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30 Questions MCQ Test TS EAMCET Mock Test Series - TS EAMCET Mock Test - 2

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TS EAMCET Mock Test - 2 - Question 1

In the following question, a Statement of Assertion (A) is given followed by a corresponding Reason (R) just below it. Read the Statements carefully and mark the correct answer-
Assertion(A): Refractive index of a material depends on the frequency of the light
Reason(R): Incoming e.m. wave applies an electric field and polarises it, contributing to (∈) permittivity of the medium, depending on its frequency.

TS EAMCET Mock Test - 2 - Question 2

A spherical ball rolls on a table without slipping. Then the fraction of its total energy associated with rotation is

TS EAMCET Mock Test - 2 - Question 3

In the following question, a Statement of Assertion (A) is given followed by a corresponding Reason (R) just below it. Read the Statements carefully and mark the correct answer-
Assertion(A): The density of air at the top of the troposphere is about 10 times the density near the earth's surface.
Reason(R): The atmosphere between the heights of 12 km and 50 km is called troposphere.

TS EAMCET Mock Test - 2 - Question 4
A straight wire of length l and electric dipole moment p is bent to form a semicircle. The new dipole moment would be
TS EAMCET Mock Test - 2 - Question 5
A glof ball of mass 0.05 kg placed on a tee, is struck by a golf club. The speed of the golf ball as it leaves the tee is 100 m/s, the time of contact between them is 0.02 s. If the force decreases to zero linearly with time, then the force at the beginning of the contact is
TS EAMCET Mock Test - 2 - Question 6
In neutron discovery experiment, Berillium element is bombarded by
TS EAMCET Mock Test - 2 - Question 7
A stationary point source of sound emits sound uniformly in all directions in a non-absorbing medium. Two points P and Q are at a distance of 4m and 9m respectively from the source. The ratio of amplitudes of the waves at P and Q is
TS EAMCET Mock Test - 2 - Question 8

The dominant contribution to current comes from holes in case of

TS EAMCET Mock Test - 2 - Question 9

Following compounds are respectively ... geometrical isomers

Detailed Solution for TS EAMCET Mock Test - 2 - Question 9

In I and II both neighbouring Cl are on the same side, thus both of them are cis whereas for III, both Cl are on the opposite side. Thus, it is trans

So correct option is d) I = cis, II = cis, III = trans 

TS EAMCET Mock Test - 2 - Question 10
If H₂S is passed in ZnSO₄ containing HCl,Zinc sulphide is not precipitated because Ksp of
TS EAMCET Mock Test - 2 - Question 11
The order of a reaction depends upon
TS EAMCET Mock Test - 2 - Question 12
The pH of blood is around
TS EAMCET Mock Test - 2 - Question 13

The largest bond angle is in

Detailed Solution for TS EAMCET Mock Test - 2 - Question 13

To determine which molecule has the largest bond angle among AsH₃, NH₃, H₂O, and PH₃, we need to consider their molecular geometries and the factors affecting bond angles, such as lone pair repulsion and atomic size.

All four molecules have a central atom bonded to hydrogen atoms, with lone pairs on the central atom. Their geometries are derived from a tetrahedral electron pair arrangement (4 electron pairs around the central atom), but the molecular shape is different due to lone pairs:

  • NH₃ (Nitrogen, Group 15): Nitrogen has 5 valence electrons, forms 3 N-H bonds, and has 1 lone pair. The electron geometry is tetrahedral, but the molecular shape is trigonal pyramidal. Bond angle ≈ 107°.
  • PH₃ (Phosphorus, Group 15): Phosphorus also has 5 valence electrons, 3 P-H bonds, and 1 lone pair. The electron geometry is tetrahedral, molecular shape is trigonal pyramidal. Bond angle ≈ 93.5°.
  • AsH₃ (Arsenic, Group 15): Arsenic has 5 valence electrons, 3 As-H bonds, and 1 lone pair. Electron geometry is tetrahedral, molecular shape is trigonal pyramidal. Bond angle ≈ 91.8°.
  • H₂O (Oxygen, Group 16): Oxygen has 6 valence electrons, forms 2 O-H bonds, and has 2 lone pairs. Electron geometry is tetrahedral, molecular shape is bent. Bond angle ≈ 104.5°.

