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Test: Chemistry - 1 - MCAT MCQ


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15 Questions MCQ Test - Test: Chemistry - 1

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Test: Chemistry - 1 - Question 1

If 3.21 g of silver nitrate reacts with an excess of sodium sulfate, what mass of silver sulfate will be produced?
(MM silver nitrate = 169.87 g/mol; MM sodium sulfate = 142.04 g/mol; MM silver sulfate = 311.799 g/mol; MM sodium nitrate = 84.9947 g/mol)11.8 g

Detailed Solution for Test: Chemistry - 1 - Question 1

The balanced chemical equation between silver nitrate and sodium sulfate is the following:

To calculate the mass of silver sulfate produced, the following conversion factors are applied:

Test: Chemistry - 1 - Question 2

Which of the following statements correctly describes an exothermic reaction?

Detailed Solution for Test: Chemistry - 1 - Question 2

In an exothermic reaction, energy is released in the form of heat to the surroundings. The reactants have a higher energy level compared to the products, and the excess energy is given off as heat. This is why exothermic reactions often feel warm or hot to the touch.

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Test: Chemistry - 1 - Question 3

What is the oxidation number of sulfur in the compound H2SO4?

Detailed Solution for Test: Chemistry - 1 - Question 3

In H2SO4 (sulfuric acid), the hydrogen atoms have an oxidation number of +1, and the oxygen atoms have an oxidation number of -2. To find the oxidation number of sulfur, we can set up the equation:
(+1) * 2 + x + (-2) * 4 = 0
Simplifying the equation gives:
2 + x - 8 = 0
x - 6 = 0
x = 6
Therefore, the oxidation number of sulfur in H2SO4 is +6.

Test: Chemistry - 1 - Question 4

Which of the following factors affects the rate of a chemical reaction?

Detailed Solution for Test: Chemistry - 1 - Question 4

The rate of a chemical reaction can be influenced by several factors, including temperature, pressure, and concentration. Increasing the temperature generally leads to faster reaction rates as it provides more energy for reactant molecules to collide effectively. Pressure affects the rate of reactions involving gases by altering the frequency of collisions. Increasing the concentration of reactants typically results in a faster reaction rate due to the increased number of collisions between reactant particles. Therefore, all of the options (a), (b), and (c) are correct factors that can affect the rate of a chemical reaction.

Test: Chemistry - 1 - Question 5

Pyruvate generated from glycolysis can follow different catabolic paths depending on many factors. In animal tissues and under anaerobic conditions, pyruvate is reduced to lactate and NADH is oxidized to NAD+, in a reaction catalyzed by lactate dehydrogenase. During the recovery period after strenuous exercise, lactate is converted back to glucose in the liver.
In an experiment, the lactate levels in blood for two athletes are measured at different times from the start of vigorous exercise. The results of the experiment are shown in the table below:

Q. Lactate dehydrogenase is classified as what type of enzyme? (You may consult the attachment.)

Detailed Solution for Test: Chemistry - 1 - Question 5

Oxidoreductases are enzymes that catalyze oxidation and reduction reactions in which electrons are transferred. The reduction of pyruvate to lactate and the oxidation of NADH to NAD+ is a redox reaction, hence lactate dehydrogenase is classified as an oxidoreductase.

Test: Chemistry - 1 - Question 6

Pyruvate generated from glycolysis can follow different catabolic paths depending on many factors. In animal tissues and under anaerobic conditions, pyruvate is reduced to lactate and NADH is oxidized to NAD+, in a reaction catalyzed by lactate dehydrogenase. During the recovery period after strenuous exercise, lactate is converted back to glucose in the liver.
In an experiment, the lactate levels in blood for two athletes are measured at different times from the start of vigorous exercise. The results of the experiment are shown in the table below:

Q. If an individual has a lactate dehydrogenase deficiency, what will be observed in a blood test during vigorous exercise? (You may utilize the attachment.)

Detailed Solution for Test: Chemistry - 1 - Question 6

If an individual has a lactate dehydrogenase deficiency, the pyruvate that is accumulated during vigorous exercise is not able to be converted to lactate, and the NADH is not able to be converted to NAD+. In that case, a blood test during vigorous exercise will show high concentration of both species.

Test: Chemistry - 1 - Question 7

Pyruvate generated from glycolysis can follow different catabolic paths depending on many factors. In animal tissues and under anaerobic conditions, pyruvate is reduced to lactate and NADH is oxidized to NAD+, in a reaction catalyzed by lactate dehydrogenase. During the recovery period after strenuous exercise, lactate is converted back to glucose in the liver.
In an experiment, the lactate levels in blood for two athletes are measured at different times from the start of vigorous exercise. The results of the experiment are shown in the table below:

Q. From the results of the experiment (see attachment), which athlete is in the best physical shape?

Detailed Solution for Test: Chemistry - 1 - Question 7

The lactate blood concentration of athlete A continues to rise after the lactate blood concentration of athlete B starts to decrease. This means that athlete A has a higher ability to provide his muscles with oxygen for a longer time, hence he is in the best physical shape.

