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Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - JEE MCQ


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9 Questions MCQ Test - Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers)

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Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 1

Passage for Q. Nos. (1 and 2)

Q. 

Compound X is 

(2015 Adv., Comprehension Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 1

The reaction condition indicates that starting compound is phenyl acetylene.


Hydroboration oxidation brings about anti-Markonikoff's hydration of alkene.

Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 2

Q. 

The major compound Y is 

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 2

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Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 3

The acidic hydroiysis of ether X shown below is fastest when

(2014 Adv., Only One Option Correct Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 3

This problem can be solved by using the concept of stab ility of carbocation and SN1 reaction.
When two phenyl groups are replaced by two para methoxy group, carbocation formed will be more stable.
As the stability of carbocation formed increases, rate of acidic hydrolysis increases.

Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 4

The major product of the following reaction is

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 4

Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 5

Passage for Q. Nos. (5 and 6)

A tertiary alcohol H upon acid catalysed dehydration gives a product I, Ozonolysis of I leads to compounds J and K. Compound J upon reaction with KOH gives benzyl alcohol and a compound L, where as K on reaction with KOH gives only M.

Q. 

Compound H is formed by the reaction of

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 5

Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 6

A tertiary alcohol H upon acid catalysed dehydration gives a product I, Ozonolysis of I leads to compounds J and K. Compound J upon reaction with KOH gives benzyl alcohol and a compound L, where as K on reaction with KOH gives only M.

Q. 

The structures of compounds J, K and L respectively are

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 6

Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 7

The increasing order of boiling points of the following mentioned alcohols is

I. 1, 2-dihydroxy benzene
II. 1, 3-dihydroxy benzene
III. 1, 4-dihydroxy benzene
IV. Hydroxy benzene

(2006, Only One Option Correct Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 7

All dihydroxy benzene will have higher boiling points than monohydroxy benzene. Also, among dihydroxy benzenes, 1, 2,-dihydroxy benzene has lowest boiling point due to intramolecular H-bonding.

Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 8

The best method to prepare cyclohexene from cyclohexanol is by using

(2005, Only One Option Correct Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 8

Concentrated H3PO4 solution does not involve any substitution product while with others, substitution product are also formed.

Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 9

When phenyl magnesium bromide reacts with tert. butanol, which of the following is formed ?

(2005, Only One Option Correct Type)

Detailed Solution for Retro (Past 13 Year) IIT-JEE Advanced (Alcohols Phenols And Ethers) - Question 9

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