Factors Affecting Bond Angles:

  1. Lone Pair Repulsion: Lone pairs repel bonding pairs more strongly than bonding pairs repel each other (VSEPR theory). H₂O has 2 lone pairs, which causes more compression of the bond angle compared to NH₃, PH₃, and AsH₃, which have 1 lone pair each.
  2. Atomic Size: For NH₃, PH₃, and AsH₃ (all Group 15 hydrides), as the central atom size increases (N → P → As), the bond angle decreases. This is because larger atoms have longer bond lengths, and the lone pair occupies a more s-like orbital, reducing repulsion with bonding pairs, leading to smaller bond angles.

Bond Angle Comparison:

  • NH₃: 107° (1 lone pair, smaller N atom → more lone pair repulsion).
  • H₂O: 104.5° (2 lone pairs → more repulsion, but still less than NH₃ due to geometry).
  • PH₃: 93.5° (larger P atom → less lone pair repulsion).
  • AsH₃: 91.8° (even larger As atom → even less lone pair repulsion).

Conclusion:

NH₃ has the largest bond angle due to the smaller size of nitrogen, which causes greater lone pair-bond pair repulsion, pushing the H-N-H bonds closer together compared to PH₃ and AsH₃. H₂O, despite having more lone pairs, has a slightly smaller bond angle than NH₃ due to the bent shape and stronger lone pair repulsion.

Correct Answer:

c) NH₃

TS EAMCET Mock Test - 2 - Question 14
The heating together of sodium ethoxide and ethyl chloride will give
TS EAMCET Mock Test - 2 - Question 15
For the reaction A→B, the rate law expression is rate = k[A]. Which of the following statements is incorrect?
TS EAMCET Mock Test - 2 - Question 16

If in a moderately asymmetrical distribution mode and mean of the data are 6λ and 9λ respectively, then median is

TS EAMCET Mock Test - 2 - Question 17
For solving dy/dx=4x+y+1 suitable substitution is
TS EAMCET Mock Test - 2 - Question 18
The solution of the differential equation cos x sin y dx + sin x cos y dy =0 is
TS EAMCET Mock Test - 2 - Question 19
The solution of the equation |z| - z = 1 + 2i is
TS EAMCET Mock Test - 2 - Question 20

In the following question, a Statement of Assertion (A) is given followed by a corresponding Reason (R) just below it. Read the Statements carefully and mark the correct answer-
Assertion(A): If f : R → R defined by f (x) = x3 then f is one one onto
Reason(R) : Function f is strictly decreasing on R.

TS EAMCET Mock Test - 2 - Question 21

If the line 2x - y + k = 0 is a diameter of the circle x2 + y2 + 6x -6y + 5 =0, then k is equal to

TS EAMCET Mock Test - 2 - Question 22

If P(B)=(3/4), P(A∩B∩C̅) = (1/3) and P(A̅∩B∩C̅) = 1/3, then P(B∩C) is

TS EAMCET Mock Test - 2 - Question 23

A die is thrown 100 times. If getting an odd number is considered a success, the variance of the number of successes is

TS EAMCET Mock Test - 2 - Question 24

In the following question, a Statement of Assertion (A) is given followed by a corresponding Reason (R) just below it. Read the Statements carefully and mark the correct answer-

TS EAMCET Mock Test - 2 - Question 25

The equation of the directrix to the parabola y2 − 2x − 6y − 5 = 0 is

TS EAMCET Mock Test - 2 - Question 26

If y=sin((1+x2)/(1-x2)), (dy/dx)=

Detailed Solution for TS EAMCET Mock Test - 2 - Question 26

TS EAMCET Mock Test - 2 - Question 27

In the following question, a Statement of Assertion (A) is given followed by a corresponding Reason (R) just below it. Read the Statements carefully and mark the correct answer-
Assertion(A): The domain of the function
Reason (R): The domain of the function

TS EAMCET Mock Test - 2 - Question 28

The limiting point of the system of co-axial circles x2+y2-6x-6y+4=0, x2+y2-2x-4y+3=0 is

TS EAMCET Mock Test - 2 - Question 29

If x+y+1=0 tocuhes the parabola y2=λx,then λ is equal to

TS EAMCET Mock Test - 2 - Question 30

The complex equation |z + 1 − i| = |z + i − 1| represents a

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