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Test: Isomerism in Coordination Compounds (January 1) - NEET MCQ


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10 Questions MCQ Test - Test: Isomerism in Coordination Compounds (January 1)

Test: Isomerism in Coordination Compounds (January 1) for NEET 2024 is part of NEET preparation. The Test: Isomerism in Coordination Compounds (January 1) questions and answers have been prepared according to the NEET exam syllabus.The Test: Isomerism in Coordination Compounds (January 1) MCQs are made for NEET 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Test: Isomerism in Coordination Compounds (January 1) below.
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Test: Isomerism in Coordination Compounds (January 1) - Question 1

Only One Option Correct Type

Direction (Q. Nos. 1-10) This section contains 10 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.

Q. 

Tris (ethylenediamine) cobalt (III) cation, [Co(en)3]3+ can have

Detailed Solution for Test: Isomerism in Coordination Compounds (January 1) - Question 1


Optical isomers have mirror images that cannot be superimposed on one another. These are called as enantiomers. The molecules or ions that cannot be superimposed are called chiral.

Test: Isomerism in Coordination Compounds (January 1) - Question 2

What type of isomerism is shown by [Co(NH3)4Br2]Cl?

Detailed Solution for Test: Isomerism in Coordination Compounds (January 1) - Question 2

The complex [Co(NH3)4Br2]CI show geometrical and ionisation isomerism.

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Test: Isomerism in Coordination Compounds (January 1) - Question 3

The ionisation isomer of [Cr(H2O)4 CI(NO2)]CI is

Detailed Solution for Test: Isomerism in Coordination Compounds (January 1) - Question 3

Ionisation isomerism is due to the exchange of groups between the complex ion and the ions outside it, e.g. [Cr(H2O)4CI(NO2)CI] and [Cr(H2O)4CI2]NO2 show ionisation isomerism. 

Test: Isomerism in Coordination Compounds (January 1) - Question 4

Which of the following complex species is not expected to exhibit optical isomerism?

Detailed Solution for Test: Isomerism in Coordination Compounds (January 1) - Question 4

[CoNH3CI3] do not exhibit optical isomerism. Optical isomerism is shown by M(AA)2X2 type, M(AA)3 type , [M(AA) B2X2] type complexes containing hexadentate ligand and MLa Lb Lc Ld Left type.

Test: Isomerism in Coordination Compounds (January 1) - Question 5

Which of the following is considered to be an anticancer species?

Detailed Solution for Test: Isomerism in Coordination Compounds (January 1) - Question 5

cis platin is used as anticancer drug.

Test: Isomerism in Coordination Compounds (January 1) - Question 6

Which of the following statements is/are correct?

Detailed Solution for Test: Isomerism in Coordination Compounds (January 1) - Question 6

Geometrical isomerism is not observed in complexes of coordination number 4 having tetrahedral geometry. The platinumglycinato complex [ Pt(gly)2 show geometrical isomerism (cis and trans form).

Test: Isomerism in Coordination Compounds (January 1) - Question 7

Comprehension Type

Direction (Q. Nos. 16 and 17) This section contains a paragraph, describing theory, experiments, data etc. Two questions related to the paragraph have been given. Each has only one correct answer among the four given options (a) ,(b), (c) and (d).

Passage

Consider the following isomers of [Co(NH3)4Br2]+. The black sphere represents Co, grey sphere represents NH3 and unshaded sphere represents Br.

Q.

The oxidation state and coordination number of cobalt in the complex [Co(NH3)4Br2]+ are

Detailed Solution for Test: Isomerism in Coordination Compounds (January 1) - Question 7

For O.S:

X + 0 + 2(-1) = 1

X = 3

Coordination number is the number of molecules linked to the central atom.

Hence B is the correct answer.

*Answer can only contain numeric values
Test: Isomerism in Coordination Compounds (January 1) - Question 8

One Integer Value Correct Type

Direction (Q. Nos. 20-24) This section contains 5 questions. When worked out will result in an integer from 0 to 9 (both inclusive).

Q. 

Total number of geometrical isomers for the complex [RhCI(CO)(PPh3)(NH3)] is


Detailed Solution for Test: Isomerism in Coordination Compounds (January 1) - Question 8

For a complex of the type MABCD, three geometrical isomers are possible.

*Answer can only contain numeric values
Test: Isomerism in Coordination Compounds (January 1) - Question 9

The total number of isomers of [Co(en)2CI2]+ is


Detailed Solution for Test: Isomerism in Coordination Compounds (January 1) - Question 9

The complex has cis and trans isomers. The c/s has non-superimposable mirror images. Hence, total are 3.

*Answer can only contain numeric values
Test: Isomerism in Coordination Compounds (January 1) - Question 10

For square planar complex of platinum (II), [Pt(NH3)(Br)(CI)py]2+, how many isomeric forms are possible?


Detailed Solution for Test: Isomerism in Coordination Compounds (January 1) - Question 10

[Mabcd] type complexes exist in three isomeric forms. 


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