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Case Based Questions Test: Electrochemistry - NEET MCQ


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15 Questions MCQ Test - Case Based Questions Test: Electrochemistry

Case Based Questions Test: Electrochemistry for NEET 2024 is part of NEET preparation. The Case Based Questions Test: Electrochemistry questions and answers have been prepared according to the NEET exam syllabus.The Case Based Questions Test: Electrochemistry MCQs are made for NEET 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Case Based Questions Test: Electrochemistry below.
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Case Based Questions Test: Electrochemistry - Question 1

Read the passage given below and answer the following questions:

The cell constant is usually determined by measuring the resistance of the cell containing a solution whose conductivity is already known. For this purpose, we generally use KCl solutions whose conductivity is known accurately at various concentrations and at different temperatures. Consider the resistance of a conductivity cell filled with 0.1 M KCl solution is 200 Ohm. If the resistance of the same cell when filled with 0.02 M KCl solution is 420 Ohm. (Conductivity of 0.1 M KCl solution is 1.29 S m–1.)

The following questions are Multiple Choice Questions. Choose the most appropriate answer:

Q. What is the conductivity of 0.02 M KCl solution?

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 1
Conductivity of 0.02 mol L–1 KCl Solution = Cell constant resistance

= 258/420

= 0.614Sm-1

Case Based Questions Test: Electrochemistry - Question 2

Read the passage given below and answer the following questions:

The cell constant is usually determined by measuring the resistance of the cell containing a solution whose conductivity is already known. For this purpose, we generally use KCl solutions whose conductivity is known accurately at various concentrations and at different temperatures. Consider the resistance of a conductivity cell filled with 0.1 M KCl solution is 200 Ohm. If the resistance of the same cell when filled with 0.02 M KCl solution is 420 Ohm. (Conductivity of 0.1 M KCl solution is 1.29 S m–1.)

The following questions are Multiple Choice Questions. Choose the most appropriate answer:

Q. The cell constant of a conductivity cell ________.

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 2
The cell constant of a conductivity cell remains constant for a cell.
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Case Based Questions Test: Electrochemistry - Question 3

Read the passage given below and answer the following questions:

The cell constant is usually determined by measuring the resistance of the cell containing a solution whose conductivity is already known. For this purpose, we generally use KCl solutions whose conductivity is known accurately at various concentrations and at different temperatures. Consider the resistance of a conductivity cell filled with 0.1 M KCl solution is 200 Ohm. If the resistance of the same cell when filled with 0.02 M KCl solution is 420 Ohm. (Conductivity of 0.1 M KCl solution is 1.29 S m–1.)

The following questions are Multiple Choice Questions. Choose the most appropriate answer:

Q. What will happen to the conductivity of the cell with the dilution?

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 3
The conductivity decreases with dilution.
Case Based Questions Test: Electrochemistry - Question 4

Read the passage given below and answer the following questions:

The cell constant is usually determined by measuring the resistance of the cell containing a solution whose conductivity is already known. For this purpose, we generally use KCl solutions whose conductivity is known accurately at various concentrations and at different temperatures. Consider the resistance of a conductivity cell filled with 0.1 M KCl solution is 200 Ohm. If the resistance of the same cell when filled with 0.02 M KCl solution is 420 Ohm. (Conductivity of 0.1 M KCl solution is 1.29 S m–1.)

The following questions are Multiple Choice Questions. Choose the most appropriate answer:

Q. SI unit for conductivity of a solution is

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 4
SI unit for conductivity of a solution is S m–1.
Case Based Questions Test: Electrochemistry - Question 5

Read the passage given below and answer the following questions:

A galvanic cell consists of a metallic zinc plate immersed in 0.1 M Zn(NO3)2 solution and metallic plate of lead in 0.02 M Pb(NO3)2 solution.

The following questions are multiple choice questions.

Choose the most appropriate answer:

Q. How will the cell be represented ?

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 5
Cell representation: Zn(s)|Zn2+(aq)||Pb2+(aq)|Pb(s)
Case Based Questions Test: Electrochemistry - Question 6

Read the passage given below and answer the following questions:

 

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 6

According to Nernst equation

Case Based Questions Test: Electrochemistry - Question 7

Read the passage given below and answer the following questions:

A galvanic cell consists of a metallic zinc plate immersed in 0.1 M Zn(NO3)2 solution and metallic plate of lead in 0.02 M Pb(NO3)2 solution.

The following questions are multiple choice questions.

Choose the most appropriate answer:

Q. What product is obtained at cathode?

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 7
Anode reaction: Zn(s) → Zn2+(aq) + 2e

Cathode reaction: Pb2+(aq) + 2e → Pb(s)

Case Based Questions Test: Electrochemistry - Question 8

Read the passage given below and answer the following questions:

A galvanic cell consists of a metallic zinc plate immersed in 0.1 M Zn(NO3)2 solution and metallic plate of lead in 0.02 M Pb(NO3)2 solution.

The following questions are multiple choice questions.

Choose the most appropriate answer:

Q. Which of the following statements is not correct about an inert electrode in a cell ?

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 8
Inert electrode does not participate in redox reaction and acts only as source or sink for electrons. It provides a surface either for oxidation or for reduction reaction.
Case Based Questions Test: Electrochemistry - Question 9

Products of electrolysis depend on the nature of material being electrolysed and the type of electrodes being used. If the electrode is inert (e.g., platinum or gold), it does not participate in the chemical reaction and acts only as source or sink for electrons. On the other hand, if the electrode is reactive, it participates in the electrode reaction. Thus, the products of electrolysis may be different for reactive and inert electrodes. Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells.

