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Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - JEE MCQ


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15 Questions MCQ Test - Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law

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Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 1

A device that converts energy of combustion of fuels like hydrogen and methane, directly into electrical energy is known as:

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A device that converts energy of combustion of fuels, directly into electrical energy is known as fuel cell.
Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 2

Schematic diagram of an electrolytic cell is

Detailed Solution for Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 2


In electrolytic cell,
Cation moves to cathode and anion moves to anode.

Electrons move anode to cathode.

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Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 3

The metal that can not be obtained by electrolysis of an aqueous solution of its salt is

[JEE Main 2014]

Detailed Solution for Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 3

In electro chemical series (ECS),

thus, Ca2+ ion is not reduced to C a instead, H2O is reduce d to H2

Ag, Cu and Cr are below H in ECS (E°reduction > 0), thus they are reduced to metals on electrolysis.

Note In ECS, Ca, H, Cr, Cu elements lying above H are better reducing agents thus are easily oxidised.

Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 4
A concentration cell is a galvanic cell in which
Detailed Solution for Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 4
In concentration cell the spontaneous process is physical in nature involving transfer of matter from higher concentration to lower concentration in indirect manner
Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 5
How long a current of 3 amperes has to be passed through a solution of to coat a metal surface of and thick layer. Density of is
Detailed Solution for Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 5
Volume Area thickness
Mass Volume density
Mass of to be deposited

Amount deposited
seconds
Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 6
In which of the following cells, the space between cathode and anode is filled by a moist mixture of ammonium choride and zinc chloride?
Detailed Solution for Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 6
Leclanche cell consist of a zinc container which acts as anode. The cathode is a carbon (graphite) rod surrounded by a mixture of powdered manganese dioxide and carbon.
The space between cathode and anode is filled by a moist mixture of ammonium chloride and zinc chloride.
Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 7

Which colourless gas evolves, when reacts with zinc in a dry cell battery

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Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 8

The e.m.f. of a Daniell cell at 298 K is 
When the concentration of ZnSO4 is 1.0M and that of CuSO4 is 0.01M, the e.m.f. changed to E2. What is the relationship between E1 and E2 ?

Detailed Solution for Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 8

Cell reaction is,

Greater the factor , less is the EMF Hence

Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 9
of pure silver was converted into silver nitrate and its solution was taken in a beaker. It was electrolysed using platinum cathode and silver anode. Faraday of electricity was passed using volt above the decomposition potential of silver. The silver content of the beaker after the above shall be
Detailed Solution for Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 9

mole of electrons
left
Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 10
The acts as sacrificial or cathodic protection to prevent rusting of iron because :
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of of
Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 11
Two half cells have reduction potentials and respectively. A galvanic cell is made from these two half cells. Which of the following statements is correct?
Detailed Solution for Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 11
According to the electrochemical series, the electrode with high reduction potential will act as a cathode, and the electrode with more negative reduction potential acts as the anode.
Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 12
Aqueous solution of which of the following compounds is the best conductor of electric current?
Detailed Solution for Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 12
completely dissociates to give and ions, hence act as very good electrolyte. While others are non- electrolytes.
Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 13
A hydrogen gas electrode is made by dipping platinum wire in a solution of of and by passing hydrogen gas around the platinum wire at one atm pressure. The oxidation potential of electrode would be ?
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Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 14

Mark the false statement?

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Correct Nernst equation is

Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 15
In the silver plating of copper, is used instead of . The reason is
Detailed Solution for Test: Electrolysis & Faraday's Laws, Kohlrausch’s Law - Question 15
In the silver plating of copper, is used instead of . Copper being more electropositive readily precipitate silver from their salt solution

whereas in solution a complex anion is formed and hence are less available in the solution and therefore copper cannot displace Ag from its complex ion.
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