of the dilute aqueous solution of KCI is increased 4-fold, the value of log  is the molal mean ionic activity coefficient) will be

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