If an endothermic reaction is non-spontaneous at freezing point of water and becomes feasible at its boiling point, then:
The free energy change due to a reaction Is zero when:
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The enthalpy change for a reaction does not depend upon:
The enthalpies of combustion of carbon and carbon monoxide are -393.5 and -283kjmol-1
respectively. The enthalpy of formation of carbon monoxide per mole is:
Standard entropy of X2,Y2 and XY3 are 60, 40 and 50 JK-1 Mol -1 respectively. For a given reaction, to be in equilibrium, the temperature will be :
An ideal gas expands in volume from 1 x 10-3 m3 to 1 x 10-2m3 at 300 K against a constant pressure of 1 x 10-5 Nm-2. The work done is:
What is the entropy change (in JK-1 mol -1 ) when 1 mole of ice is converted into water at 00C (The enthalpy change for the conversion of ice to liquid water is 6.0 KJ mol -1 at 00C)
The heat of formation for a compound in following reaction
. Equal volumes of two monatomic gases, A and B at sae temperature and pressure are mixed. The rato of specific heats (Cp/Cv) of the mixture will be:
. Considering entropy (S) as a thermodynamic parameter, the criterion for the spontaneity of any process is :
The enthalpy of fusion of water is 1.435 Kcal/mol. The molar entropy change for the melting of ice at 0oC is:
Given that :
The enthalpy of formation of carbon monoxide will be:
Atmospheric pressures recorded in different cities are as follows:
Consider the above data and mark the place at which liquid will boil first.
Bond dissociation enthalpy of H2, Cl2 and HCl are 434,242 and 431 KJ mol -1 respectively. Enthalpy of formation of HCl is:
Absolute zero is defined as the temperature :
4.4 g of a gas at STP occupies a volume of 2.24 L. the gas can be :
The ratio between most probable velocity, mean velocity and r.m.s velocity is :
In vander walls equation of state of the gas law, the constant ‘b’ is a measure of :
From heated mixture of nitrogen, oxygen and carbon, two compounds (out of the many obtained) are isolated . the rates of diffusion of the two isolated compounds are almost identical. The two compounds are .
The total pressure of a mixture of two gases is :
Dalton’s law of partial pressure will not apply to which of following mixture of gases
The values of van der Waals constant ‘a’ for the gases O2, N2, NH3 and CH4 are 1.360, 1.390, 4.170 and 2.253 L2 atm mol-2 respectively. The gas which can most easily be liquefied is:
A gas diffuse 1/5 times as fast as hydrogen Its molecular weight is
The compressibility factor for an ideal gas is:
At which one of the following temperature pressure conditions the deviation of a gas from ideal behaviour is expected to be minimum:
Which of the following volume (v) – temperature (T) plots represents the behavior of one mole of an ideal gas at one atmosphere ?