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Test: Alkynes & Aromatic hydrocarbon(10 Sep) - JEE MCQ


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10 Questions MCQ Test - Test: Alkynes & Aromatic hydrocarbon(10 Sep)

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Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 1

What two atomic or hybrid orbitals overlap to form the carbon-carbon σ (sigma) bond in ethyne?

Detailed Solution for Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 1

The correct answer is option C
The chemical bonding in acetylene (ethyne) (C2H2) consists of sp-sp overlap between the two carbon atoms forming a sigma bond, as well as two additional pi bonds formed by p-p overlap. Each carbon also bonds to hydrogen in a sigma s-sp overlap at 180 degree angles.

Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 2

When 2,3-dibromobutane is treated with KOH in ethanol, 2-bromo-2-butene is formed which does not undergo further dehydrobromination to form 2-butyne under similar condition because

Detailed Solution for Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 2


Because vinyl bromide is less reactive and Alc. KoH is not that strong a base; we need a strong base like NaNH2 .

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*Multiple options can be correct
Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 3

Which of the following reagents gives an effervescence when reacted with 1-butyne?

Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 4

Statement I : Treatment of either 1,2-dibromobutane or 2,2-dibromobutane with NaNH2 gives the same 1-butyne.

Statement II : NaNH2 forms salt with terminal alkyne which makes possible the above observation.

Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 5

Statement l : C6H5MgBr with propyne gives 1-phenyl propyne.

Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 6

Which set of reagent(s) in correct order would accomplish the following transformation?

Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 7

What is true about the final major product of the reaction?

*Multiple options can be correct
Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 8

Which of the following sets of reagent when applied sequentially, on 2-butyne will produce a meso product?

Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 9

Direction (Q. Nos. 15 - 20) This section contains 2 paragraphs, each describing theory, experiments, data, etc. Six questions related to the paragraphs have been given. Each question has only one correct answer among the four given options (a), (b), (c) and (d).

Passage I

Unlike alkenes, alkynes undergo nucleophilic addition as well as electrophilic addition as :

 

Q. Which of the following best describes what happens in the first step in the mechanism of reaction shown below?

*Answer can only contain numeric values
Test: Alkynes & Aromatic hydrocarbon(10 Sep) - Question 10

Direction (Q. Nos. 21 - 24) This section contains 4 questions. When worked out will result in an integer from 0 to 9 (both inclusive).

Q. How many different isomeric alkynes on catalytic hydrogenation can give 2, 3, 4 -trimethyl heptane?


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