Test: Chemistry - 1 - Question 8

Pyruvate generated from glycolysis can follow different catabolic paths depending on many factors. In animal tissues and under anaerobic conditions, pyruvate is reduced to lactate and NADH is oxidized to NAD+, in a reaction catalyzed by lactate dehydrogenase. During the recovery period after strenuous exercise, lactate is converted back to glucose in the liver.
In an experiment, the lactate levels in blood for two athletes are measured at different times from the start of vigorous exercise. The results of the experiment are shown in the table below:

Q. Which of the following statements about lactate formation is true? (See the attachment.)

Detailed Solution for Test: Chemistry - 1 - Question 8

In a redox reaction, the oxidizing agent is the chemical species that is being reduced, and the reducing agent is the chemical species that is being oxidized. For lactate formation, pyruvate is the oxidizing agent and NADH is the reducing agent.

Test: Chemistry - 1 - Question 9

Pyruvate generated from glycolysis can follow different catabolic paths depending on many factors. In animal tissues and under anaerobic conditions, pyruvate is reduced to lactate and NADH is oxidized to NAD+, in a reaction catalyzed by lactate dehydrogenase. During the recovery period after strenuous exercise, lactate is converted back to glucose in the liver.
In an experiment, the lactate levels in blood for two athletes are measured at different times from the start of vigorous exercise. The results of the experiment are shown in the table below:

Q. What is the net yield of NADH per mole of glucose for animal tissue under anaerobic conditions? (Using the attachment may help.)

Detailed Solution for Test: Chemistry - 1 - Question 9

Glycolysis generates 2 moles of NADH and 2 moles of pyruvate per mole of glucose, and lactate formation under anaerobic conditions consumes 1 mole of NADH per mole of pyruvate. This means that the net yield of NADH per mole of glucose is 0, because all the NADH produced by glycolysis is consumed to generate lactate.

Test: Chemistry - 1 - Question 10

Aromatic compounds possess a π system of exceptional stability. They are defined as cyclic, planar compounds with a number of conjugated π electrons equal to 4n+2, where n is a whole number (this is known as Hückel’s rule). Aromatic compounds have low reactivity and relatively high melting and boiling points. If a compound is cyclic and planar, and has a delocalized π system that does not obey Hückel’s rule, it is called antiaromatic.
Benzene is the most well-known aromatic compound. Its chemical structure is shown on the figure below:

The presence of substituents on benzene can increase or decrease its reactivity towards electrophilic aromatic substitution. If the substituent is an electron donor, reactivity increases, but if the substituent is an electron acceptor, reactivity decreases. Substituents with resonance have a stronger influence on reactivity than substituents with inductive effect.
Four different organic compounds labeled from A to D are studied. Their chemical structures are shown below:

Q. Which compound in the attachment is aromatic?

Detailed Solution for Test: Chemistry - 1 - Question 10

Compound A is cyclic, planar, and has 2 electrons in the π system, so it complies with Hückel’s rule. Compound B is not cyclic, compound C has 4 electrons in the π system so it does not comply with Hückel’s rule, and compound D is not planar.

Test: Chemistry - 1 - Question 11

Aromatic compounds possess a π system of exceptional stability. They are defined as cyclic, planar compounds with a number of conjugated π electrons equal to 4n+2, where n is a whole number (this is known as Hückel’s rule). Aromatic compounds have low reactivity and relatively high melting and boiling points. If a compound is cyclic and planar, and has a delocalized π system that does not obey Hückel’s rule, it is called antiaromatic.
Benzene is the most well-known aromatic compound. Its chemical structure is shown on the figure below:

The presence of substituents on benzene can increase or decrease its reactivity towards electrophilic aromatic substitution. If the substituent is an electron donor, reactivity increases, but if the substituent is an electron acceptor, reactivity decreases. Substituents with resonance have a stronger influence on reactivity than substituents with inductive effect.
Four different organic compounds labeled from A to D are studied. Their chemical structures are shown below:

Q. Which of the following statements regarding compounds A to D in the attachment is true?

Detailed Solution for Test: Chemistry - 1 - Question 11

Even though compound D is not entirely planar, the portion of the cycle that has the 6 π electrons can undergo resonance, making compound D a molecule with a conjugated π system. Compounds A and C are electrophiles and Lewis acids, and compound B is less stable than benzene, because benzene being a cyclic, aromatic molecule will have a less reactive π system.

