Test: Preparation and Properties of Amines - JEE MCQ
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20 Questions MCQ Test - Test: Preparation and Properties of Amines
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Test: Preparation and Properties of Amines - Question 1
Which of the following pairs of reactants is most effective in forming an enamine?
Detailed Solution for Test: Preparation and Properties of Amines - Question 1
amine must be less sterically hindered. In option (b) and (c) 
amine is being used but due to more reactivity of aldehyde compared to cyclohexanone. Option (c) is correct.
Test: Preparation and Properties of Amines - Question 2
The general formula of Diazonium salt is:
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;
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Test: Preparation and Properties of Amines - Question 4
In the following sequence of reactions, what is D?
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Test: Preparation and Properties of Amines - Question 5
An organic compound 'A'on treatment with 
gives ' 
' which on heating gives ' 
' when treated with 
in the presence of KOH produces ethylamine. Compound 'A' is:
gives ' ' which on heating gives ' ' when treated with in the presence of KOH produces ethylamine. Compound 'A' is:
Detailed Solution for Test: Preparation and Properties of Amines - Question 5
when heated with 
in presence of 
produces ethylamine, hence it must be propanamide and hence the organic compound (A) will be propanoic acid. The reactions follows.
(A)
Test: Preparation and Properties of Amines - Question 6
An organic amino compound reacts with aqueous nitrous acid at low temperature to produce an oily nitrosoamine. The compound is
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Test: Preparation and Properties of Amines - Question 7
Which of the following statements are correct ?
(i) In Sandmeyer reaction nucleophiles like
and 
are indroduced in benzene ring in the presence of 
ion
(ii) In Gattermann reaction nucleophiles are introduced in benzene ring in the presence of copper powder and
.
(iii) The yield in Gattermann reaction is found to be better than Sandmayer reaction.
(i) In Sandmeyer reaction nucleophiles like
and are indroduced in benzene ring in the presence of ion(ii) In Gattermann reaction nucleophiles are introduced in benzene ring in the presence of copper powder and
.(iii) The yield in Gattermann reaction is found to be better than Sandmayer reaction.
Detailed Solution for Test: Preparation and Properties of Amines - Question 7
Test: Preparation and Properties of Amines - Question 8
Consider the following sequence of reactions:
Compound
The compound
is
Compound
The compound
is
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Test: Preparation and Properties of Amines - Question 9
The correct order of basicity of the following compounds
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Test: Preparation and Properties of Amines - Question 10
Which of the following compounds is most basic?
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Test: Preparation and Properties of Amines - Question 11
Match the compounds given in List - I with their characteristic reactions given in List - II. Select the correct option.
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(alcohol) and 
produces bad smell
Test: Preparation and Properties of Amines - Question 12
Which reaction sequence would be best to prepare 3-chloroanilne from benzene?
Detailed Solution for Test: Preparation and Properties of Amines - Question 12
group in ortho-position, not in 
-position
group is reduced earlier than the chlorination step, 
group formed on reduction will again introduce 
in o-position
Test: Preparation and Properties of Amines - Question 13
The reduction of nitro compounds is most preferred in the presence of
Detailed Solution for Test: Preparation and Properties of Amines - Question 13
formed gets hydrolysed to release hydrochloric acid during the reaction. Thus, only a small amount of hydrochloric acid is required to initiate the reaction.
Test: Preparation and Properties of Amines - Question 14
The correct order of basicities of the following compounds is:
Detailed Solution for Test: Preparation and Properties of Amines - Question 14
amines are more basic than 
, while amides
Test: Preparation and Properties of Amines - Question 15
Which of the following reactions will not give a primary amine?
Detailed Solution for Test: Preparation and Properties of Amines - Question 15
(methyl isocyanide) on reduction with 
gives secondary amine.
Test: Preparation and Properties of Amines - Question 16
Indicate which nitrogen compound amongst the following would undergo Hoffmann reaction (i.e.., reaction with 
and strong 
) to furnish the primary amine 
and strong ) to furnish the primary amine
Detailed Solution for Test: Preparation and Properties of Amines - Question 16
amides (i.e. 
) in the present case undergo Hofmann bromamide reaction.
Test: Preparation and Properties of Amines - Question 17
Reagents capable of converting cyclohexanone to N-ethyl cyclohexylamine is
Detailed Solution for Test: Preparation and Properties of Amines - Question 17
Test: Preparation and Properties of Amines - Question 18
Which of the following gives propylamine upon hydrolysis?
Detailed Solution for Test: Preparation and Properties of Amines - Question 18
or amines.
Test: Preparation and Properties of Amines - Question 19
Number of amines which will form colourful dye with 
and form azodye
and form azodye
Detailed Solution for Test: Preparation and Properties of Amines - Question 19
Test: Preparation and Properties of Amines - Question 20
Total Number of reactions in which product is 
amine
amine
Detailed Solution for Test: Preparation and Properties of Amines - Question 20
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