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Test: Colligative Properties and Abnormal Molecular Masses - JEE MCQ


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15 Questions MCQ Test - Test: Colligative Properties and Abnormal Molecular Masses

Test: Colligative Properties and Abnormal Molecular Masses for JEE 2024 is part of JEE preparation. The Test: Colligative Properties and Abnormal Molecular Masses questions and answers have been prepared according to the JEE exam syllabus.The Test: Colligative Properties and Abnormal Molecular Masses MCQs are made for JEE 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Test: Colligative Properties and Abnormal Molecular Masses below.
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Test: Colligative Properties and Abnormal Molecular Masses - Question 1

What is the van't Hoff factor of Ferric Sulphate (Assume ionization)

Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 1

Ferric sulphate
(complete ionization)
⇒ van't Hoff factor = i = 2 + 3 = 5.

Test: Colligative Properties and Abnormal Molecular Masses - Question 2

 Relative lowering of vapour pressure is directly proportional to

Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 2

Relative lowering of vapour pressure is directly proportional to mole fraction of solute. Hence it is a colligative property.
 

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Test: Colligative Properties and Abnormal Molecular Masses - Question 3

When common salt is dissolved in water:

Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 3

The correct answer is Option B.

When a non-volatile solute is dissolved in a pure solvent, its vapour pressure is decreased. The difference in the boiling points of the solution and pure solvent is called elevation in boiling point.
 
The elevation in the boiling point of a solution of nonelectrolyte is proportional to its molality and the equimolal solution of all the substances in the same solvent will show an equal elevation in boiling points. These are known as Raoult's laws of elevation of the boiling point.
 
So, the addition of salt will increase the boiling point of the solution.
 

Test: Colligative Properties and Abnormal Molecular Masses - Question 4

Camphor is used as solvent to determine the molecular mass of non-volatile solute by Rast method because for camphor

Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 4

The correct answer is “molal depression constant is high”.

Camphor is used for the determination of molecular masses of solute by Rast method because its molal depression constant is very high 40Kmolality-1 .

Test: Colligative Properties and Abnormal Molecular Masses - Question 5
of an aqueous solution of a protein contains its . The osmotic pressure of this solution at is found to be bar. The molar mass of protein will be
Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 5
Osmotic pressure


Molecular mass
Test: Colligative Properties and Abnormal Molecular Masses - Question 6

The difference between the boiling point and freezing point of an aqueous solution containing sucrose (molecular in of water is . If and of water are and respectively, the weight of sucrose in the solution is about

Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 6




i.e., moles in water
(or) moles in water
∴ Wt. of sucrose

Test: Colligative Properties and Abnormal Molecular Masses - Question 7

A solution containing 1.8 g of a compound (empirical formula CH2O) in 40 g of water is observed to freeze at −0.465C. The molecular formula of the compound is (Kf of water = 1.86 kg K mol−1)

Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 7




Molecular formula
Molecular formula

Test: Colligative Properties and Abnormal Molecular Masses - Question 8
Freezing point of an aqueous solution is . If the values of and of water are respectively and , then the elevation of boiling point of the solution in is
Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 8



Test: Colligative Properties and Abnormal Molecular Masses - Question 9

If the elevation in boiling point of a solution of of solute . wt. in of water is , the ebullioscopic constant of water is

Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 9

Test: Colligative Properties and Abnormal Molecular Masses - Question 10

Which one of the following statements is incorrect?

Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 10

ΔTf = K× m × i.
Since Kf has different values for different solvents, hence even if m is the same ΔTf will be different

Test: Colligative Properties and Abnormal Molecular Masses - Question 11
and atm are the osmotic pressures of (mass/volume) solutions of urea, fructose, sucrose and respectively at certain temperature. The correct order of their magnitudes is :
Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 11
Moles of urea ;
moles of fructose

moles of sucrose

moles of (effective)


this order is
Test: Colligative Properties and Abnormal Molecular Masses - Question 12
Which of the following has been arranged in the increasing order of freezing point?
Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 12
Greater is the effective molarity , higher the value and lower the freezing point.
(i)
(ii)
(iii)
(iv)
Thus, order is
Test: Colligative Properties and Abnormal Molecular Masses - Question 13
1.0 aqueous solution of freezes at . Assuming complete ionization of the hydrated complex, which of the following isomers conforms to the observation for water ?
Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 13


Test: Colligative Properties and Abnormal Molecular Masses - Question 14
A living cell contains a solution which is isotonic with glucose solution. What osmotic pressure develops when the cell is placed in solution at
Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 14
For non electrolyte solute (glucose)
For
ionized
number of ions afterionization



Test: Colligative Properties and Abnormal Molecular Masses - Question 15

A solution of 0.5 g of a solute (molar mass = 150 g mol−1) in 50 g of a solvent yields a boiling point elevation of 0.40 K. Another solution of 0.60 g of an unknown solute in the same mass of solvent exhibits a boiling point elevation of 0.8 K. The molar mass of unknown solute is :

Detailed Solution for Test: Colligative Properties and Abnormal Molecular Masses - Question 15

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