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MCQ Practice Test & Solutions: Chemistry: Topic-wise Test- 4 (45 Questions)

You can prepare effectively for NEET NEET Mock Test Series - Updated 2026 Pattern with this dedicated MCQ Practice Test (available with solutions) on the important topic of "Chemistry: Topic-wise Test- 4". These 45 questions have been designed by the experts with the latest curriculum of NEET 2026, to help you master the concept.

Test Highlights:

  • - Format: Multiple Choice Questions (MCQ)
  • - Duration: 45 minutes
  • - Number of Questions: 45

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Chemistry: Topic-wise Test- 4 - Question 1

The number of moles of acidified KMnO4 required to convert one mole of sulphite ion into sulphate ion is-

Detailed Solution: Question 1

Chemistry: Topic-wise Test- 4 - Question 2

N2(g) + 3H2 (g)  2NH3(g) ; Haber's process, Mo is used as -

Detailed Solution: Question 2

MO is catalytic promoter & it improves catalytic properties as catalyst

*Multiple options can be correct
Chemistry: Topic-wise Test- 4 - Question 3

Potash alum is a double salt, its aqueous solution shows the characteristics of-

Detailed Solution: Question 3

K2SO4 .Al2(SO4)3.24 H2O + H2O

Chemistry: Topic-wise Test- 4 - Question 4

x is moles of HIO4 consumed

Detailed Solution: Question 4

Chemistry: Topic-wise Test- 4 - Question 5

Product (B) is -

Detailed Solution: Question 5

Chemistry: Topic-wise Test- 4 - Question 6

; Product (A) is -

Detailed Solution: Question 6

Chemistry: Topic-wise Test- 4 - Question 7

Product of above reaction is obtained by

Detailed Solution: Question 7

Chemistry: Topic-wise Test- 4 - Question 8

, Products obtained in the above reaction are -

Detailed Solution: Question 8

Chemistry: Topic-wise Test- 4 - Question 9

The vapour pressure of n-hexane at 350 K is 840 torr and that of cyclohexane is 600 torr. Mole fraction of hexane in the mixture that boils at 350 K and 1 atm pressure assuming ideal behaviour is

Detailed Solution: Question 9

d) Mixture boils at 1 atm and 350 K.
Thus, total vapour pressure is 1 atm = 760torr (h) used for hexane and (ch) for cyclohexane.

Chemistry: Topic-wise Test- 4 - Question 10

At 298 K, the vapour pressure of pure water is 23.76 mm Hg and that of an aqueous solution is 22.98 mm Hg. Thus, molality of solution is (assume dilute solution) 

Detailed Solution: Question 10

(c)

By Raoult’s law for a non-volatile solute in volatile solvent.

Chemistry: Topic-wise Test- 4 - Question 11

12.8 g of naphthalene (C10H8) is dissolved in 92 g toluene (C7H8). Boiling point of this solution is

(boiling point of toluene = 110°Cand mole fraction boiling point elevation constant of toluene is 36.1 K)

Detailed Solution: Question 11

When (Kz) mole fraction boiling point elevation constant is given, then

Thus,boiling point of solution =110+ 3.28 =113.28°C 

Chemistry: Topic-wise Test- 4 - Question 12

Elevation in boiling point of a molar (1 M) glucose solution (d = 1.2 g mL-1) is

Detailed Solution: Question 12

(a) Molarity =1 M =1 mol L-1

 1000 mL of solution has glucose = 180 g

(1000 x 1.2) g of solution has glucose = 180g

∴ Solute (w1) =180 g

Solution =1200 g 

Chemistry: Topic-wise Test- 4 - Question 13

For a dilute solution containing 2.5 g of a non-volatile non-electrolyte solute in 100 g water, the elevation in boiling point at 1 atm pressure is 2°C. Assuming concentration of solute is much lower than the concentration of solvent, the vapour pressure (mm of Hg) of the solution is (Take, Kb = 0.76 K mol-1 kg).

[IITJEE2012]

Detailed Solution: Question 13

 

Chemistry: Topic-wise Test- 4 - Question 14

Osmotic pressure of insulin solution at 298 K is found to be 0.0072 atm at 298 K. Hence, height of water column due to this pressure is (density of mercury = 13.6 g mL-1)

Detailed Solution: Question 14

(c) Pressure (due to insulin) = 0.0072 atm

= 0.0072 x 76 cm of Hg

= 0.0072 x 76 x 13.6 cm of Hg column

Height of water column = h cm

∴ p = h x 1 cm of water column

(Density of water = 1 g mL-1)

∴ h x 1 = 0.0072 x 76 x 13.6 = 7.44 cm

Chemistry: Topic-wise Test- 4 - Question 15

Which has maximum osmotic pressure at temperature T K?

Detailed Solution: Question 15

Chemistry: Topic-wise Test- 4 - Question 16

There is formation of Prussian blue when Fe3+ reacts with [Fe(CN)6]4-. Two solutions as shown are separated by a semipermeable membrane AB. Due to osmosis, there is

Detailed Solution: Question 16

Side X (0.1 M)            Side Y (0.01 M)

     (Concentrated)              (Dilute)

There is osmosis of solvent (H20) from dilute solution (Y) to concentrated solution (X). There is no osmosis of ions, hence no blue colour formation.

