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Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - JEE MCQ


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10 Questions MCQ Test - Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14)

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Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 1

In the evaporation of water, the entropy

Detailed Solution for Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 1

As the randomness increases on evaporation, entropy also increases. 
The greater the randomness in a system, greater is its entropy.

Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 2

The value of ΔS for spontaneous process is

Detailed Solution for Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 2

The second law of thermodynamics states that for any spontaneous process, the overall ΔS must be greater than or equal to zero.

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Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 3

What is the change in the entropy of water, When ice melts into water?

Detailed Solution for Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 3

The greater the randomness in a system, greater is its entropy. The randomness is greater in liquid state as compared to solid state so the entropy increases when ice melts into water.

Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 4

 For the reaction Hg (l) ———> Hg (g) , the entropy change will have the sign:

Detailed Solution for Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 4

In this reaction,  disordered gaseous state changes to liquid state.

Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 5

Which of the following is extensive property?

Detailed Solution for Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 5

Intensive properties: Properties which are independent of the amount of substance (or substances) present in the system are called intensive properties, e.g. pressure, density, temperature, viscosity, surface tension, refractive index, emf, chemical potential, sp. heat etc, These are intensive properties.
So, we can say that entropy is an extensive property.

Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 6

 Which of the following is true about a spontaneous process?

Detailed Solution for Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 6

In cases where ΔG is: negative, the process is spontaneous and proceed in the forward direction.

Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 7

For a spontaneous chemical process, the free energy change is

Detailed Solution for Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 7

The sign of ΔG will change from positive to negative (or vice versa) where T = ΔH/ΔS. In cases where ΔG is: negative, the process is spontaneous and may proceed in the forward direction as written. positive, the process is non-spontaneous as written, but it may proceed spontaneously in the reverse direction.

Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 8

Which of the following statements is correct about the process of evaporation of water from an open beaker?

Detailed Solution for Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 8

Evaporation of water from an open pot is a spontaneous process. As it starts on its own without any external agent. However it takes heat from surrounding means that it is endothermic.

Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 9

Which of the following is NOT a state function?

Detailed Solution for Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 9

A state function is the property of the system whose value depends only on the initial and final state of the system and is independent of the path. It is a state function because it is independent of the path. Heat (q) and work (W) are not state functions being path dependent.

Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 10

The equilibrium constant for a reaction is 10. Calculate the value of ΔG° at 300K

Detailed Solution for Test: Spontaneity & Gibbs Energy Change and Equilibrium (June 14) - Question 10

The value of equilibrium constant(k) = 10
∆G° = -2.303RTlogk
On calculating values, we will get ∆G° = -5.744kJmol-1

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