Test: Chemistry - 1 - Question 12

Aromatic compounds possess a π system of exceptional stability. They are defined as cyclic, planar compounds with a number of conjugated π electrons equal to 4n+2, where n is a whole number (this is known as Hückel’s rule). Aromatic compounds have low reactivity and relatively high melting and boiling points. If a compound is cyclic and planar, and has a delocalized π system that does not obey Hückel’s rule, it is called antiaromatic.
Benzene is the most well-known aromatic compound. Its chemical structure is shown on the figure below:

The presence of substituents on benzene can increase or decrease its reactivity towards electrophilic aromatic substitution. If the substituent is an electron donor, reactivity increases, but if the substituent is an electron acceptor, reactivity decreases. Substituents with resonance have a stronger influence on reactivity than substituents with inductive effect.
Four different organic compounds labeled from A to D are studied. Their chemical structures are shown below:

Q. Which of the following compounds will be less reactive towards electrophilic aromatic substitution? (See attachment.)

Detailed Solution for Test: Chemistry - 1 - Question 12

Nitrobenzene is an electron attractor by resonance. This makes it strongly deactivating towards electrophilic aromatic substitution. Methoxybenzene and aminobenzene are activators by resonance, while fluorobenzene is only weakly deactivating by induction.

Test: Chemistry - 1 - Question 13

Aromatic compounds possess a π system of exceptional stability. They are defined as cyclic, planar compounds with a number of conjugated π electrons equal to 4n+2, where n is a whole number (this is known as Hückel’s rule). Aromatic compounds have low reactivity and relatively high melting and boiling points. If a compound is cyclic and planar, and has a delocalized π system that does not obey Hückel’s rule, it is called antiaromatic.
Benzene is the most well-known aromatic compound. Its chemical structure is shown on the figure below:

The presence of substituents on benzene can increase or decrease its reactivity towards electrophilic aromatic substitution. If the substituent is an electron donor, reactivity increases, but if the substituent is an electron acceptor, reactivity decreases. Substituents with resonance have a stronger influence on reactivity than substituents with inductive effect.
Four different organic compounds labeled from A to D are studied. Their chemical structures are shown below:

Q. Which of the 4 compounds in the attachment is/are antiaromatic?

Detailed Solution for Test: Chemistry - 1 - Question 13

For a compound to be antiaromatic, it needs to be cyclic and planar, but not comply with Hückel’s rule. In this case, compound C is cyclic and planar, but it has 4 electrons in the π system, which is not a Hückel’s number (4n+2).

Test: Chemistry - 1 - Question 14

Aromatic compounds possess a π system of exceptional stability. They are defined as cyclic, planar compounds with a number of conjugated π electrons equal to 4n+2, where n is a whole number (this is known as Hückel’s rule). Aromatic compounds have low reactivity and relatively high melting and boiling points. If a compound is cyclic and planar, and has a delocalized π system that does not obey Hückel’s rule, it is called antiaromatic.
Benzene is the most well-known aromatic compound. Its chemical structure is shown on the figure below:

The presence of substituents on benzene can increase or decrease its reactivity towards electrophilic aromatic substitution. If the substituent is an electron donor, reactivity increases, but if the substituent is an electron acceptor, reactivity decreases. Substituents with resonance have a stronger influence on reactivity than substituents with inductive effect.
Four different organic compounds labeled from A to D are studied. Their chemical structures are shown below:

Q. Which of the following compounds will be more reactive toward electrophilic aromatic substitution? (You may consult the attachment.)

Detailed Solution for Test: Chemistry - 1 - Question 14

Alkyl groups are activating groups by induction. They donate electronic density to the aromatic ring and increase reactivity towards electrophilic aromatic substitution. The strength of the inductive effect depends on the length of the alkyl chain, and in this case butylbenzene, having the longest alkyl group, will have a stronger inductive effect, making it more reactive towards electrophilic aromatic substitution.

Test: Chemistry - 1 - Question 15

The chemical structure of aspirin is shown in the attached image. What is the IUPAC name for aspirin?

Detailed Solution for Test: Chemistry - 1 - Question 15

The main functional group in aspirin is the carboxylic acid. This means that the suffix of the name of the compound would be -oic acid. The main alkyl backbone of the acid group is the benzyl radical, so the name of the compound is benzoic acid. The acetoxy radical is located on C′2 of the ring, so the full IUPAC name of aspirin would be 2-Acetoxybenzoic acid. Acetylsalicylic acid is a common name for aspirin, but it does not follow the IUPAC nomenclature system.

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