Chemistry: Topic-wise Test- 4 - Question 17

Three solutions of following in water are isothermal conditions as given:

Thus,

Detailed Solution: Question 17

Chemistry: Topic-wise Test- 4 - Question 18

Only One Option Correct Type
This section contains 7 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct

Q.

The degree of dissociation (α ) o f weak electrolyte AxBy is related to van’t Hoff factor (i) by the expression

[AIEEE 2011]

Detailed Solution: Question 18

 (a) van’t Hoff factor (i) = [1 + (n - 1)α] where, n = number of ions from one mole of solute

α = degree of ionisation/association 

Chemistry: Topic-wise Test- 4 - Question 19

0.004 M Na2S04 aqueous solution is isotonic with 0.01 M glucose solution at 300 K. Thus, degree of dissociation of Na2S04 is

Detailed Solution: Question 19

i (van’t Hoff factor) = 1 + (y — 1) x = (1 + 2 x)

∴ π, (osmotic pressure) = MRTi = 0.004 x R x 300 x (1 + 2x)

Glucose is a non-electrolyte.
Hence,

i = 1

π2 = mRTi = 0.01 x R x 300 x 1 Two solutions are isotonic, hence

Chemistry: Topic-wise Test- 4 - Question 20

When 20 g of naphthoic acid (C11H8O2) is dissolved in 50 g of benzene, a freezing point depression of 2 K is observed. [Kf (benzene) = 1.72Kmol-1 kg]. The van’t Hoff factor (i) is 

[IIT - JEE 2007]

Detailed Solution: Question 20

w1| = 20.0 g

m1 = 11x 12 + 8 x 1 + 2 x 16 = 172 g mol-1  w2 = 50.0 g 

Chemistry: Topic-wise Test- 4 - Question 21

An aqueous solution of a solute AB has boiling point of 101.08° C and freezes at -1 .80 °C . AB is found to be 100% ionised at boiling point. If Kb /Kf = 0.3, then AB

Detailed Solution: Question 21

Thus, AS behaves as a non-electrolyte at the freezing point of solution (remains non-ionised).

Chemistry: Topic-wise Test- 4 - Question 22

Only One Option Correct Type

Direction (Q. Nos. 1-8) This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.

Q. 

The correct order of acidic strength of the following alcohols is

Detailed Solution: Question 22

Electron donating (+ / -effect) alkyl groups decreases the acidic strength.

Chemistry: Topic-wise Test- 4 - Question 23

Which compound given below has the highest solubility in water ?

Detailed Solution: Question 23

Greater the number of hydroxy groups , greater its a bility to form H-bonds with water, hence greater solubility.

Chemistry: Topic-wise Test- 4 - Question 24

What is the correct increasing order of acidity of the following?

 

Detailed Solution: Question 24

Both (I) and (II) are 2° alcohols, less acidicthan (I) and (IV) where there is electron withdrawing chloride group is present. Between (I) and (II), (I) is less acidic as ring is considered here equivalent to two ethyl groups attached to α-carbon. (Ill) is more acidic than (IV) because in (III) Cl is at α-carbon while it is at β-carbon in (IV).

Chemistry: Topic-wise Test- 4 - Question 25

What is the order of solubility of the following in water?

Detailed Solution: Question 25

Dihydric alcohols are always more soluble in water than monohydric alcohol. Between (I) and (II), (I) is more soluble as it forms intermolecular H-bonds with water while (II) forms intramolecular H-bonds which decreases its ability to form intermolecular H-bonds with water.

Chemistry: Topic-wise Test- 4 - Question 26

Which of the following can be used for the distinction of ethanol from phenol?

Detailed Solution: Question 26

Phenol forms salt with NaOH while a liphatic alcohols do not.

Chemistry: Topic-wise Test- 4 - Question 27

Consider the following reaction,

The above reaction can best be brought about by

Detailed Solution: Question 27

In the below reaction , no bond with chiral carbon is disturbed, hence, configuration is retained in product.

*Answer can only contain numeric values
Chemistry: Topic-wise Test- 4 - Question 28

E° values of Mn+ + ne- → M are given below
Fe2+/Fe -0.44 V, Mg2+/Mg -2.37 V, Pt(H2)/H+ 0.00 V,
AI3+/AI -1.66 V , Zn2+/Zn - 0.76 V, Cu2+/Cu +0.34 V,
Ag+/Ag + 0.80 V, Ni2+/Ni -0.26 V

How many of the metals can be used to prevent corrosion of Ni to Ni2+?


Detailed Solution: Question 28

Fe, Al, Zn and Mg can be used to protect Ni from being oxidised to Ni2+ since, E°cell > 0 and ΔG° < 0.

*Answer can only contain numeric values
Chemistry: Topic-wise Test- 4 - Question 29

A fully charged battery contains 500 mL of 5.00 M H2SO4. What is the concentration of H2SO4 in the battery after 6.0 A of current is drawn from the battery for 13.40 h?


Detailed Solution: Question 29

Chemistry: Topic-wise Test- 4 - Question 30

 With increase in temperature the degree of dissociation of electrolyte:

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