In these questions, a statement of assertion followed by a statement of reason. Choose the correct answer out of the following choices.

Assertion (A): The mass of copper and silver, deposited on the cathode be same.

Reason (R): Copper and silver have different equivalent masses.

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 9
W = it E/96500 = 1 × 10 × 60 × 31.8/96500 for copper.

It will be different for silver since the equivalent weight of silver is different.

Case Based Questions Test: Electrochemistry - Question 10

Products of electrolysis depend on the nature of material being electrolysed and the type of electrodes being used. If the electrode is inert (e.g., platinum or gold), it does not participate in the chemical reaction and acts only as source or sink for electrons. On the other hand, if the electrode is reactive, it participates in the electrode reaction. Thus, the products of electrolysis may be different for reactive and inert electrodes. Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells.

In these questions, a statement of assertion followed by a statement of reason. Choose the correct answer out of the following choices.

Assertion (A): At equilibrium condition Ecell = 0 or ΔrG = 0.

Reason (R): Ecell is zero when both electrodes of the cell are of the same metal.

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 10
At equilibrium, condition of Ecell = 0, ∆rG = 0
Case Based Questions Test: Electrochemistry - Question 11

Products of electrolysis depend on the nature of material being electrolysed and the type of electrodes being used. If the electrode is inert (e.g., platinum or gold), it does not participate in the chemical reaction and acts only as source or sink for electrons. On the other hand, if the electrode is reactive, it participates in the electrode reaction. Thus, the products of electrolysis may be different for reactive and inert electrodes. Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. In these questions, a statement of assertion followed by a statement of reason. Choose the correct answer out of the following choices.

Assertion (A): In a galvanic cell, chemical energy is converted into electrical energy.

Reason (R): Redox reactions provide the chemical energy to the cell.

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 11
The redox reactions provide the chemical energy to the galvanic cell which is converted into electrical energy.
Case Based Questions Test: Electrochemistry - Question 12

Products of electrolysis depend on the nature of material being electrolysed and the type of electrodes being used. If the electrode is inert (e.g., platinum or gold), it does not participate in the chemical reaction and acts only as source or sink for electrons. On the other hand, if the electrode is reactive, it participates in the electrode reaction. Thus, the products of electrolysis may be different for reactive and inert electrodes. Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. In these questions, a statement of assertion followed by a statement of reason. Choose the correct answer out of the following choices.

Assertion (A): The negative sign in the expression EZn2+/Zn = – 0.76V means Zn2+ cannot be oxidised to Zn.

Reason (R): Zn is more reactive than hydrogen & Zn will oxidised, & H+ will get reduced.

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 12
It shows that the reduced form of (Zn) is not stable. It is difficult to reduce Zn2+ to Zn. Rather the reverse reaction i.e Zn can get oxidised to Zn2+ and H+ will get reduced as it is stabler among both the reduced species.
Case Based Questions Test: Electrochemistry - Question 13

Read the passage given below and answer the following questions:

All chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules are present in a few gram of any chemical compound varying with their atomic/molecular masses. To handle such large number conveniently, the mole concept was introduced. All electrochemical cell reactions are also based on mole concept. For example, a 4.0 molar aqueous solution of NaCl is prepared and 500 mL of this solution is electrolysed. This leads to the evolution of chlorine gas at one of the electrode. The amount of products formed can be calculated by using mole concept.

The following questions are multiple choice questions. Choose the most appropriate answer:

Q. The total number of moles of chlorine gas evolved is

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 13

Case Based Questions Test: Electrochemistry - Question 14

Read the passage given below and answer the following questions:

All chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules are present in a few gram of any chemical compound varying with their atomic/molecular masses. To handle such large number conveniently, the mole concept was introduced. All electrochemical cell reactions are also based on mole concept. For example, a 4.0 molar aqueous solution of NaCl is prepared and 500 mL of this solution is electrolysed. This leads to the evolution of chlorine gas at one of the electrode. The amount of products formed can be calculated by using mole concept.

The following questions are multiple choice questions. Choose the most appropriate answer:

Q. If cathode is a Hg electrode, then the maximum weight of amalgam formed from this solution is

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 14

2 moles of amalgam = 23 x 2 + 2 x 200

= 446g

Case Based Questions Test: Electrochemistry - Question 15

Read the passage given below and answer the following questions:

All chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules are present in a few grams of any chemical compound varying with their atomic/molecular masses. To handle such large numbers conveniently, the mole concept was introduced. All electrochemical cell reactions are also based on mole concept. For example, a 4.0 molar aqueous solution of NaCl is prepared and 500 mL of this solution is electrolysed. This leads to the evolution of chlorine gas at one of the electrode. The amount of products formed can be calculated by using mole concept.

The following questions are multiple choice questions. Choose the most appropriate answer:

Q. In electrolysis of NaCl when Pt electrode is taken then H2 is liberated at cathode while with Hg cathode it forms sodium amalgam :-

Detailed Solution for Case Based Questions Test: Electrochemistry - Question 15
In electrolysis of NaCl when Pt electrode is taken thenH2 is liberated at cathode while with Hg cathode it forms sodium amalgam.

Conc of H+ ions is larger when the Pt electrode is taken. Hence, H+ ions are discharged in preference to Na+ ions. When Hg cathode is used Na+ ions are discharged.

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